hexacarbonylvanadium

Formula: C₆O₆V
Molecular weight: 219.0021
CAS Registry Number: 14024-00-1
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Gas phase ion energetics data

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV)	Method	Reference	Comment
7.53 ± 0.15	EI	Bidinosti and McIntyre, 1967	RDSH
7.52	PE	Evans, Green, et al., 1969	Vertical value; RDSH

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
VCO⁺	13.8 ± 0.2	5CO	EI	Bidinosti and McIntyre, 1967	RDSH
VC⁺	23.8 ± 0.8	?	EI	Bidinosti and McIntyre, 1967	RDSH
VC₂O₂⁺	12.3 ± 0.2	4CO	EI	Bidinosti and McIntyre, 1967	RDSH
VC₃O₃⁺	10.98 ± 0.15	3CO	EI	Bidinosti and McIntyre, 1967	RDSH
VC₄O₄⁺	9.7 ± 0.2	2CO	EI	Bidinosti and McIntyre, 1967	RDSH
VC₅O₅⁺	8.24 ± 0.15	CO	EI	Bidinosti and McIntyre, 1967	RDSH
V⁺	15.5 ± 0.2	6CO	EI	Bidinosti and McIntyre, 1967	RDSH

References

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Bidinosti and McIntyre, 1967
Bidinosti, D.R.; McIntyre, N.S., Electron-impact study of some binary metal carbonyls, Can. J. Chem., 1967, 45, 641. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Orchard, A.F.; Saito, T.; Turner, D.W., The photoelectron spectrum of vanadium hexacarbonyl, Chem. Phys. Lett., 1969, 4, 361. [all data]

Notes

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Symbols used in this document:

AE Appearance energy
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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