CuNO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx Ne 500 670 Krim, Wang, et al., 2005
Tx Ar 500 670 Krim, Wang, et al., 2005

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5444.8 Ne 1350 1840 Krim, Wang, et al., 2005
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NO stretch 1545.4 Ne AB Krim, Wang, et al., 2005
2 Bend 196.2 Ne AB Krim, Wang, et al., 2005
3 CuN stretch 329.5 Ne AB Krim, Wang, et al., 2005

State:   X'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Ar Zhou and Andrews, 2000
Krim, Wang, et al., 2005
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NO stretch 1520.6 Ar IR Zhou and Andrews, 2000
Krim, Wang, et al., 2005
1 NO stretch 1516.0 Ar IR Zhou and Andrews, 2000
Krim, Wang, et al., 2005
2 Bend 219.5 w Ar IR Krim, Wang, et al., 2005
3 CuN stretch 512.1 Ar IR Krim, Wang, et al., 2005

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NO stretch 1602.2 Ne IR Zhou and Andrews, 2000
Krim, Wang, et al., 2005
1 NO stretch 1587.1 Ar IR Zhou and Andrews, 2000
Krim, Wang, et al., 2005
2 Bend 276.4 Ne IR Krim, Wang, et al., 2005
2 Bend 278.2 Ar IR Krim, Wang, et al., 2005
3 CuN stretch 452.1 Ne IR Krim, Wang, et al., 2005
3 CuN stretch 452.6 Ar IR Krim, Wang, et al., 2005

Additional references: Jacox, 2003, page 93

Notes

wWeak
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Krim, Wang, et al., 2005
Krim, L.; Wang, X.; Manceron, L.; Andrews, L., Absorption Spectra of Ground-State and Low-Lying Electronic States of Copper Nitrosyl: A Rare Gas Matrix Isolation Study, J. Phys. Chem. A, 2005, 109, 45, 10264, https://doi.org/10.1021/jp053778l . [all data]

Zhou and Andrews, 2000
Zhou, M.; Andrews, L., Reactions of Laser-Ablated Cu with NO: Infrared Spectra and Density Functional Calculations of CuNO, J. Phys. Chem. A, 2000, 104, 12, 2618, https://doi.org/10.1021/jp993516h . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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