Dimethyl ether

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
ΔfH°gas-184.1 ± 0.50kJ/molCcbPilcher, Pell, et al., 1964ALS
Quantity Value Units Method Reference Comment
ΔcH°gas-1460.4 ± 0.46kJ/molCcbPilcher, Pell, et al., 1964Corresponding ΔfHºgas = -184.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
42.27100.Chao J., 1986p=1 bar. Selected values are in close agreement with other statistically calculated values [ Handi M.A., 1954, Seha Z., 1955, Banerjee S.C., 1964, Stull D.R., 1969] and ab initio result [ East A.L.L., 1997] at low temperatures. Discrepancies in S(1000 K) and Cp(1000 K) amount to about 5 and 3 J/mol*K, respectively, for [ Handi M.A., 1954, Banerjee S.C., 1964, Stull D.R., 1969].; GT
48.99150.
54.47200.
62.56273.15
65.57 ± 0.08298.15
65.80300.
78.68400.
91.36500.
102.86600.
113.03700.
121.99800.
129.84900.
136.701000.
142.691100.
147.891200.
152.411300.
156.351400.
159.771500.
166.571750.
171.502000.
175.152250.
177.912500.
180.032750.
181.703000.

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
62.01272.20Kistiakowsky G.B., 1940GT
65.90300.76
70.33333.25
75.14370.42

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

C3H7O2+ + Dimethyl ether = (C3H7O2+ • Dimethyl ether)

By formula: C3H7O2+ + C2H6O = (C3H7O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°126.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°90.4kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H9O2+ + Dimethyl ether = (C4H9O2+ • Dimethyl ether)

By formula: C4H9O2+ + C2H6O = (C4H9O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°125.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°122.J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°88.7kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°85. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°100. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°92.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
73.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
73.6298.CIDCMcMahon and Ohanessian, 2000RCD

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ • Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°40.kJ/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

(CH5O+ • 2Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + C2H6O = (CH5O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°72.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 3Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + C2H6O = (CH5O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°57.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°129.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + C2H6O = (CH5O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°91.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

C2H7O+ + Dimethyl ether = (C2H7O+ • Dimethyl ether)

By formula: C2H7O+ + C2H6O = (C2H7O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°134.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrH°128.kJ/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°133.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrS°124.J/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

Potassium ion (1+) + Dimethyl ether = (Potassium ion (1+) • Dimethyl ether)

By formula: K+ + C2H6O = (K+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°72.8 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
ΔrH°87.0kJ/molHPMSDavidson and Kebarle, 1976, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°112.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
ΔrS°104.J/mol*KHPMSDavidson and Kebarle, 1976, 2gas phase; M

CH5O+ + Dimethyl ether = (CH5O+ • Dimethyl ether)

By formula: CH5O+ + C2H6O = (CH5O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°146.kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M

(C2H7O+ • Dimethyl ether • 2Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • 2Water)

By formula: (C2H7O+ • C2H6O • 2H2O) + C2H6O = (C2H7O+ • 2C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°66.1kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°153.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • Dimethyl ether) + Water = (C2H7O+ • Water • Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + H2O = (C2H7O+ • H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°68.2kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°162.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • Water)

By formula: (C2H7O+ • C2H6O • H2O) + C2H6O = (C2H7O+ • 2C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°70.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 3Dimethyl ether • Water)

By formula: (C2H7O+ • 2C2H6O • H2O) + C2H6O = (C2H7O+ • 3C2H6O • H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
ΔrH°90.8kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°174.J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M

(C2H7O+ • 2Methyl Alcohol • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • 3Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • 2CH4O • C2H6O) + CH4O = (C2H7O+ • 3CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Methyl Alcohol • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • 2Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • CH4O • C2H6O) + CH4O = (C2H7O+ • 2CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°63.2kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°128.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 2Dimethyl ether) + Water = (C2H7O+ • 2Water • 2Dimethyl ether)

By formula: (C2H7O+ • H2O • 2C2H6O) + H2O = (C2H7O+ • 2H2O • 2C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 3Dimethyl ether) + Water = (C2H7O+ • 2Water • 3Dimethyl ether)

By formula: (C2H7O+ • H2O • 3C2H6O) + H2O = (C2H7O+ • 2H2O • 3C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water • Dimethyl ether) + Water = (C2H7O+ • 3Water • Dimethyl ether)

By formula: (C2H7O+ • 2H2O • C2H6O) + H2O = (C2H7O+ • 3H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°48.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°112.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Water)

By formula: (C2H7O+ • 2H2O) + C2H6O = (C2H7O+ • C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°68.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°95.4J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Water)

By formula: (C2H7O+ • 3H2O) + C2H6O = (C2H7O+ • C2H6O • 3H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°70.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°138.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • Dimethyl ether) + Water = (C2H7O+ • 2Water • Dimethyl ether)

By formula: (C2H7O+ • H2O • C2H6O) + H2O = (C2H7O+ • 2H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°56.9kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Water)

By formula: (C2H7O+ • H2O) + C2H6O = (C2H7O+ • C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°77.4kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (C2H7O+ • 2CH4O) + C2H6O = (C2H7O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°69.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°133.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (C2H7O+ • 3CH4O) + C2H6O = (C2H7O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°52.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°107.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + CH4O = (C2H7O+ • CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°75.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°128.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Methyl Alcohol)

By formula: (C2H7O+ • CH4O) + C2H6O = (C2H7O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°84.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°125.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + C2H6O = (C2H7O+ • 2C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°42.3kJ/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

CH6N+ + Dimethyl ether = (CH6N+ • Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
ΔrH°90.0kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°123.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
ΔrH°31.4 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°12. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

C2H5O- + Hydrogen cation = Dimethyl ether

By formula: C2H5O- + H+ = C2H6O

Quantity Value Units Method Reference Comment
ΔrH°1703. ± 8.4kJ/molBranDePuy, Bierbaum, et al., 1984gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°1666. ± 9.2kJ/molH-TSDePuy, Bierbaum, et al., 1984gas phase; B

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°66.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°58.2 ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD

(Potassium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 3Dimethyl ether)

By formula: (K+ • 2C2H6O) + C2H6O = (K+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 4Dimethyl ether)

By formula: (K+ • 3C2H6O) + C2H6O = (K+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°50.2 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 3Dimethyl ether)

By formula: (Cs+ • 2C2H6O) + C2H6O = (Cs+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°40. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 2Dimethyl ether)

By formula: (Cs+ • C2H6O) + C2H6O = (Cs+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°46.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 3Dimethyl ether)

By formula: (Rb+ • 2C2H6O) + C2H6O = (Rb+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°37. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 2Dimethyl ether)

By formula: (Rb+ • C2H6O) + C2H6O = (Rb+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 2Dimethyl ether)

By formula: (K+ • C2H6O) + C2H6O = (K+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°69.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Copper ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 3Dimethyl ether)

By formula: (Cu+ • 2C2H6O) + C2H6O = (Cu+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 4.2kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 4Dimethyl ether)

By formula: (Cu+ • 3C2H6O) + C2H6O = (Cu+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°45. ± 10.kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 2Dimethyl ether)

By formula: (Cu+ • C2H6O) + C2H6O = (Cu+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°193. ± 7.9kJ/molCIDTKoizumi, 2001RCD

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) • Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) • Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H6O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.025 ± 0.025eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)792.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity764.5kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.025 ± 0.025PIPECOButler, Holland, et al., 1984LBLHLM
9.95 ± 0.07EIBowen and Maccoll, 1984LBLHLM
10.04PEKimura, Katsumata, et al., 1981LLK
9.8 ± 0.1PEAue, Webb, et al., 1980LLK
9.8PEAue and Bowers, 1979LLK
10.01 ± 0.01PIBotter, Pechine, et al., 1977LLK
9.94 ± 0.01PECocksey, Eland, et al., 1971LLK
10.1 ± 0.2EIIvko, 1970RDSH
9.94PEDewar and Worley, 1969RDSH
9.96 ± 0.05SHernandez, 1963RDSH
10.00 ± 0.02PIWatanabe, 1957RDSH
10.0PEBajic, Humski, et al., 1985Vertical value; LBLHLM
10.1PEBieri, Asbrink, et al., 1982Vertical value; LBLHLM
11.94PEUtsunomiya, Kobayashi, et al., 1980Vertical value; LLK
10.0 ± 0.2PECarnovale, Livett, et al., 1980Vertical value; LLK
10.1PEAue and Bowers, 1979Vertical value; LLK
10.03PEKobayashi, 1978Vertical value; LLK
9.98PEBenoit and Harrison, 1977Vertical value; LLK
10.052PEAue, Webb, et al., 1975Vertical value; LLK
10.04PEBock, Mollere, et al., 1973Vertical value; LLK
10.04PECradock and Whiteford, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+≤12.85 ± 0.10H2+CH3PIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CHO+14.0 ± 0.2?EIIvko, 1970RDSH
CH3+≤14.4 ± 0.1CH2O+HPIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CH3+14.93 ± 0.13?EIHaney and Franklin, 1969RDSH
CH3O+≤11.85 ± 0.10CH3PIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CH3O+≤11.8CH3EILossing, 1977LLK
CH3O+12.4 ± 0.1CH3EIIvko, 1970RDSH
CH3O+11.95 ± 0.05CH3EIHaney and Franklin, 1969RDSH
C2H5O+11.115 ± 0.010HPIPECOButler, Holland, et al., 1984T = 0K; LBLHLM
C2H5O+10.99 ± 0.08HEIBowen and Maccoll, 1984LBLHLM
C2H5O+10.99HEILossing, 1977LLK
C2H5O+11.23 ± 0.04HEISolka and Russell, 1974LLK
C2H5O+10.70 ± 0.13HEIFinney and Harrison, 1972LLK
C2H5O+11.55 ± 0.15HEIIvko, 1970RDSH
C2H5O+11.42 ± 0.01HEIMartin, Lampe, et al., 1966RDSH

De-protonation reactions

C2H5O- + Hydrogen cation = Dimethyl ether

By formula: C2H5O- + H+ = C2H6O

Quantity Value Units Method Reference Comment
ΔrH°1703. ± 8.4kJ/molBranDePuy, Bierbaum, et al., 1984gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°1666. ± 9.2kJ/molH-TSDePuy, Bierbaum, et al., 1984gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CH5O+ • Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + C2H6O = (CH5O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°91.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 2Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + C2H6O = (CH5O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°72.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 3Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + C2H6O = (CH5O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°57.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°129.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

CH5O+ + Dimethyl ether = (CH5O+ • Dimethyl ether)

By formula: CH5O+ + C2H6O = (CH5O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°146.kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M

CH6N+ + Dimethyl ether = (CH6N+ • Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
ΔrH°90.0kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°123.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C2H7O+ • Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Methyl Alcohol)

By formula: (C2H7O+ • CH4O) + C2H6O = (C2H7O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°84.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°125.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (C2H7O+ • 2CH4O) + C2H6O = (C2H7O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°69.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°133.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (C2H7O+ • 3CH4O) + C2H6O = (C2H7O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°52.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°107.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Dimethyl ether = (C2H7O+ • Dimethyl ether)

By formula: C2H7O+ + C2H6O = (C2H7O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°134.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrH°128.kJ/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°133.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrS°124.J/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ • Dimethyl ether) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + C2H6O = (C2H7O+ • 2C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°42.3kJ/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ • Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • Water)

By formula: (C2H7O+ • C2H6O • H2O) + C2H6O = (C2H7O+ • 2C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°70.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether • 2Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • 2Water)

By formula: (C2H7O+ • C2H6O • 2H2O) + C2H6O = (C2H7O+ • 2C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°66.1kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°153.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • 2Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 3Dimethyl ether • Water)

By formula: (C2H7O+ • 2C2H6O • H2O) + C2H6O = (C2H7O+ • 3C2H6O • H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
ΔrH°90.8kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°174.J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M

(C2H7O+ • Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Water)

By formula: (C2H7O+ • H2O) + C2H6O = (C2H7O+ • C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°77.4kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Water)

By formula: (C2H7O+ • 2H2O) + C2H6O = (C2H7O+ • C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°68.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°95.4J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Water)

By formula: (C2H7O+ • 3H2O) + C2H6O = (C2H7O+ • C2H6O • 3H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°70.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°138.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C3H7O2+ + Dimethyl ether = (C3H7O2+ • Dimethyl ether)

By formula: C3H7O2+ + C2H6O = (C3H7O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°126.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°90.4kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H9O2+ + Dimethyl ether = (C4H9O2+ • Dimethyl ether)

By formula: C4H9O2+ + C2H6O = (C4H9O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°125.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°122.J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°88.7kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ • Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°40.kJ/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
ΔrH°31.4 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°12. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) • Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 2Dimethyl ether)

By formula: (Cs+ • C2H6O) + C2H6O = (Cs+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°46.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 3Dimethyl ether)

By formula: (Cs+ • 2C2H6O) + C2H6O = (Cs+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°40. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Dimethyl ether = (Copper ion (1+) • Dimethyl ether)

By formula: Cu+ + C2H6O = (Cu+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°185. ± 12.kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 2Dimethyl ether)

By formula: (Cu+ • C2H6O) + C2H6O = (Cu+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°193. ± 7.9kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 3Dimethyl ether)

By formula: (Cu+ • 2C2H6O) + C2H6O = (Cu+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 4.2kJ/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 4Dimethyl ether)

By formula: (Cu+ • 3C2H6O) + C2H6O = (Cu+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°45. ± 10.kJ/molCIDTKoizumi, 2001RCD

Potassium ion (1+) + Dimethyl ether = (Potassium ion (1+) • Dimethyl ether)

By formula: K+ + C2H6O = (K+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°72.8 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
ΔrH°87.0kJ/molHPMSDavidson and Kebarle, 1976, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°112.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
ΔrS°104.J/mol*KHPMSDavidson and Kebarle, 1976, 2gas phase; M

(Potassium ion (1+) • Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 2Dimethyl ether)

By formula: (K+ • C2H6O) + C2H6O = (K+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°69.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 3Dimethyl ether)

By formula: (K+ • 2C2H6O) + C2H6O = (K+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 4Dimethyl ether)

By formula: (K+ • 3C2H6O) + C2H6O = (K+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°50.2 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°100. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°92.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
73.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
73.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°85. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°66.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°58.2 ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) • Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 2Dimethyl ether)

By formula: (Rb+ • C2H6O) + C2H6O = (Rb+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 3Dimethyl ether)

By formula: (Rb+ • 2C2H6O) + C2H6O = (Rb+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°37. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 78

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C2ν     Symmetry Number σ = 2
 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase
a1 1 CH3 d-str 2996  B 2996 S gas 2989 S liq.
a1 2 CH3 s-str 2817  B 2817 S gas 2815 VS p liq.
a1 3 CH3 d-deform 1464  D 1464 M gas
a1 4 CH3 s-deform 1452  D 1452 M gas 1452 S dp liq.
a1 5 CH3 rock 1244  B 1244 W gas
a1 6 CO s-str 928  B 928 S gas 922 S p liq.
a1 7 COC deform 418  C 418 M gas 428 M p liq.
a2 8 CH3 d-str 2952  C  ia 2952 S liq.
a2 9 CH3 d-deform 1464  D  ia SF(ν3)
a2 10 CH3 rock 1150  C  ia 1150 M d liq.
a2 11 Torsion 203  E  ia CF
b1 12 CH3 d-str 2996  B 2996 S gas 2989 S liq. OV(ν1)
b1 13 CH3 s-str 2817  B 2817 S gas 2815 VS p liq. OV(ν2)
b1 14 CH3 d-deform 1464  D 1464 M gas OV(ν3)
b1 15 CH3 s-deform 1452  D 1452 M gas 1452 S dp liq. OV(ν4)
b1 16 CH3 rock 1227  C 1227 W liq.
b1 17 CO a-str 1102  B 1102 VS gas 1104 M dp liq.
b2 18 CH3 d-str 2925  B 2925 S gas
b2 19 CH3 d-deform 1464  D 1464 M gas OV(ν3)
b2 20 CH3 rock 1179  B 1179 VS gas 1170 sh liq.
b2 21 Torsion 242  C 242 W gas

Source: Shimanouchi, 1972

Notes

dPhotodissociation threshold
VSVery strong
SStrong
MMedium
WWeak
iaInactive
shShoulder
pPolarized
dpDepolarized
CFCalculated frequency
SFCalculation shows that the frequency approximately equals that of the vibration indicated in the parentheses.
OVOverlapped by band indicated in parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty
E15~30 cm-1 uncertainty

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedSqualane50.323.Becerra, Sánchez, et al., 1982N2, Chromosorb W-AM; Column length: 6. m
PackedSqualane50.325.Becerra, Sánchez, et al., 1982N2, Chromosorb W-AM; Column length: 6. m
PackedApiezon L120.324.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L160.331.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon M130.323.Golovnya and Garbuzov, 1974N2, Chromosorb W; Column length: 2.1 m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101327.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySE-30350.Vinogradov, 2004Program: not specified
CapillarySPB-1328.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryPolydimethyl siloxanes327.Zenkevich and Chupalov, 1996Program: not specified
CapillarySPB-1328.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C

Normal alkane RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M60.478.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium
CapillaryCarbowax 20M80.481.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax 20M524.Vinogradov, 2004Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher, Pell, et al., 1964
Pilcher, G.; Pell, A.S.; Coleman, D.J., Measurements of heats of combustion by flame calorimetry. Part 2-Dimethyl ether, methyl ethyl ether, methyl n-propyl ether, methyl isopropyl ether, Trans. Faraday Soc., 1964, 60, 499-505. [all data]

Chao J., 1986
Chao J., Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties, J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]

Handi M.A., 1954
Handi M.A., Molecular spectroscopy. Determination and interpretation of fundamental frequencies of dimethyl ether from infrared absorption spectrum; application for thermodynamic functions calculation, Compt. Rend. Acad. Sci., 1954, 239, 349-351. [all data]

Seha Z., 1955
Seha Z., Thermodynamic functions of dimethyl ether, Chem. Listy, 1955, 49, 1569-1570. [all data]

Banerjee S.C., 1964
Banerjee S.C., Thermodynamic properties of organic compounds. Part 1. Normal symmetrical aliphatic ethers, Brit. Chem. Eng., 1964, 9, 311-313. [all data]

Stull D.R., 1969
Stull D.R., Jr., The Chemical Thermodynamics of Organic Compounds. Wiley, New York, 1969. [all data]

East A.L.L., 1997
East A.L.L., Ab initio statistical thermodynamical models for the computation of third-law entropies, J. Chem. Phys., 1997, 106, 6655-6674. [all data]

Kistiakowsky G.B., 1940
Kistiakowsky G.B., Gaseous heat capacities. III, J. Chem. Phys., 1940, 8, 618-622. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

More, Gledening, et al., 1996
More, M.B.; Gledening, E.D.; Ray, D.; Feller, D.; Armentrout, P.B., Cation-Ether Complexes in the Gas Phase: Bond Dissociation Energies and Equilibrium Structures of Li+[O(CH3)2]x, x=1-4, J. Phys. Chem., 1996, 100, 5, 1605, https://doi.org/10.1021/jp9523175 . [all data]

Larson and McMahon, 1982
Larson, J.W.; McMahon, T.B., Formation, Thermochemistry, and Relative Stabilities of Proton - Bound dimers of Oxygen n - Donor Bases from Ion Cyclotron Resonance Solvent - Exchange Equilibria Measurements, J. Am. Chem. Soc., 1982, 104, 23, 6255, https://doi.org/10.1021/ja00387a016 . [all data]

Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Amicangelo and Armentrout, 2001
Amicangelo, J.C.; Armentrout, P.B., Relative and Absolute Bond Dissociation Energies of Sodium Cation Complexes Determined Using Competitive Collision-Induced Dissociation Experiments, Int. J. Mass Spectrom., 2001, 212, 1-3, 301, https://doi.org/10.1016/S1387-3806(01)00494-8 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

Meot-Ner (Mautner), 1989
Meot-Ner (Mautner), M., Ion DChemistry of Ferrocene. Thermochemistry of Ionization and Protonation and Solvent Clustering. Slow and Entropy - Driven Proton - Transfer Kinetics, J. Am. Chem. Soc., 1989, 111, 8, 2830, https://doi.org/10.1021/ja00190a014 . [all data]

Hiraoka, Grimsrud, et al., 1974
Hiraoka, K.; Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Hydrogen Ion in Water - Dimethyl Ether and Methanol - Dimethyl Ether Mixtures, J. Am. Chem. Soc., 1974, 96, 11, 3359, https://doi.org/10.1021/ja00818a004 . [all data]

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes with Ethylene Diamine and Dimethoxyethane (Glyme) from Measurements of the Complexing Equilibria in the Gas Phase, Can. J. Chem., 1976, 54, 16, 2594, https://doi.org/10.1139/v76-368 . [all data]

Davidson and Kebarle, 1976, 2
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes from Studies of Gas Phase Ion Equilibria K+ + M = K+.M, J. Am. Chem. Soc., 1976, 98, 20, 6133, https://doi.org/10.1021/ja00436a011 . [all data]

Tholman, Tonner, et al., 1994
Tholman, D.; Tonner, D.S.; McMahon, T.B., Spontaneous Unimolecular Dissociation of Small Cluster Ions, (H3O)+(L)n and Cl-(H2O)n (n = 2-4), under Fourier Transform Ion Cyclotron Resonance Conditions, J. Phys. Chem., 1994, 98, 8, 2002, https://doi.org/10.1021/j100059a002 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Bogdanov, Lee, et al., 2001
Bogdanov, B.; Lee, H.J.S.; McMahon, T.B., Influence of fluorine substitution on the structures and thermochemistry of chloride ion-ether complexes in the gas phase, Int. J. Mass Spectrom., 2001, 210, 387-402, https://doi.org/10.1016/S1387-3806(01)00404-3 . [all data]

DePuy, Bierbaum, et al., 1984
DePuy, C.H.; Bierbaum, V.M.; Damrauer, R., Relative Gas-Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1984, 106, 4051. [all data]

Koizumi, 2001
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethyl Ether Complexes, J.Phys. Chem. A, 2001, 105, 11, 2444, https://doi.org/10.1021/jp003509p . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Butler, Holland, et al., 1984
Butler, J.J.; Holland, D.M.P.; Parr, A.C.; Stockbauer, R., A threshold photoelectron-photoion coincidence spectrometric study of dimethyl ether (CH3OCH3), Int. J. Mass Spectrom. Ion Processes, 1984, 58, 1. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]

Aue, Webb, et al., 1980
Aue, D.H.; Webb, H.M.; Davidson, W.R.; Vidal, M.; Bowers, M.T.; Goldwhite, H.; Vertal, L.E.; Douglas, J.E.; Kollman, P.A.; Kenyon, G.L., Proton affinities photoelectron spectra of three-membered-ring J. Heterocycl. Chem., J. Am. Chem. Soc., 1980, 102, 5151. [all data]

Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T., Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]

Botter, Pechine, et al., 1977
Botter, R.; Pechine, J.M.; Rosenstock, H.M., Photoionization of dimethyl ether and diethyl ether, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 7. [all data]

Cocksey, Eland, et al., 1971
Cocksey, B.J.; Eland, J.H.D.; Danby, C.J., The effect of alkyl substitution on ionisation potential, J. Chem. Soc., 1971, (B), 790. [all data]

Ivko, 1970
Ivko, A.A., Use of mass spectroscopy and isotope labelling for determining the structure of ions and molecules, Org. Katal., 1970, 20. [all data]

Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D., Photoelectron spectra of molecules. I. Ionization potentials of some organic molecules and their interpretation, J. Chem. Phys., 1969, 50, 654. [all data]

Hernandez, 1963
Hernandez, G.J., Vacuum ultraviolet absorption spectrum of dimethyl ether, J. Chem. Phys., 1963, 38, 1644. [all data]

Watanabe, 1957
Watanabe, K., Ionization potentials of some molecules, J. Chem. Phys., 1957, 26, 542. [all data]

Bajic, Humski, et al., 1985
Bajic, M.; Humski, K.; Klasinc, L.; Ruscic, B., Substitution effects on electronic structure of thiophene, Z. Naturforsch. B:, 1985, 40, 1214. [all data]

Bieri, Asbrink, et al., 1982
Bieri, G.; Asbrink, L.; Von Niessen, W., 30.4-nm He(II) photoelectron spectra of organic molecules, J. Electron Spectrosc. Relat. Phenom., 1982, 27, 129. [all data]

Utsunomiya, Kobayashi, et al., 1980
Utsunomiya, C.; Kobayashi, T.; Nagakura, S., Photoelectron angular distribution measurements for some aliphatic alcohols, amines, halides, Bull. Chem. Soc. Jpn., 1980, 53, 1216. [all data]

Carnovale, Livett, et al., 1980
Carnovale, F.; Livett, M.K.; Peel, J.B., The photoelectron spectrum of the dimethyl ether-hydrogen chloride complex, J. Am. Chem. Soc., 1980, 102, 569. [all data]

Kobayashi, 1978
Kobayashi, T., A simple general tendency in photoelectron angular distributions of some monosubstituted benzenes, Phys. Lett., 1978, 69, 105. [all data]

Benoit and Harrison, 1977
Benoit, F.M.; Harrison, A.G., Predictive value of proton affinity. Ionization energy correlations involving oxygenated molecules, J. Am. Chem. Soc., 1977, 99, 3980. [all data]

Aue, Webb, et al., 1975
Aue, D.H.; Webb, H.M.; Bowers, M.T., Proton affinities, ionization potentials, and hydrogen affinities of nitrogen and oxygen bases. Hybridization effects, J. Am. Chem. Soc., 1975, 97, 4137. [all data]

Bock, Mollere, et al., 1973
Bock, H.; Mollere, P.; Becker, G.; Fritz, G., Photoelectron spectra molecular properties. XX. Dimethyl ether, methoxysilane, and disiloxane, J. Organomet. Chem., 1973, 61, 113. [all data]

Cradock and Whiteford, 1972
Cradock, S.; Whiteford, R.A., Photoelectron spectra of the methyl, silyl and germyl derivatives of the group VI elements, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 281. [all data]

Haney and Franklin, 1969
Haney, M.A.; Franklin, J.L., Excess energies in mass spectra of some oxygen-containing organic compounds, J. Chem. Soc. Faraday Trans., 1969, 65, 1794. [all data]

Lossing, 1977
Lossing, F.P., Heats of formation of some isomeric [CnH2n+1]+ ions. Substitutional effects on ion stability, J. Am. Chem. Soc., 1977, 99, 7526. [all data]

Solka and Russell, 1974
Solka, B.H.; Russell, M.E., Energetics of formation of some structural isomers of gaseous C2H5O+ C2H6N+ ions, J. Phys. Chem., 1974, 78, 1268. [all data]

Finney and Harrison, 1972
Finney, C.D.; Harrison, A.G., A third-derivative method for determining electron-impact onset potentials, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 221. [all data]

Martin, Lampe, et al., 1966
Martin, R.H.; Lampe, F.W.; Taft, R.W., An electron-impact study of ionization and dissociation in methoxy- and halogen- substituted methanes, J. Am. Chem. Soc., 1966, 88, 1353. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume I, National Bureau of Standards, 1972, 1-160. [all data]

Becerra, Sánchez, et al., 1982
Becerra, M.R.; Sánchez, E.F.; Domínguez, J.A.G.; Muñoz, J.G.; Molera, M.J., The use of gaseous and liquid n-paraffins in GC identification of oxidation products of acetondimethyl acetal, J. Chromatogr. Sci., 1982, 20, 8, 363-366, https://doi.org/10.1093/chromsci/20.8.363 . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Golovnya and Garbuzov, 1974
Golovnya, R.V.; Garbuzov, V.G., Effect of heteroatom in aliphatic sulfur- and oxygen-containing compounds on the values of the retention indices in gas chromatography, Izv. Akad. Nauk SSSR Ser. Khim., 1974, 7, 1519-1521. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Vinogradov, 2004
Vinogradov, B.A., Production, composition, properties and application of essential oils, 2004, retrieved from http://viness.narod.ru. [all data]

Flanagan, Streete, et al., 1997
Flanagan, R.J.; Streete, P.J.; Ramsey, J.D., Volatile Substance Abuse, UNODC Technical Series, No 5, United Nations, Office on Drugs and Crime, Vienna International Centre, PO Box 500, A-1400 Vienna, Austria, 1997, 56, retrieved from http://www.odccp.org/pdf/technicalseries1997-01-011.pdf. [all data]

Zenkevich and Chupalov, 1996
Zenkevich, I.G.; Chupalov, A.A., New Possibilities of Chromato Mass Pectrometric Identification of Organic Compounds Using Increments of Gas Chromatographic Retention Indices of Molecular Structural Fragments, Zh. Org. Khim. (Rus.), 1996, 32, 5, 656-666. [all data]

Strete, Ruprah, et al., 1992
Strete, P.J.; Ruprah, M.; Ramsey, J.D.; Flanagan, R.J., Detection and identification of volatile substances by headspace capillary gas chromatography to aid the diagnosis of acute poisoning, Analyst, 1992, 117, 7, 1111-1127, https://doi.org/10.1039/an9921701111 . [all data]

Sun, Siepmann, et al., 2006
Sun, L.; Siepmann, J.I.; Klotz, W.L.; Schure, M.R., retention in gas-liquid chromatography with a polyethylene oxide stationary phase: molecular simulation and experiment, J. Chromatogr. A, 2006, 1126, 1-2, 373-380, https://doi.org/10.1016/j.chroma.2006.05.084 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References