Cl2PS

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13169.31 ± 0.35 gas B-X 560 760 Yang, Zhang, et al., 2009
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PS stretch 612.8 gas LF Yang, Zhang, et al., 2009
3 ClPCl wag 252.2 gas LF Yang, Zhang, et al., 2009
4 PCl2 scissor 184.1 gas LF Yang, Zhang, et al., 2009

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PS stretch 675 gas LF Yang, Zhang, et al., 2009
2 PCl2 s-stretch 444 gas LF Yang, Zhang, et al., 2009
3 ClPCl wag 238 gas LF Yang, Zhang, et al., 2009
4 PCl2 scissor 192 gas LF Yang, Zhang, et al., 2009

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yang, Zhang, et al., 2009
Yang, J.; Zhang, X.; Clouthier, D.J.; Tarroni, R., Heavy atom nitroxyl radicals. III. Identification of the Cl[sub 2]P=S free radical in the gas phase by laser spectroscopy and ab initio calculations, J. Chem. Phys., 2009, 131, 20, 204307, https://doi.org/10.1063/1.3266944 . [all data]

Notes

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