AlNC

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 36389.1 ± 0.2 gas A-X 265 279 Gerasimov, Yang, et al., 1999
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend (w) 238 gas LF Gerasimov, Yang, et al., 1999
2 Bend (κ 1S+) 371 gas LF Gerasimov, Yang, et al., 1999
Σ+ 3 NC stretch 598 gas LF Gerasimov, Yang, et al., 1999

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 NC stretch 2069 ± 21 gas LF Gerasimov, Yang, et al., 1999
1 NC stretch 2051.4 Ar IR Lanzisera and Andrews, 1997
Π 2 Bend 100 ± 6 gas LF Gerasimov, Yang, et al., 1999
Σ+ 3 AlN stretch 557 gas LF Gerasimov, Yang, et al., 1999

Additional references: Jacox, 2003, page 79; Robinson, Apponi, et al., 1997; Walker and Gerry, 1997; Walker, Evans, et al., 2001

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gerasimov, Yang, et al., 1999
Gerasimov, I.; Yang, X.; Dagdigian, P.J., Laser fluorescence excitation spectra of the AlNC and AlCN isomers, J. Chem. Phys., 1999, 110, 1, 220, https://doi.org/10.1063/1.478097 . [all data]

Lanzisera and Andrews, 1997
Lanzisera, D.V.; Andrews, L., Reactions of Laser-Ablated Al, Ga, In, and Tl Atoms with Hydrogen Cyanide in Excess Argon. Matrix Infrared Spectra and Density Functional Theory Calculations on New Cyanide and Isocyanide Products, J. Phys. Chem. A, 1997, 101, 50, 9660, https://doi.org/10.1021/jp972333x . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Robinson, Apponi, et al., 1997
Robinson, J.S.; Apponi, A.J.; Ziurys, L.M., The millimeter-wave spectrum of AlNC: chemical trends in metal isocyanide molecules, Chem. Phys. Lett., 1997, 278, 1-3, 1, https://doi.org/10.1016/S0009-2614(97)00950-0 . [all data]

Walker and Gerry, 1997
Walker, K.A.; Gerry, M.C.L., Nuclear hyperfine interactions in the microwave spectrum of aluminium isocyanide, Chem. Phys. Lett., 1997, 278, 1-3, 9, https://doi.org/10.1016/S0009-2614(97)00951-2 . [all data]

Walker, Evans, et al., 2001
Walker, K.A.; Evans, C.J.; Suh, S.-H.K.; Gerry, M.C.L.; Watson, J.K.G., Fourier Transform Microwave Spectroscopy of Cyanides and Isocyanides of Al, Ga, and In, J. Mol. Spectrosc., 2001, 209, 2, 178, https://doi.org/10.1006/jmsp.2001.8421 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References