2-Silaisobutene

• Formula: C₃H₈Si
• Molecular weight: 72.1811
• IUPAC Standard InChI: InChI=1S/C3H8Si/c1-4(2)3/h1H2,2-3H3 Copy

  
• IUPAC Standard InChIKey: ZIOQFHFYVWYPJP-UHFFFAOYSA-N Copy
• CAS Registry Number: 4112-23-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 401; Jacox, 2003, page 386; Mahaffy, Gutowsky, et al., 1980; Mal'tsev, Khabashesku, et al., 1984; Khabashesku, Kudin, et al., 1998

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Trommer, Sander, et al., 1993
Trommer, M.; Sander, W.; Patyk, A., Oxidation of methylsilenes with molecular oxygen. A matrix isolation study, J. Am. Chem. Soc., 1993, 115, 25, 11775, https://doi.org/10.1021/ja00078a016 . [all data]

Mal'tsev, Khabashesku, et al., 1977
Mal'tsev, A.K.; Khabashesku, V.N.; Nefedov, O.M., Dokl. Akad. Nauk SSSR, 1977, 233, 421. [all data]

Mal'tsev, Khabashesku, et al., 1979
Mal'tsev, A.K.; Khabashesku, V.N.; Nefedov, O.M., Izv. A.N. SSSR, 1979, Ser. Khim., 2152. [all data]

Nefedov, Mal'tsev, et al., 1980
Nefedov, O.M.; Mal'tsev, A.K.; Khabashesku, V.N.; Korolev, V.A., Ar-matrix stabilization and ir spectra of 1,1-dimethyl-1-silaethylene and its deuteromethyl derivative, J. Organomet. Chem., 1980, 201, 1, 123, https://doi.org/10.1016/S0022-328X(00)92571-3 . [all data]

Gusel'nikov, Volkova, et al., 1980
Gusel'nikov, L.E.; Volkova, V.V.; Avakyan, V.G.; Nametkin, N.S., Very low pressure pyrolysis (VLPP) of monosilacyclobutanes. Infrared absorptions of 1,1-dimethyl-1-silaethylene, (CH3)2Si«58875»CH2, and 1,1-dideuteriomethyl-1-silaethylene, (CD3)2Si«58875»CH2 isolated in argon matrices, J. Organomet. Chem., 1980, 201, 1, 137, https://doi.org/10.1016/S0022-328X(00)92572-5 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Mahaffy, Gutowsky, et al., 1980
Mahaffy, P.G.; Gutowsky, R.; Montgomery, L.K., An electron diffraction study of 1,1-dimethylsilaethylene, J. Am. Chem. Soc., 1980, 102, 8, 2854, https://doi.org/10.1021/ja00528a064 . [all data]

Mal'tsev, Khabashesku, et al., 1984
Mal'tsev, A.K.; Khabashesku, V.N.; Nefedov, O.M., Direct spectroscopic study of silaolefins. Vibrational frequencies of R2Si«58875»CD2 (R = CH3, CD3) in an argon matrix, J. Organomet. Chem., 1984, 271, 1-3, 55, https://doi.org/10.1016/0022-328X(84)85163-3 . [all data]

Khabashesku, Kudin, et al., 1998
Khabashesku, V.N.; Kudin, K.N.; Margrave, J.L., Vibrational analysis of infrared spectra of matrix-isolated transient silenes on basis of density functional theory calculations, J. Mol. Struct., 1998, 443, 1-3, 175, https://doi.org/10.1016/S0022-2860(97)00398-0 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.