Hydrogen chloride
- Formula: ClH
- Molecular weight: 36.461
- IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-N
- CAS Registry Number: 7647-01-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Hydrochloric ccid; Anhydrous hydrochloric acid; Chlorohydric acid; Hydrochloric acid gas; Hydrochloride; Muriatic acid; Salzsaeure; HCl; Hydrochloric acid, anhydrous; Hydrogen-chloride-anhydrous-; Acide chlorhydrique; Acido cloridrico; Chloorwaterstof; Chlorowodor; Chlorwasserstoff; NA 1789; Spirits of salt; UN 1050; UN 1789; UN 2186; Anhydrous hydrogen chloride; Hydrogen chloride (acid); Marine acid; Soldering acid; Spirit of salt; Spirits of salts; Hydrogen chloride (HCl); NSC 77365; Hydrochloric acid
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase thermochemistry data
Go To: Top, IR Spectrum, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -92.31 ± 0.10 | kJ/mol | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
ΔfH°gas | -92.31 | kJ/mol | Review | Chase, 1998 | Data last reviewed in September, 1964 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 186.902 ± 0.005 | J/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
S°gas,1 bar | 186.90 | J/mol*K | Review | Chase, 1998 | Data last reviewed in September, 1964 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | 298. to 1200. | 1200. to 6000. |
---|---|---|
A | 32.12392 | 31.91923 |
B | -13.45805 | 3.203184 |
C | 19.86852 | -0.541539 |
D | -6.853936 | 0.035925 |
E | -0.049672 | -3.438525 |
F | -101.6206 | -108.0150 |
G | 228.6866 | 218.2768 |
H | -92.31201 | -92.31201 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in September, 1964 | Data last reviewed in September, 1964 |
IR Spectrum
Go To: Top, Gas phase thermochemistry data, Constants of diatomic molecules, References, Notes
Data compiled by: Coblentz Society, Inc.
- GAS (200 mmHg DILUTED TO A TOTAL PRESSURE OF 600 mmHg WITH N2); DOW KBr FOREPRISM; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm-1 resolution
- GAS (200 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg); DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
Constants of diatomic molecules
Go To: Top, Gas phase thermochemistry data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Symbol | Meaning |
---|---|
State | electronic state and / or symmetry symbol |
Te | minimum electronic energy (cm-1) |
ωe | vibrational constant – first term (cm-1) |
ωexe | vibrational constant – second term (cm-1) |
ωeye | vibrational constant – third term (cm-1) |
Be | rotational constant in equilibrium position (cm-1) |
αe | rotational constant – first term (cm-1) |
γe | rotation-vibration interaction constant (cm-1) |
De | centrifugal distortion constant (cm-1) |
βe | rotational constant – first term, centrifugal force (cm-1) |
re | internuclear distance (Å) |
Trans. | observed transition(s) corresponding to electronic state |
ν00 | position of 0-0 band (units noted in table) |
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Rydberg 1 | 200-210 eV | |||||||||||
↳Hayes and Brown, 1972; Schwarz, 1975 | ||||||||||||
Numerous absorption bands above 123000 cm-1, tentatively assigned to higher members of the Rydberg series starting with L and M and converging to A 2Σ+ of HCl+. | ||||||||||||
↳Terwilliger and Smith, 1973 | ||||||||||||
M (1Σ+) | (117811) | [1529] 2 | M ← X | 117093 | ||||||||
↳missing citation | ||||||||||||
L (1Σ+,1Π) | 111280 | 1531 | 52 3 | L ← X | 110555 | |||||||
↳missing citation | ||||||||||||
4 | ||||||||||||
↳Douglas and Greening, 1979 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
K 1Π | (89861) | [2604.6] Z | [9.230] 5 | [-12.6E-4] 5 | [1.3654] | K ← X R | 89680.5 Z | |||||
↳Douglas and Greening, 1979 | ||||||||||||
H 1Σ+ | (89120) | [2093.8] Z | [8.4410] | [8.93E-4] | [1.4278] | H ← X R | 88684.5 Z | |||||
↳Douglas and Greening, 1979 | ||||||||||||
E 1Σ+ | (84193) | [2138.6] Z | [6.6423] | [36.2] | [1.6096] | E ← X R | 83780.2 Z | |||||
↳Douglas and Greening, 1979 | ||||||||||||
g (3Σ-)1 | [84329.7] 6 | [10.36] 7 | [17E-4] 7 | [1.289] | g ← X | 82847.4 Z | ||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
f1 3Δ1 | [84006.1] 6 | [10.270] 8 | [-13E-4] 8 | [1.294] | f1 ← X | 82523.8 Z | ||||||
↳missing citation | ||||||||||||
D 1Π | [83972.0] 9 | [9.794] 10 | [20.5E-4] 10 | [1.326] | D ← X R | 82489.7 Z | ||||||
↳missing citation | ||||||||||||
d0 3Π0 | [83753.6] 9 | [9.404] 11 | [-2.2E-4] 11 | [1.353] | d0 ← X R | 82271.3 Z | ||||||
↳missing citation | ||||||||||||
f2 3Δ2 | [83497.7] 6 | [10.851] 12 | [29.5E-4] 12 | [1.259] | f2 ← X V | 82015.4 Z | ||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
f3 3Δ3 | [83308.2] 6 | [9.45] 8 | [-1.3E-4] 8 | [1.349] | f3 ← X R | 81825.9 Z | ||||||
↳missing citation | ||||||||||||
d1 3Π1 | [83255.6] 9 | [9.768] 13 | [8E-4] 13 | [1.327] | d1 ← X R | 81773.3 Z | ||||||
↳missing citation | ||||||||||||
d2 3Π2 | [83083] 9 | [8.632] 14 | [-14E-4] 14 | [1.412] | d2 ← X R | 81600.7 Z | ||||||
↳missing citation | ||||||||||||
C 1Π | 77575 15 | [2684.0] Z | 16 | [9.333] | 16 | [1.358] | C ← X 17 R | 77485.3 Z | ||||
↳missing citation; Tilford, Ginter, et al., 1970 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
V 1Σ+ | 77293.0 18 | 877.16 Z | 16.04 19 | 2.727 | -0.026 | 1.02E-4 19 | 0.20E-4 | 2.512 | V ↔ X 20 R | 76245.3 Z | ||
↳Jacques, 1959; Jacques and Barrow, 1959; missing citation | ||||||||||||
V 1Σ+ 21 | V → A | |||||||||||
↳Jacques and Barrow, 1959 | ||||||||||||
b0 3Π0 | (75617) 15 | [2712] | [10.36] 22 | [1.289] | b0 ← X 23 | 75490.4 Z | ||||||
↳Price, 1938; missing citation | ||||||||||||
b1 3Π1 | (75195) 15 | (2900) | (79) | [9.87] 22 | [1.320] | b1 ← X R | 75142.6 Z | |||||
↳Price, 1938; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
b2 3Π2 | [76322.2] 15 | [9.18] 22 | [1.369] | b2 ← X 23 R | 74839.9 Z | |||||||
↳Price, 1938; missing citation | ||||||||||||
A (1Π) 24 25 | A ← X | |||||||||||
↳Datta and Banerjee, 1941; Romand, 1949 | ||||||||||||
X 1Σ+ | 0 | 2990.9463 26 | 52.8186 27 | 0.22437 | 10.593416 26 28 | 0.307181 29 | 5.3194E-4 28 30 | 1.274552 31 32 | ||||
↳Rank, Eastman, et al., 1962; Rank, Rao, et al., 1965 | ||||||||||||
Rotation spectrum 33 34 | ||||||||||||
↳Hansler and Oetjen, 1953; Jones and Gordy, 1964; Rosenberg, Lightman, et al., 1972 | ||||||||||||
Raman cross sections | ||||||||||||
↳Kaiser, 1970; de Leeuw and Dymanus, 1973 | ||||||||||||
Mol. beam electric reson. 35 | ||||||||||||
↳Kaiser, 1970; de Leeuw and Dymanus, 1973 | ||||||||||||
Mol. beam magnetic reson. 36 | ||||||||||||
↳Code, Khosla, et al., 1968 |
Notes
1 | Rydberg series corresponding to excitation of a 2p electron. |
2 | v=0...5 observed. Assigned as 3pσ3pπ4 5sσ. 39 |
3 | Assigned as 3pσ3pπ4 4pσ/π. 39 |
4 | Many other absorption bands in the region 83000 - 93000 cm-1 corresponding to Rydberg states strongly perturbed by the V 1Σ+ state which itself gives rise to many perturbed bands. |
5 | Average B, D values; B(R,P)-B(Q) = +0.385. |
6 | Configuration ...σ2π3 4pπ. |
7 | Average B, D values; B(1+)-B(1-) = - 0.060. |
8 | Refers to Δ+; Q branch not resolved. |
9 | Configuration ...σ2π3 4pσ. |
10 | Average B, D values; B(Π+)-B(Π-) = +0.063. |
11 | Average B, D values; B(Π+)-B(Π-) = -0.040. |
12 | Average B, D values; B(Δ+)-B(Δ-) = -0.030. |
13 | Average B, D values; B(Π+)-B(Π-) = -0.160. |
14 | Average B, D values; B(Π+)-B(Π-) = -0.667. |
15 | Configuration σ2π3 4sσ. |
16 | v=1,2,3 are increasingly diffuse; B1 = 9.296. Tilford, Ginter, et al., 1970 give ωe = 2817.5, ωexe = 66.0, Be = 9.44, αe = 0.15. |
17 | A1so observed in inert matrices Boursey, 1975. |
18 | Typica1 "V" state with configuration ... σπ4 σ*. |
19 | missing note |
20 | Very extended progression in absorption, not yet analyzed in detail. The higher vibrational levels are strongly perturbed by Rydberg states Tilford and Ginter, 1971, Douglas and Greening, 1979. The vibrational and rotational constants given were obtained from the emission spectrum with v≤3 Jacques, 1959, Jacques and Barrow, 1959 but because of the perturbations have only very limited meaning. |
21 | Continuous absorption starting at 44000 cm-1, maximum 40 at 65500 cm-1. |
22 | Diffuse rotational structure; 1-0 and 2-0 are increasingly diffuse. |
23 | The b2←X and b0←X components have only 1/50 of the intensity of b1←X. |
24 | Configuration ...σ2π3 σ*. |
25 | Continuous aabsorption starting at 44000 cm-1, maximum at 65500 cm-1. |
26 | Applying the Dunham corrections Rank, Rao, et al., 1965 obtain ωe = 2991.0904 and Be = 10.593553. Additional corrections (adiabatic, non- adiabatic) discussed by Bunker, 1972. Vibrational levels up to v=5 have been observed in infrared absorption Rank, Birtley, et al., 1960, Rank, Eastman, et al., 1962, Rank, Rao, et al., 1965 and emission Mould, Price, et al., 1960, higher levels in the V→X bands Jacques, 1959, Jacques and Barrow, 1959. Dunham potential coefficients Ogilvie and Koo, 1976. Most recent ab initio values of the ground state molecular constants Meyer and Rosmus, 1975; charge distribution Cade, Bader, et al., 1969. |
27 | ωeze = -0.01218 Rank, Rao, et al., 1965. |
28 | Slightly different constants in Plyler and Tidwell, 1960, Levy, Rossi, et al., 1965, Levy, Rossi, et al., 1966. These papers and Webb and Rao, 1968 give also constants for H37Cl. |
29 | +0.0017724(v+1/2)2 - 0.0001201(v+1/2)3. |
30 | -7.510E-6(v+1/2) + 4.00E-7(v+1/2)2; higher order terms in Rank, Rao, et al., 1965. See also Herman and Asgharian, 1966. |
31 | Uncorrected value from the Be(=Y01) given in the table. The internuclear distance at the minimum of the Born-Oppenheimer curve is re = 1.2746149 Bunker, 1972, Watson, 1973. |
32 | Rot.-vibr. Bands 41 34 |
33 | Absolute intensity measurements Chamberlain and Gebbie, 1965, Sanderson, 1967. |
34 | Pressure-induced shifts (by foreign gases) of rotation-vibration and rotation lines Rank, Eastman, et al., 1960, Ben-Reuven, Kimel, et al., 1961, Gebbie and Stone, 1963, Jaffe, Friedmann, et al., 1963, Jaffe, Hirshfeld, et al., 1964. For discussions of pressure-induced bands and pure rotation lines (ΔJ=2) see Atwood, Vu, et al., 1967, Weiss and Cole, 1967. Self and foreign-gas line broadening Benedict, Herman, et al., 1956, Babrov, Ameer, et al., 1959, Goldring and Benesch, 1962, Jaffe, Kimel, et al., 1962, Plyler and Thibault, 1962, Alamichel and Legay, 1966, Levy, Mariel-Piollet, et al., 1970, Toth, Hunt, et al., 1970, Rich and Welsh, 1971, Rosenberg, Lightman, et al., 1972. Infrared absorption in liquid and solid phases Katz and Ron, 1970, Khatibi and Vu, 1972. |
35 | μel(v=0,1,2)= 1.1085, 1.1390, 1.1685 D, respectively Kaiser, 1970. Dipole moment function Kaiser, 1970, Smith, 1973; see also Bunker, 1973, Kaiser, 1974. gJ = 0.4594, also quadrupole and other hyperfine coupling constants Kaiser, 1970, de Leeuw and Dymanus, 1973; see also Tokuhiro, 1967, Bunker, 1973. |
36 | Proton spin - rotation interaction constant Leavitt, Baker, et al., 1961, Code, Khosla, et al., 1968. |
37 | From D00(H2), D00(Cl2), and ΔHof0(HCl) |
38 | From the photoelectron spectrum Frost, McDowell, et al., 1967, Lempka, Passmore, et al., 1968, Weiss, Lawrence, et al., 1970; photoionization measurements give similar results Watanabe, Nakayama, et al., 1962, Nicholson, 1965. A somewhat smaller I.P.(12.730 eV) may be derived from the second band system in the photoelectron spectrum at 16.254 eV corresponding to A 2Σ+ of HCl+. Higher ionization potentials at 207.1 and 208.7 eV correspond to the removal of a 2p electron Hayes and Brown, 1972. |
39 | Strongly broadened by preionization (lifetime τ= 1.1E-14 s) Terwilliger and Smith, 1973. |
40 | Absorption coefficient k=40. |
41 | Absolute intensities (cm-2atm-1) of the 1-0 band: 130 Benedict, Herman, et al., 1956 2-0 band: 2.9 Benedict, Herman, et al., 1956 3.70 Jaffe, Kimel, et al., 1962, Toth, Hunt, et al., 1970 3-0 band: 0.023 Benedict, Herman, et al., 1956 |
References
Go To: Top, Gas phase thermochemistry data, IR Spectrum, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Hayes and Brown, 1972
Hayes, W.; Brown, F.C.,
Absorption by some molecular gases in the extreme ultraviolet,
Phys. Rev. A: Gen. Phys., 1972, 6, 21. [all data]
Schwarz, 1975
Schwarz, W.H.E.,
Interpretation of the core electron excitation spectra of hydride molecules and the properties of hydride radicals,
Chem. Phys., 1975, 11, 217. [all data]
Terwilliger and Smith, 1973
Terwilliger, D.T.; Smith, A.L.,
Analysis of autoionizing Rydberg states in the vacuum ultraviolet absorption spectrum of HCl and DCl,
J. Mol. Spectrosc., 1973, 45, 366. [all data]
Douglas and Greening, 1979
Douglas; Greening,
Unpublished cited in Huber and Herzberg, 1979, 1979, 287. [all data]
Tilford, Ginter, et al., 1970
Tilford, S.G.; Ginter, M.L.; Vanderslice, J.T.,
Electronic spectra and structure of the hydrogen halides. The b3Πi and C1Π states of HCl and DCl,
J. Mol. Spectrosc., 1970, 33, 505. [all data]
Jacques, 1959
Jacques,
D. Phil. Thesis, Oxford, 1959, 1. [all data]
Jacques and Barrow, 1959
Jacques, J.K.; Barrow, R.F.,
The transition v1Σ+-x1Σ+ in hydrogen chloride,
Proc. Phys. Soc. London, 1959, 73, 538. [all data]
Price, 1938
Price, W.C.,
The absorption spectra of the halogen acids in the vacuum ultra-violet,
Proc. Roy. Soc. (London), 1938, A167, 216. [all data]
Datta and Banerjee, 1941
Datta, S.; Banerjee, S.,
The continuous absorption spectra of the hydrogen-halides. Part II. HCl,
Proc. Natl. Inst. Sci. India, 1941, 7, 305. [all data]
Romand, 1949
Romand, J.,
Absorption ultraviolette dans la region de Schumann etude de: ClH, BrH et lH gazeux,
Ann. Phys. (Paris), 1949, 4, 527. [all data]
Rank, Eastman, et al., 1962
Rank, D.H.; Eastman, D.P.; Rao, B.S.; Wiggins, T.A.,
Rotational and vibrational constants of the HCl35 and DCl35 molecules,
J. Opt. Soc. Am., 1962, 52, 1. [all data]
Rank, Rao, et al., 1965
Rank, D.H.; Rao, B.S.; Wiggins, T.A.,
Molecular constants of HCl35,
J. Mol. Spectrosc., 1965, 17, 122. [all data]
Hansler and Oetjen, 1953
Hansler, R.L.; Oetjen, R.A.,
The infrared spectra of HCl, DCl, HBr, and NH3 in the region from 40 to 140 microns,
J. Chem. Phys., 1953, 21, 1340. [all data]
Jones and Gordy, 1964
Jones, G.; Gordy, W.,
Extension of submillimeter wave spectroscopy below a half-millimeter wavelength,
Phys. Rev., 1964, 135, 295. [all data]
Rosenberg, Lightman, et al., 1972
Rosenberg, A.; Lightman, A.; Ben-Reuven, A.,
Interferometric measurements of the pure rotational spectra of HCl and DCl,
J. Quant. Spectrosc. Radiat. Transfer, 1972, 12, 219. [all data]
Kaiser, 1970
Kaiser, E.W.,
Dipole moment and hyperfine parameters of H35Cl and D35Cl,
J. Chem. Phys., 1970, 53, 1686. [all data]
de Leeuw and Dymanus, 1973
de Leeuw, F.H.; Dymanus, A.,
Magnetic properties and molecular quadrupole moment of HF and HCl by molecular-beam electric-resonance spectroscopy,
J. Mol. Spectrosc., 1973, 48, 427. [all data]
Code, Khosla, et al., 1968
Code, R.F.; Khosla, A.; Ozier, I.; Ramsey, N.F.; Yi, P.N.,
Nuclear magnetic hyperfine spectra of H35Cl and H37Cl,
J. Chem. Phys., 1968, 49, 1895. [all data]
Boursey, 1975
Boursey, E.,
Electronic excitation of HCl trapped in inert matrices,
J. Chem. Phys., 1975, 62, 3353. [all data]
Tilford and Ginter, 1971
Tilford, S.G.; Ginter, M.L.,
Electronic spectra and structure of the hydrogen halides: states associated with the (σ2π3) cπ and (σ2π3) cσ configurations of HCl and DCl,
J. Mol. Spectrosc., 1971, 40, 568. [all data]
Bunker, 1972
Bunker, P.R.,
On the breakdown of the Born-Oppenheimer approximation for a diatomic molecule,
J. Mol. Spectrosc., 1972, 5, 478. [all data]
Rank, Birtley, et al., 1960
Rank, D.H.; Birtley, W.B.; Eastman, D.P.; Rao, B.S.; Wiggins, T.A.,
Precise measurements of some infrared bands of hydrogen chloride,
J. Opt. Soc. Am., 1960, 50, 1275. [all data]
Mould, Price, et al., 1960
Mould, H.M.; Price, W.C.; Wilkinson, G.R.,
Infra-red emission from gases excited by a radio-frequency discharge,
Spectrochim. Acta, 1960, 16, 479. [all data]
Ogilvie and Koo, 1976
Ogilvie, J.F.; Koo, D.,
Dunham potential energy coefficients of the hydrogen halides and carbon monoxide,
J. Mol. Spectrosc., 1976, 61, 332-336. [all data]
Meyer and Rosmus, 1975
Meyer, W.; Rosmus, P.,
PNO-Cl and CEPA studies of electron correlation effects. III. Spectroscopic constants and dipole moment functions for the ground states of the first-row and second-row diatomic hydrides,
J. Chem. Phys., 1975, 63, 2356. [all data]
Cade, Bader, et al., 1969
Cade, P.E.; Bader, R.F.W.; Henneker, W.H.; Keaveny, I.,
Molecular charge distributions and chemical binding. IV. The second-row diatomic hydrides AH,
J. Chem. Phys., 1969, 50, 5313. [all data]
Plyler and Tidwell, 1960
Plyler, E.K.; Tidwell, E.D.,
The rotational constants of hydrogen chloride,
Z. Elektrochem., 1960, 64, 717. [all data]
Levy, Rossi, et al., 1965
Levy, A.; Rossi, I.; Joffrin, C.; Van Thanh, N.,
Spectre de vibration-rotation de l'acide chlorhydrique gazeux. Etude de la bande v0→2 a 1,7 micron,
J. Chim. Phys. Phys.-Chim. Biol., 1965, 62, 600. [all data]
Levy, Rossi, et al., 1966
Levy, A.; Rossi, I.; Haeusler, C.,
Constantes de vibration-rotation de l'acide chlorhydrique gazeux etude des bandes vo→2 et vo→3,
J. Phys. (Paris), 1966, 27, 526. [all data]
Webb and Rao, 1968
Webb, D.U.; Rao, K.N.,
Vibration rotation bands of heated hydrogen halides,
J. Mol. Spectrosc., 1968, 28, 121. [all data]
Herman and Asgharian, 1966
Herman, R.M.; Asgharian, A.,
Finite nuclear mass effects on the centrifugal stretching constant in H35Cl,
J. Chem. Phys., 1966, 45, 2433. [all data]
Watson, 1973
Watson, J.K.G.,
The isotope dependence of the equilibrium rotational constants in 1Σ states of diatomic molecules,
J. Mol. Spectrosc., 1973, 45, 99. [all data]
Chamberlain and Gebbie, 1965
Chamberlain, J.E.; Gebbie, H.A.,
Sub-millimetre dispersion and rotational line strengths of the hydrogen halides,
Nature (London), 1965, 208, 480. [all data]
Sanderson, 1967
Sanderson, R.B.,
Measurement of rotational line strengths in HCl by asymmetric Fourier transform techniques,
Appl. Opt., 1967, 6, 1527. [all data]
Rank, Eastman, et al., 1960
Rank, D.H.; Eastman, D.P.; Birtley, W.B.; Wiggins, T.A.,
Perturbation of molecular rotation-vibration energy levels by rare gases,
J. Chem. Phys., 1960, 33, 323. [all data]
Ben-Reuven, Kimel, et al., 1961
Ben-Reuven, A.; Kimel, S.; Hirshfeld, M.A.; Jaffe, J.H.,
Theory and measurement of pressure-induced shifts of HCl lines due to noble gases,
J. Chem. Phys., 1961, 35, 955. [all data]
Gebbie and Stone, 1963
Gebbie, H.A.; Stone, N.W.B.,
Measurement of widths and shifts of pure rotation lines of hydrogen chloride perturbed by rare gases,
Proc. Phys. Soc. London, 1963, 82, 309. [all data]
Jaffe, Friedmann, et al., 1963
Jaffe, J.H.; Friedmann, H.; Hirshfeld, M.A.; Ben-Reuven, A.,
Pressure-induced shifts of molecular lines in emission and in absorption,
J. Chem. Phys., 1963, 39, 1447. [all data]
Jaffe, Hirshfeld, et al., 1964
Jaffe, J.H.; Hirshfeld, M.A.; Ben-Reuven, A.,
Pressure-induced shifts of DCl lines due to HCl: shift oscillation,
J. Chem. Phys., 1964, 40, 1705. [all data]
Atwood, Vu, et al., 1967
Atwood, M.R.; Vu, H.; Vodar, B.,
Forme et structures fines de la bande induite par la pression dans la bande fondamentale de vibration-rotation des molecules HF, HCl et HBr,
Spectrochim. Acta, 1967, 23, 553. [all data]
Weiss and Cole, 1967
Weiss, S.; Cole, R.H.,
Pressure-induced rotational quadrupole spectra of HCl and HBr,
J. Chem. Phys., 1967, 46, 644. [all data]
Benedict, Herman, et al., 1956
Benedict, W.S.; Herman, R.; Moore, G.E.; Silverman, S.,
The strengths, widths, and shapes of infrared lines. II. The HCl fundamental,
Can. J. Phys., 1956, 34, 850. [all data]
Babrov, Ameer, et al., 1959
Babrov, H.; Ameer, G.; Benesch, W.,
Line strengths and widths in the HCl fundamental band,
J. Mol. Spectrosc., 1959, 3, 185. [all data]
Goldring and Benesch, 1962
Goldring, H.; Benesch, W.,
Widths of HCl overtone lines at various temperatures,
Can. J. Phys., 1962, 40, 1801. [all data]
Jaffe, Kimel, et al., 1962
Jaffe, J.H.; Kimel, S.; Hirshfeld, M.A.,
Refraction spectrum of gases in the infrared intensities and widths of lines in the 2-0 band of HCl,
Can. J. Phys., 1962, 40, 113. [all data]
Plyler and Thibault, 1962
Plyler, E.K.; Thibault, R.J.,
Foreign gas broadening of the lines of hydrogen chloride and carbon monoxide,
J. Res. Nat. Bur. Stand. Sect. A, 1962, 66, 435. [all data]
Alamichel and Legay, 1966
Alamichel, C.; Legay, F.,
Etude de la dispersion dans le doublet isotopique R2 de la premiere bande harmonique de vibration-rotation de HCl,
J. Phys. (Paris), 1966, 27, 233. [all data]
Levy, Mariel-Piollet, et al., 1970
Levy, A.; Mariel-Piollet, E.; Bouanich, J.-P.; Haeusler, C.,
Spectre de vibration-rotation du gaz chlorhydrique comprime. Intensites et largeurs de raies dans la bande v0-2,
J. Quant. Spectrosc. Radiat. Transfer, 1970, 10, 203. [all data]
Toth, Hunt, et al., 1970
Toth, R.A.; Hunt, R.H.; Plyler, E.K.,
Line strengths, line widths, and dipole moment function for HCl,
J. Mol. Spectrosc., 1970, 35, 110. [all data]
Rich and Welsh, 1971
Rich, N.H.; Welsh, H.L.,
Measurement of the pressure broadening of the rotational Raman lines of HCl,
Chem. Phys. Lett., 1971, 11, 292. [all data]
Katz and Ron, 1970
Katz, B.; Ron, A.,
Far infrared spectra of HCl and DCl in a nitrogen matrix,
Chem. Phys. Lett., 1970, 7, 357. [all data]
Khatibi and Vu, 1972
Khatibi, P.; Vu, H.,
Spectres d'absorption infrarouge de HCl et de HBr en phases denses. I. Spectres dans le fondamental de vibration-rotation,
J. Chim. Phys. Phys.-Chim. Biol., 1972, 69, 654. [all data]
Smith, 1973
Smith, F.G.,
Dipole moment function and vibration-rotation matrix elements of HCl35 and DCl35,
J. Quant. Spectrosc. Radiat. Transfer, 1973, 13, 717. [all data]
Bunker, 1973
Bunker, P.R.,
The breakdown of the Born-Oppenheimer approximation for a diatomic molecule: the dipole moment and nuclear quadrupole coupling constants,
J. Mol. Spectrosc., 1973, 45, 151. [all data]
Kaiser, 1974
Kaiser, E.W.,
Note: Comment to "Dipole moment function and vibration-rotation matrix elements of HCl35 and DCl35",
J. Quant. Spectrosc. Radiat. Transfer, 1974, 14, 317. [all data]
Tokuhiro, 1967
Tokuhiro, T.,
Vibrational and rotational effects on the nuclear quadrupole coupling constants in hydrogen, deuterium, and tritium halides,
J. Chem. Phys., 1967, 47, 109. [all data]
Leavitt, Baker, et al., 1961
Leavitt, J.A.; Baker, M.R.; Nelson, H.M.; Ramsey, N.F.,
Proton radio-frequency spectrum of HCl35,
Phys. Rev., 1961, 124, 1482. [all data]
Frost, McDowell, et al., 1967
Frost, D.C.; McDowell, C.A.; Vroom, D.A.,
Photoelectron spectra of the halogens and the hydrogen halides,
J. Chem. Phys., 1967, 46, 4255. [all data]
Lempka, Passmore, et al., 1968
Lempka, H.J.; Passmore, T.R.; Price, W.C.,
The photoelectron spectra and ionized states of the halogen acids,
Proc. Roy. Soc. (London), 1968, A304, 53. [all data]
Weiss, Lawrence, et al., 1970
Weiss, M.J.; Lawrence, G.M.; Young, R.A.,
Photoelectron spectroscopy of HCI and DCI using molecular beams,
J. Chem. Phys., 1970, 52, 2867. [all data]
Watanabe, Nakayama, et al., 1962
Watanabe, K.; Nakayama, T.; Mottl, J.,
Ionization potentials of some molecules,
J. Quant. Spectry. Radiative Transfer, 1962, 2, 369. [all data]
Nicholson, 1965
Nicholson, A.J.C.,
Photoionization-efficiency curves. II. False and genuine structure,
J. Chem. Phys., 1965, 43, 1171. [all data]
Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G.,
Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules, Van Nostrand Reinhold Company, New York, 1979, 716. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, IR Spectrum, Constants of diatomic molecules, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.