HCCCCS
- Formula: C4HS
- Molecular weight: 81.116
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| To = 19980.69 | gas | A-X | 470 | 510 | Nakajima, Sumiyoshi, et al., 2002 | ||
| Reilly, Cupitt, et al., 2006 | |||||||
| Mazzotti, Achkasova, et al., 2008 | |||||||
| Mazzotti, Chauhan, et al., 2008 | |||||||
State: 2Π3/2
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 5 | CS stretch | 504 | gas | LF | Nakajima, Sumiyoshi, et al., 2002 Reilly, Cupitt, et al., 2006 | |
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 2 | 2007 | gas | LF | Reilly, Cupitt, et al., 2006 | ||
| 3 | 1910 | gas | LF | Reilly, Cupitt, et al., 2006 | |||
| 4 | 1077 | T | gas | LF | Reilly, Cupitt, et al., 2006 | ||
| 5 | CS stretch | 551 | gas | LF | Reilly, Cupitt, et al., 2006 | ||
Additional references: Jacox, 1998, page 317; Hirahara, Ohshima, et al., 1994
Notes
| T | Tentative assignment or approximate value |
| o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nakajima, Sumiyoshi, et al., 2002
Nakajima, M.; Sumiyoshi, Y.; Endo, Y.,
Laser induced fluorescence spectroscopy of the HC4S and DC4S radicals,
Chem. Phys. Lett., 2002, 351, 5-6, 359, https://doi.org/10.1016/S0009-2614(01)01400-2
. [all data]
Reilly, Cupitt, et al., 2006
Reilly, N.J.; Cupitt, G.C.; Kable, S.H.; Schmidt, T.W.,
Experimental and theoretical investigation of the dispersed fluorescence spectroscopy of HC[sub 4]S,
J. Chem. Phys., 2006, 124, 19, 194310, https://doi.org/10.1063/1.2196886
. [all data]
Mazzotti, Achkasova, et al., 2008
Mazzotti, F.J.; Achkasova, E.; Chauhan, R.; Tulej, M.; Radi, P.P.; Maier, J.P.,
Electronic spectra of radicals in a supersonic slit-jet discharge by degenerate and two-color four-wave mixing,
Phys. Chem. Chem. Phys., 2008, 10, 1, 136, https://doi.org/10.1039/b712737e
. [all data]
Mazzotti, Chauhan, et al., 2008
Mazzotti, F.J.; Chauhan, R.; Jamshidi, Z.; Tulej, M.; Radi, P.P.; Maier, J.P.,
The,
Mol. Phys., 2008, 106, 24, 2709, https://doi.org/10.1080/00268970802656984
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Hirahara, Ohshima, et al., 1994
Hirahara, Y.; Ohshima, Y.; Endo, Y.,
Pulsed-discharge-nozzle Fourier-transform microwave spectroscopy of HC3S(2Πr) and HC4S(2Πi),
J. Chem. Phys., 1994, 101, 9, 7342, https://doi.org/10.1063/1.468292
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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