Hydrogen chloride
- Formula: ClH
- Molecular weight: 36.461
- IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-N
- CAS Registry Number: 7647-01-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Hydrochloric ccid; Anhydrous hydrochloric acid; Chlorohydric acid; Hydrochloric acid gas; Hydrochloride; Muriatic acid; Salzsaeure; HCl; Hydrochloric acid, anhydrous; Hydrogen-chloride-anhydrous-; Acide chlorhydrique; Acido cloridrico; Chloorwaterstof; Chlorowodor; Chlorwasserstoff; NA 1789; Spirits of salt; UN 1050; UN 1789; UN 2186; Anhydrous hydrogen chloride; Hydrogen chloride (acid); Marine acid; Soldering acid; Spirit of salt; Spirits of salts; Hydrogen chloride (HCl); NSC 77365; Hydrochloric acid
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Phase change data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 161.15 | K | N/A | Beckmann and Waentig, 1910 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.13800 | bar | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.00006 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 324.68 | K | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.03 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 82.56 | bar | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.0824 bar; VP measured up to 219 K and Pc determined from fitted Wagner equation; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
16.2 | 188. | C | Giauque and Wiebe, 1928 | AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
122.3 to 188.3 | 3.60765 | 535.172 | -39.847 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
188.3 to 309.4 | 4.57389 | 868.358 | 1.754 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
19.7 | 127. | Ser and Larher, 1990 | Based on data from 121. to 133. K.; AC |
19.6 | 142. | Ser and Larher, 1990 | Based on data from 134. to 150. K.; AC |
IR Spectrum
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compiled by: Coblentz Society, Inc.
- GAS (200 mmHg DILUTED TO A TOTAL PRESSURE OF 600 mmHg WITH N2); DOW KBr FOREPRISM; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm-1 resolution
- GAS (200 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg); DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
Mass spectrum (electron ionization)
Go To: Top, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 18847 |
References
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Beckmann and Waentig, 1910
Beckmann, E.; Waentig, P.,
Cryoscopic Measurements at Low Temperatures,
Z. Anorg. Chem., 1910, 67, 17. [all data]
Henderson, Lewis, et al., 1986
Henderson, C.; Lewis, D.G.; Prichard, P.C.; Staveley, L.A.K.; Fonseca, I.M.A.; Lobo, L.Q.,
Some thermodynamic properties of hydrogen chloride and deuterium chloride,
J. Chem. Thermodyn., 1986, 18, 1077. [all data]
Giauque and Wiebe, 1928
Giauque, W.F.; Wiebe, R.,
THE ENTROPY OF HYDROGEN CHLORIDE. HEAT CAPACITY FROM 16°K. TO BOILING POINT. HEAT OF VAPORIZATION. VAPOR PRESSURES OF SOLID AND LIQUID,
J. Am. Chem. Soc., 1928, 50, 1, 101-122, https://doi.org/10.1021/ja01388a013
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Ser and Larher, 1990
Ser, Frederic; Larher, Yves,
Sublimation pressures of hydrogen chloride,
The Journal of Chemical Thermodynamics, 1990, 22, 4, 407-412, https://doi.org/10.1016/0021-9614(90)90129-E
. [all data]
Notes
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Pc Critical pressure Ptriple Triple point pressure Tc Critical temperature Tfus Fusion (melting) point ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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