BF3+
- Formula: BF3+
- Molecular weight: 67.806
- CAS Registry Number: 12355-91-8
- Information on this page:
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Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 47990 ± 50 | gas | Haller, Koppel, et al., 1983 | |||||
Yencha, Lopes, et al., 2002 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Lucchese, Montuoro, et al., 2010 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BF stretch | 810 ± 35 | gas | PE TPE | Haller, Koppel, et al., 1983 Haller, Koppel, et al., 1983 Mackie, Shpinkova, et al., 2003 | |
e' | 3 | BF stretch | 2040 ± 35 | gas | TPE | Yencha, Lopes, et al., 2002 Mackie, Shpinkova, et al., 2003 | |
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 35190 ± 50 | gas | Bassett and Lloyd, 1971 | |||||
Hagenow, Hottmann, et al., 1989 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Yencha, Lopes, et al., 2002 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BF stretch | 760 ± 20 | gas | PE TPE | Bassett and Lloyd, 1971 Hagenow, Hottmann, et al., 1989 Shpinkova, Holland, et al., 1999 Yencha, Lopes, et al., 2002 Mackie, Shpinkova, et al., 2003 | |
a2 | 2 | OPLA | 270 ± 35 | gas | PE TPE | Shpinkova, Holland, et al., 1999 Yencha, Lopes, et al., 2002 Mackie, Shpinkova, et al., 2003 | |
e' | 4 | Deformation | 470 ± 35 | gas | PE TPE | Shpinkova, Holland, et al., 1999 Yencha, Lopes, et al., 2002 Mackie, Shpinkova, et al., 2003 | |
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 27460 ± 50 | gas | Bassett and Lloyd, 1971 | |||||
Batten, Taylor, et al., 1978 | |||||||
Hagenow, Hottmann, et al., 1989 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Yencha, Lopes, et al., 2002 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BF stretch | 775 ± 20 | gas | PE TPE | Batten, Taylor, et al., 1978 Hagenow, Hottmann, et al., 1989 Shpinkova, Holland, et al., 1999 Yencha, Lopes, et al., 2002 Mackie, Shpinkova, et al., 2003 | |
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 12370 ± 60 | gas | Bassett and Lloyd, 1971 | |||||
Batten, Taylor, et al., 1978 | |||||||
Hagenow, Hottmann, et al., 1989 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Yencha, Lopes, et al., 2002 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BF stretch | 770 ± 60 | gas | PE | Bassett and Lloyd, 1971 Hagenow, Hottmann, et al., 1989 Shpinkova, Holland, et al., 1999 | |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 5890 ± 240 | gas | Bassett and Lloyd, 1971 | |||||
Hagenow, Hottmann, et al., 1989 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Yencha, Lopes, et al., 2002 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a2 | 2 | OPLA | 509.6 | Ne | IR | Jacox and Thompson, 1995 Jacox and Thompson, 2011 | |
e' | 3 | BF3 stretch | 1790.8 | Ne | IR | Jacox and Thompson, 1995 Jacox and Thompson, 2011 | |
4 | Deformation | 202 ± 24 | gas | TPE | Yencha, Lopes, et al., 2002 | ||
Additional references: Jacox, 1994, page 201; Jacox, 1998, page 255; Jacox, 2003, page 234; Creasey, Hatherly, et al., 1993
Notes
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Haller, Koppel, et al., 1983
Haller, E.; Koppel, H.; Cederbaum, L.S.; von Niessen, W.; Bieri, G.,
Multimode Jahn--Teller and pseudo-Jahn--Teller effects in BF+3,
J. Chem. Phys., 1983, 78, 3, 1359, https://doi.org/10.1063/1.444875
. [all data]
Yencha, Lopes, et al., 2002
Yencha, A.J.; Lopes, M.C.A.; King, G.C.,
Threshold photoelectron spectroscopy of boron trifluoride,
Chem. Phys., 2002, 279, 1, 55, https://doi.org/10.1016/S0301-0104(02)00452-4
. [all data]
Mackie, Shpinkova, et al., 2003
Mackie, R.A.; Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A.,
A study of the threshold photoelectron spectra and the photoionisation yield curves of the boron trihalides,
Chem. Phys., 2003, 288, 2-3, 211, https://doi.org/10.1016/S0301-0104(03)00025-9
. [all data]
Lucchese, Montuoro, et al., 2010
Lucchese, R.R.; Montuoro, R.; Kotsis, K.; Tashiro, M.; Ehara, M.; Bozek, J.D.; Das, A.; Landry, A.; Rathbone, J.; Poliakoff, E.D.,
The effect of vibrational motion on the dynamics of shape resonant photoionization of BF,
Mol. Phys., 2010, 108, 7-9, 1055, https://doi.org/10.1080/00268971003641866
. [all data]
Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R.,
J. Chem. Soc. A, 1971, 641. [all data]
Hagenow, Hottmann, et al., 1989
Hagenow, G.; Hottmann, K.; Baumgartel, H.,
Vibronic coupling effects observed in the high-resolution He(I) photoelectron spectra of BF3,
Chem. Phys. Lett., 1989, 164, 4, 395, https://doi.org/10.1016/0009-2614(89)85226-1
. [all data]
Shpinkova, Holland, et al., 1999
Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A.,
Mol. Phys., 1999, 96, 323. [all data]
Batten, Taylor, et al., 1978
Batten, C.F.; Taylor, J.A.; Tsai, B.P.; Meisels, G.G.,
Photoionization processes at threshold. II. Threshold photoelectron, photoionization, and coincidence ion-threshold photoelectron spectra of BF3,
J. Chem. Phys., 1978, 69, 2547. [all data]
Jacox and Thompson, 1995
Jacox, M.E.; Thompson, W.E.,
Matrix isolation study of the interaction of excited neon atoms with BF3: Infrared spectra of BF2, BF+2, BF+3, and BF-3,
J. Chem. Phys., 1995, 102, 12, 4747, https://doi.org/10.1063/1.469523
. [all data]
Jacox and Thompson, 2011
Jacox, M.E.; Thompson, W.E.,
The infrared spectra of BF3+ and BF2OH+ trapped in solid neon,
J. Chem. Phys., 2011, 134, 19, 194306, https://doi.org/10.1063/1.3587133
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Creasey, Hatherly, et al., 1993
Creasey, J.C.; Hatherly, P.A.; Jones, H.M.; Lambert, I.R.; Tuckett, R.P.,
Vacuum UV fluorescence excitation spectroscopy of BF,
Mol. Phys., 1993, 78, 4, 837, https://doi.org/10.1080/00268979300100571
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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