CH2COCH3-
- Formula: C3H5O-
- Molecular weight: 57.0717
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 14095 ± 16 | gas | Zimmerman, Reed, et al., 1977 | |||||
Ellison, Engleking, et al., 1982 | |||||||
Brinkman, Berger, et al., 2001 | |||||||
Alconcel, Deyerl, et al., 2001 | |||||||
Yacovitch, Garand, et al., 2010 | |||||||
Ichino, Villano, et al., 2011 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 13 | OCC bend | 500 ± 30 | gas | PE | Ichino, Villano, et al., 2011 | |
14 | CCC bend | 420 ± 15 | gas | PE | Ichino, Villano, et al., 2011 | ||
Notes
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I.,
Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals,
J. Am. Chem. Soc., 1977, 99, 7203. [all data]
Ellison, Engleking, et al., 1982
Ellison, G.B.; Engleking, P.C.; Lineberger, W.C.,
Photoelectron spectroscopy of alkoxide and enolate negative ions,
J. Phys. Chem., 1982, 86, 4873. [all data]
Brinkman, Berger, et al., 2001
Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I.,
J. Chem. Phys., 2001, 99, 12675. [all data]
Alconcel, Deyerl, et al., 2001
Alconcel, L.S.; Deyerl, H.-J.; Continetti, R.E.,
Effects of Alkyl Substitution on the Energetics of Enolate Anions and Radicals,
J. Am. Chem. Soc., 2001, 123, 50, 12675, https://doi.org/10.1021/ja0120431
. [all data]
Yacovitch, Garand, et al., 2010
Yacovitch, T.I.; Garand, E.; Neumark, D.M.,
Slow Photoelectron Velocity-Map Imaging of the,
J. Phys. Chem. A, 2010, 114, 42, 11091, https://doi.org/10.1021/jp101930b
. [all data]
Ichino, Villano, et al., 2011
Ichino, T.; Villano, S.M.; Gianola, A.J.; Goebbert, D.J.; Velarde, L.; Sanov, A., et al.,
Photoelectron Spectroscopic Study of the Oxyallyl Diradical,
J. Phys. Chem. A, 2011, 115, 9, 1634, https://doi.org/10.1021/jp111311k
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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