InOH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 36900 Kr A-X Douglas, Hauge, et al., 1983

State:   1A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 27188.00 gas 1A''-X 345 377 Lakin, Brown, et al., 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 829.6 ± 0.4 gas LF Lakin, Brown, et al., 1994
3 InO STretch 496.9 gas LF Lakin, Brown, et al., 1994

State:   1A'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 26914.34 gas 1A'-X 345 377 Lakin, Brown, et al., 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 820.41 ± 0.03 gas LF Lakin, Brown, et al., 1994

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OH stretch 3675.5 Ar IR Wang and Andrews, 2007
2 Bend 378 ± 2 gas LF Lakin, Brown, et al., 1994
2 Bend 421.8 Ar IR Hauge, Kauffman, et al., 1980
3 InO stretch 542 ± 5 gas LF Lakin, Brown, et al., 1994
3 InO stretch 522.8 Ar IR Hauge, Kauffman, et al., 1980
Wang and Andrews, 2007

Additional references: Jacox, 1994, page 37; Jacox, 1998, page 144; Lakin, Whitham, et al., 1996; Lakin, Varberg, et al., 1997

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., J. Chem. Soc., 1983, Faraday Trans. 1 79, 1533. [all data]

Lakin, Brown, et al., 1994
Lakin, N.M.; Brown, J.M.; Beattie, I.R.; Jones, P.J., The identification of InOH in the gas phase and determination of its geometric structure, J. Chem. Phys., 1994, 100, 11, 8546, https://doi.org/10.1063/1.466756 . [all data]

Wang and Andrews, 2007
Wang, X.; Andrews, L., Infrared Spectroscopic Observation of the Group 13 Metal Hydroxides, M(OH), J. Phys. Chem. A, 2007, 111, 10, 1860, https://doi.org/10.1021/jp066390e . [all data]

Hauge, Kauffman, et al., 1980
Hauge, R.H.; Kauffman, J.W.; Margrave, J.L., Infrared matrix-isolation studies of the interactions and reactions of Group 3A metal atoms with water, J. Am. Chem. Soc., 1980, 102, 19, 6005, https://doi.org/10.1021/ja00539a005 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Lakin, Whitham, et al., 1996
Lakin, N.M.; Whitham, C.J.; Brown, J.M., Evidence for Renner-Teller coupling in the upper, triplet electronic state of the 370 nm system of InOH, Chem. Phys. Lett., 1996, 250, 1, 9, https://doi.org/10.1016/0009-2614(95)01395-4 . [all data]

Lakin, Varberg, et al., 1997
Lakin, N.M.; Varberg, T.D.; Brown, J.M., The Detection of Lines in the Microwave Spectrum of Indium Hydroxide, InOH, and Its Isotopomers, J. Mol. Spectrosc., 1997, 183, 1, 34, https://doi.org/10.1006/jmsp.1996.7237 . [all data]

Notes

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