HN=C=NH
- Formula: CH2N2
- Molecular weight: 42.0400
- CAS Registry Number: 151-51-9
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a | 2 | NCN s-stretch | 1285 ± 20 | gas | IR | Birk and Winnewisser, 1986 | |
2 | NCN s-stretch | 1275 | Ar | IR | King and Strope, 1971 | ||
5 | NCN deform. | 537 | m | Ar | IR | King and Strope, 1971 | |
b | 7 | NCN a-stretch | 2104.7 | gas | IR | Birk and Winnewisser, 1986 | |
7 | NCN a-stretch | 2097 | s | Ar | IR | King and Strope, 1971 | |
8 | NH deform. | 890 ± 10 | gas | IR | Birk and Winnewisser, 1986 | ||
8 | NH deform. | 886 | vs | Ar | IR | King and Strope, 1971 | |
Additional references: Jacox, 1994, page 254; Jacox, 1998, page 282; Jacox, 2003, page 266; Winniwisser and Birk, 1988; Birk, Winnewisser, et al., 1989; Wagener, Winnewisser, et al., 1995; Jabs, Winnewisser, et al., 1999
Notes
m | Medium |
s | Strong |
vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Birk and Winnewisser, 1986
Birk, M.; Winnewisser, M.,
The rotation-vibration spectrum of gaseous carbodiimide (HNCNH),
Chem. Phys. Lett., 1986, 123, 5, 386, https://doi.org/10.1016/0009-2614(86)80027-6
. [all data]
King and Strope, 1971
King, S.T.; Strope, J.H.,
Infrared Spectra of the Argon Matrix-Isolated Cyanamide, Cyanamide-d2, and Carbodiimide,
J. Chem. Phys., 1971, 54, 3, 1289, https://doi.org/10.1063/1.1674967
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Winniwisser and Birk, 1988
Winniwisser, M.; Birk, M.,
J. Chem. Soc., 1988, Faraday Trans. 2 84, 1341. [all data]
Birk, Winnewisser, et al., 1989
Birk, M.; Winnewisser, M.; Cohen, E.A.,
The rotational-torsional spectrum of carbodiimide: A probe for the unusual dynamics,
J. Mol. Spectrosc., 1989, 136, 2, 402, https://doi.org/10.1016/0022-2852(89)90345-7
. [all data]
Wagener, Winnewisser, et al., 1995
Wagener, V.; Winnewisser, M.; Bellini, M.,
The rQKa, Branches of Carbodiimide, HNCNH, between 1.8 and 3.3 THz,
J. Mol. Spectrosc., 1995, 170, 2, 323, https://doi.org/10.1006/jmsp.1995.1074
. [all data]
Jabs, Winnewisser, et al., 1999
Jabs, W.; Winnewisser, M.; Belov, S.P.; Lewen, F.; Maiwald, F.; Winnewisser, G.,
The structure of carbodiimide, HNCNH,
Mol. Phys., 1999, 97, 1-2, 213, https://doi.org/10.1080/00268979909482825
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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