HOP
- Formula: HOP
- Molecular weight: 47.9811
- IUPAC Standard InChIKey: DMGNFLJBACZMRM-UHFFFAOYSA-N
- CAS Registry Number: 13817-06-6
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
OP- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1454. ± 40. | kJ/mol | D-EA | Zittel and Lineberger, 1976 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1425. ± 41. | kJ/mol | H-TS | Zittel and Lineberger, 1976 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
De-protonation reactions
OP- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1454. ± 40. | kJ/mol | D-EA | Zittel and Lineberger, 1976 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1425. ± 41. | kJ/mol | H-TS | Zittel and Lineberger, 1976 | gas phase |
Vibrational and/or electronic energy levels
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 19032.778 ± 0.007 | gas | A-X | 460 | 744 | Lam Thanh My and Peyron, 1962 | ||
Lam Thanh My and Peyron, 1963 | |||||||
Lam Thanh My and Peyron, 1964 | |||||||
Larzilliere, 1979 | |||||||
Larzilliere, 1980 | |||||||
Tackett and Clouthier, 2002 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | PH stretch | 1848.5 | gas | LF | Tackett and Clouthier, 2002 | |
2 | Bend | 565.6 | gas | EM LF | Larzilliere, 1979 Tackett and Clouthier, 2002 | ||
3 | PO stretch | 857.7 | gas | EM LF | Larzilliere, 1979 Tackett and Clouthier, 2002 | ||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | PH stretch | 2059 | gas | LF | Tackett and Clouthier, 2002 | |
1 | PH stretch | 2095 | m s | Ar | IR | Larzilliere and Jacox, 1980 | |
2 | Bend | 985.54 ± 0.03 | gas | EM LF | Lam Thanh My and Peyron, 1963 Larzilliere, 1980 Tackett and Clouthier, 2002 | ||
2 | Bend | 998.0 | w | Ar | IR | Withnall and Andrews, 1987 | |
3 | PO stretch | 1188.04 ± 0.03 | gas | EM LF | Lam Thanh My and Peyron, 1963 Larzilliere, 1980 Tackett and Clouthier, 2002 | ||
3 | PO stretch | 1188 | s | Ar | IR | Larzilliere and Jacox, 1980 | |
Additional references: Jacox, 1994, page 46; Saito, Endo, et al., 1986; Ozeki and Saito, 2003
Notes
w | Weak |
m | Medium |
s | Strong |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zittel and Lineberger, 1976
Zittel, P.F.; Lineberger, W.C.,
Laser photoelectron spectrometry of PO-, PH-, and PH2-,
J. Chem. Phys., 1976, 65, 1236. [all data]
Lam Thanh My and Peyron, 1962
Lam Thanh My; Peyron, M.,
J. Chim. Phys., 1962, 59, 688. [all data]
Lam Thanh My and Peyron, 1963
Lam Thanh My; Peyron, M.,
J. Chim. Phys., 1963, 60, 1289. [all data]
Lam Thanh My and Peyron, 1964
Lam Thanh My; Peyron, M.,
J. Chim. Phys., 1964, 61, 1531. [all data]
Larzilliere, 1979
Larzilliere, M.,
N. Damany, 1979, and Lam Thanh My, Can J. Phys. 57, 539. [all data]
Larzilliere, 1980
Larzilliere, M.,
N. Damany, 1980, and Lam Thanh My, Chem. Phys. 46, 401. [all data]
Tackett and Clouthier, 2002
Tackett, B.S.; Clouthier, D.J.,
HPO does not follow Walsh's rules! Improved molecular structures from the spectroscopy of jet-cooled HPO and DPO,
J. Chem. Phys., 2002, 117, 23, 10604, https://doi.org/10.1063/1.1521130
. [all data]
Larzilliere and Jacox, 1980
Larzilliere, M.; Jacox, M.E.,
Infrared and ultraviolet absorption spectra of PO and HPO isolated in an argon matrix,
J. Mol. Spectrosc., 1980, 79, 1, 132, https://doi.org/10.1016/0022-2852(80)90298-2
. [all data]
Withnall and Andrews, 1987
Withnall, R.; Andrews, L.,
FTIR spectra of the photolysis products of the phosphine-ozone complex in solid argon,
J. Phys. Chem., 1987, 91, 4, 784, https://doi.org/10.1021/j100288a008
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Saito, Endo, et al., 1986
Saito, S.; Endo, Y.; Hirota, E.,
The microwave spectrum of an unstable molecule, HPO,
J. Chem. Phys., 1986, 84, 3, 1157, https://doi.org/10.1063/1.450505
. [all data]
Ozeki and Saito, 2003
Ozeki, H.; Saito, S.,
Microwave spectra of HPO and DPO: molecular structure,
J. Mol. Spectrosc., 2003, 219, 2, 305, https://doi.org/10.1016/S0022-2852(03)00052-3
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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