Lead oxide
- Formula: OPb
- Molecular weight: 223.2
- IUPAC Standard InChIKey: YEXPOXQUZXUXJW-UHFFFAOYSA-N
- CAS Registry Number: 1317-36-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: lead monoxide
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Gas phase ion energetics data
Go To: Top, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 9.1 ± 0.1 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.7220 ± 0.0060 | LPES | Polak, Gilles, et al., 1993 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.4 ± 0.3 | EI | Makarov and Zbezhneva, 1993 | LL |
9.5 ± 0.4 | EI | Semenikhin, Rykov, et al., 1983 | LBLHLM |
9.08 ± 0.10 | EI | Zmbov and Miletic, 1978 | LLK |
9.1 ± 0.5 | EI | Uy and Drowart, 1969 | RDSH |
9.0 ± 0.5 | EI | Drowart, Colin, et al., 1965 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Pb+ | 11. ± 1. | O | EI | Uy and Drowart, 1969 | RDSH |
Constants of diatomic molecules
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through July, 1977
Symbol | Meaning |
---|---|
State | electronic state and / or symmetry symbol |
Te | minimum electronic energy (cm-1) |
ωe | vibrational constant – first term (cm-1) |
ωexe | vibrational constant – second term (cm-1) |
ωeye | vibrational constant – third term (cm-1) |
Be | rotational constant in equilibrium position (cm-1) |
αe | rotational constant – first term (cm-1) |
γe | rotation-vibration interaction constant (cm-1) |
De | centrifugal distortion constant (cm-1) |
βe | rotational constant – first term, centrifugal force (cm-1) |
re | internuclear distance (Å) |
Trans. | observed transition(s) corresponding to electronic state |
ν00 | position of 0-0 band (units noted in table) |
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Fragments of two further absorption systems in the region 54800 - 57500 cm-1; not fully published. | ||||||||||||
↳Barrow, 1970 | ||||||||||||
G | 51661 | 540.5 H | 6 | G ← X R | 51570 H | |||||||
↳Barrow, 1970 | ||||||||||||
F | 51153 | 558.5 H | 3 | F ← X R | 51072 H | |||||||
↳Barrow, 1970 | ||||||||||||
E 0+ | 34454 | 454 H | 7 | (0.239) 1 | (0.0014) | (2.18) | E ↔ X R | 34320 H | ||||
↳missing citation; Barrow, Deutsch, et al., 1961 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
D 1 | 30198.7 | 530.5 H | 2.92 | 0.2711 2 3 | 0.0031 | (0.28E-6) | 2.046 | D ↔ X 4 R | 30103.5 H | |||
↳Howell, 1936; missing citation; Barrow, Deutsch, et al., 1961; missing citation | ||||||||||||
C' 1 | 24947 | 494 H | 3.0 | 0.248 5 | 0.0018 | (0.25E-6) | 2.14 | C' ← X R | 24833 H | |||
↳Howell, 1936; Barrow, Deutsch, et al., 1961; Barrow, 1970 | ||||||||||||
C 0+ | 23820 | 532 6 H | 3.9 | 0.254 | 0.002 | (0.25E-6) | 2.11 | C ← X R | 23725 H | |||
↳Howell, 1936; Barrow, Deutsch, et al., 1961; Barrow, 1970 | ||||||||||||
B 1 | 22285 | 498.0 7 H | 2.20 | 0.2646 8 3 | 0.0026 | (0.30E-6) | 2.071 | B ↔ X 9 10 R | 22173.4 H | |||
↳Howell, 1936; Barrow, Deutsch, et al., 1961; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
A 0+ | 19862.6 | 444.3 11 H | 0.54 11 | 0.25869 3 | 0.00138 | (0.33E-6) | 2.0946 | A ↔ X 9 4 R | 19725.0 H | |||
↳Bloomenthal, 1930; missing citation; Barrow, Deutsch, et al., 1961; Linton and Broida, 1976 | ||||||||||||
b 0- (3Σ+) | (16454) | (441) | b → X R | 16315 H | ||||||||
↳Oldenborg, Dickson, et al., 1975; Kurylo, Braun, et al., 1976 | ||||||||||||
a 1 (3Σ+) | 16024.9 | 481.5 H | 2.45 | (0.252) | (2.12) | a → X R | 15905.4 H | |||||
↳missing citation; Kurylo, Braun, et al., 1976; missing citation | ||||||||||||
X 1Σ+ | 0 | 721.0 H | 3.54 12 | 0.3073056 3 | 0.0019148 | (0.223E-6) | 1.921813 13 | |||||
↳Torring, 1964 | ||||||||||||
Matrix IR sp. | ||||||||||||
↳Ogden and Ricks, 1972 |
Notes
1 | Strong perturbations make the constants for this state somewhat uncertain. For 206Pb0. Be = 0.2421 Barrow, 1970, αe = 0.0026 Barrow, 1970. |
2 | Perturbations in v=0 Ram, Singh, et al., 1973. |
3 | RKR potential functions Nair, Singh, et al., 1965. |
4 | Franck-Condon factors Nicholls, Fraser, et al., 1959. |
5 | Barrow, 1970 quotes Be = 0.2491 Barrow, 1970 (extrapololated from v=6,7) for 206PbO. |
6 | The vibrational numbering of Howell, 1936 has been increased by 2. |
7 | Vibrational constants from Howell, 1936; Barrow, Deutsch, et al., 1961 give ωe = 493.5 Barrow, Deutsch, et al., 1961, ωexe= 2.26 Barrow, Deutsch, et al., 1961. Irregular vibrational intervals. |
8 | Rotational perturbations in v=1 Ram, Singh, et al., 1973. |
9 | Lifetimes τ[B(v=0,1)] = 2.58 μs Oldenborg, Dickson, et al., 1975; τ[A(v=2)] = 3.75 μs Oldenborg, Dickson, et al., 1975. |
10 | Relative intensities Dube, Upadhya, et al., 1970; transition probabilities Dube, 1971. |
11 | Constants derived from band heads with v' ≤ 6 Linton and Broida, 1976, in good agreement with results quoted by Barrow, 1970 from an unpublished thesis by Travis (rotational analysis of v=0... 3 of 206PbO) but considerably smaller than earlier values (ωe = 451.7, ωexe = 3.33) proposed by Bloomenthal, 1930. |
12 | Ground state levels observed to v=l5 Linton and Broida, 1976. |
13 | Microwave sp. 15 |
14 | Thermochemical value (mass-spectrometry) Drowart, Colin, et al., 1965. From the Pb + O3 chemiluminescence spectrum under single-collision conditions Oldenborg, Dickson, et al., 1975 derive D00 ≥ 3.74 eV. |
15 | Stark effect, μel(v=0) = 4.64 D Hoeft, Lovas, et al., 1969. Zeeman effect, gJ(v=0) = -0.1623 Honerjager and Tischer, 1973. |
References
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Polak, Gilles, et al., 1993
Polak, M.L.; Gilles, M.K.; Gunion, R.F.; Lineberger, W.C.,
Photoelectron Spectroscopy of PbO-,
Chem. Phys. Lett., 1993, 210, 1-3, 55, https://doi.org/10.1016/0009-2614(93)89099-4
. [all data]
Makarov and Zbezhneva, 1993
Makarov, A.V.; Zbezhneva, S.G.,
Use of high-temperature mass spectrometry for analysis of the vapour phase of some substances used in film deposition,
Vysokochist. Veshchestva, 1993, 1, 124. [all data]
Semenikhin, Rykov, et al., 1983
Semenikhin, V.I.; Rykov, A.N.; Sidorov, L.N.,
Mass spectrometric study of the evaporation of lead monoxide,
Russ. J. Phys. Chem., 1983, 47, 1008, In original 1663. [all data]
Zmbov and Miletic, 1978
Zmbov, K.F.; Miletic, M.,
Mass spectrometric determination of the dissociation energy of PbO2 and ionization potentials of PbO and PbO2 molecules,
Adv. Mass Spectrom., 1978, 7, 573. [all data]
Uy and Drowart, 1969
Uy, O.M.; Drowart, J.,
Mass spectrometric determination of the dissociation energies of the molecules BiO, BiS, BiSe and BiTe,
J. Chem. Soc. Faraday Trans., 1969, 65, 3221. [all data]
Drowart, Colin, et al., 1965
Drowart, J.; Colin, R.; Exsteen, G.,
Mass spectrometric study of the vaporization of lead monoxide. Dissociation energy of PbO,
J. Chem. Soc. Faraday Trans., 1965, 61, 1376. [all data]
Barrow, 1970
Barrow,
In Rosen, 1970, 1970, 320. [all data]
Barrow, Deutsch, et al., 1961
Barrow, R.F.; Deutsch, J.L.; Travis, D.N.,
Rotational analysis of absorption bands of lead monoxide,
Nature (London), 1961, 191, 374. [all data]
Howell, 1936
Howell, H.G.,
The absorption spectrum of lead oxide (PbO),
Proc. R. Soc. London A, 1936, 153, 683. [all data]
Bloomenthal, 1930
Bloomenthal, S.,
Vibrational quantum analysis and isotope effect for the lead oxide band spectra,
Phys. Rev., 1930, 35, 34. [all data]
Linton and Broida, 1976
Linton, C.; Broida, H.P.,
Chemiluminescent spectra of PbO from reactions of Pb atoms,
J. Mol. Spectrosc., 1976, 62, 396. [all data]
Oldenborg, Dickson, et al., 1975
Oldenborg, R.C.; Dickson, C.R.; Zare, R.N.,
A new electronic band system of PbO,
J. Mol. Spectrosc., 1975, 58, 283. [all data]
Kurylo, Braun, et al., 1976
Kurylo, M.J.; Braun, W.; Abramowitz, S.; Krauss, M.,
A study of the chemiluminescence of the Pb + O3 reactions,
J. Res. Nat. Bur. Stand. Sect. A, 1976, 80, 167. [all data]
Torring, 1964
Torring, T.,
Das Mikrowellenrotationsspektrum des Bleimonoxids,
Z. Naturforsch. A, 1964, 19, 1426. [all data]
Ogden and Ricks, 1972
Ogden, J.S.; Ricks, M.J.,
Matrix Isolation Studies of Group IV Oxides. IV. Infrared Spectra and Structures of PbO, Pb2O2, and Pb4O4,
J. Chem. Phys., 1972, 56, 4, 1658, https://doi.org/10.1063/1.1677422
. [all data]
Ram, Singh, et al., 1973
Ram, R.S.; Singh, J.; Upadhya, K.N.,
Structure and analysis of some bands of the B → X and D → X systems of PbO,
Spectrosc. Lett., 1973, 6, 9, 515-540. [all data]
Nair, Singh, et al., 1965
Nair, K.P.R.; Singh, R.B.; Rai, D.K.,
Potential-energy curves and dissociation energies of oxides and sulfides of group IV A elements,
J. Chem. Phys., 1965, 43, 3570. [all data]
Nicholls, Fraser, et al., 1959
Nicholls, R.W.; Fraser, P.A.; Jarmain, W.R.,
Transition probability parameters of molecular spectra arising from combustion processes,
Combust. Flame, 1959, 3, 13. [all data]
Dube, Upadhya, et al., 1970
Dube, P.S.; Upadhya, K.N.; Rai, D.K.,
Electronic transition-moment variation in the B1-X1Σ+ system of PbO and determination of the effective vibrational temperature,
J. Quant. Spectrosc. Radiat. Transfer, 1970, 10, 1191. [all data]
Dube, 1971
Dube, P.S.,
Einstein coefficient oscillator strength and the lifetime measurement in the B1 - X1Σ system of PbO,
Curr. Sci., 1971, 40, 32. [all data]
Hoeft, Lovas, et al., 1969
Hoeft, J.; Lovas, F.J.; Tiemann, E.; Tischer, R.; Torring, T.,
Elektrisches Dipolmoment und Mikrowellenrotationsspektrum von SnO, SnS, PbO und PbS,
Z. Naturforsch. A, 1969, 24, 1222. [all data]
Honerjager and Tischer, 1973
Honerjager, R.; Tischer, R.,
gJ-Faktor der Molekeln SnO und PbO und Anisotropie ihrer magnetischen Suszeptibilitat,
Z. Naturforsch. A, 1973, 28, 1372. [all data]
Rosen, 1970
Rosen, B.,
International tables of selected constants. 17. Spectroscopic data relative to diatomic molecules, Pub. Pergamon Press, Oxford, 1970, 0. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.