Al(CO)2
- Formula: C2AlO2
- Molecular weight: 83.0017
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 1 | CO s-stretch | 2001.9 | Ne | IR | Kong, Chen, et al., 2002 | |
| 1 | CO s-stretch | 1995.3 | m | Ar | IR | Xu, Manceron, et al., 1993 Feltrin, Guido, et al., 1995 Zhang, Dong, et al., 2000 | |
| 1 | CO s-stretch | 1988.7 | Ar | IR | Xu, Manceron, et al., 1993 Feltrin, Guido, et al., 1995 Zhang, Dong, et al., 2000 | ||
| 1 | CO s-stretch | 1988 | Kr | IR | Hinchliffe, Ogden, et al., 1972 | ||
| 1 | CO s-stretch | 2003.0 | N2 | IR | Feltrin, Guido, et al., 1995 | ||
| 497.0 | w | Ar | IR | Xu, Manceron, et al., 1993 | |||
| b1 | Wag | 234.7 | w | Ar | IR | Xu, Manceron, et al., 1993 | |
| b2 | CO a-stretch | 1916.6 | Ne | IR | Kong, Chen, et al., 2002 | ||
| CO a-stretch | 1907.6 | vs | Ar | IR | Xu, Manceron, et al., 1993 Feltrin, Guido, et al., 1995 Zhang, Dong, et al., 2000 | ||
| CO a-stretch | 1891.0 | Ar | IR | Xu, Manceron, et al., 1993 Feltrin, Guido, et al., 1995 Zhang, Dong, et al., 2000 | |||
| CO a-stretch | 1890 | Kr | IR | Hinchliffe, Ogden, et al., 1972 | |||
| CO a-stretch | 1912.8 | N2 | IR | Feltrin, Guido, et al., 1995 | |||
| AlCO deform. | 281.0 | w | Ar | IR | Xu, Manceron, et al., 1993 | ||
Additional references: Jacox, 2003, page 291
Notes
| w | Weak |
| m | Medium |
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kong, Chen, et al., 2002
Kong, Q.; Chen, M.; Dong, J.; Li, Z.; Fan, K.; Zhou, M.,
Matrix Infrared Spectrum and Aromaticity of the Al,
J. Phys. Chem. A, 2002, 106, 48, 11709, https://doi.org/10.1021/jp026351c
. [all data]
Xu, Manceron, et al., 1993
Xu, C.; Manceron, L.; Perchard, J.P.,
J. Chem. Soc., 1993, Faraday Trans. 89, 1291. [all data]
Feltrin, Guido, et al., 1995
Feltrin, A.; Guido, M.; Nunziante Cesaro, S.,
Fourier transform infrared study and matrix effects of aluminum and gallium carbonyls isolated in argon and nitrogen,
Vib. Spectrosc., 1995, 8, 2, 175, https://doi.org/10.1016/0924-2031(94)00042-F
. [all data]
Zhang, Dong, et al., 2000
Zhang, L.; Dong, J.; Zhou, M.; Qin, Q.,
The AlCO[sup -] and Al(CO)[sub 2][sup -] anions: Matrix isolation infrared spectra and density functional theory studies,
J. Chem. Phys., 2000, 113, 22, 10169, https://doi.org/10.1063/1.1322363
. [all data]
Hinchliffe, Ogden, et al., 1972
Hinchliffe, A.J.; Ogden, J.S.; Oswald, D.D.,
J. Chem. Soc., 1972, Chem. Commun. 388. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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