NiNN
- Formula: N2Ni
- Molecular weight: 86.7068
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | NN stretch | 2089.2 | vs | Ar | IR Ra | Huber, Kundig, et al., 1973 Klotzbucher and Ozin, 1975 Andrews, Citra, et al., 1998 Manceron, Alikhani, et al., 1998 |
| Π | 2 | Bend | 357.0 | w | Ar | IR | Manceron, Alikhani, et al., 1998 |
| Σ+ | 3 | NiN stretch | 563.7 | w m | Ar | IR | Andrews, Citra, et al., 1998 Manceron, Alikhani, et al., 1998 |
Additional references: Jacox, 2003, page 73
Notes
| w | Weak |
| m | Medium |
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Huber, Kundig, et al., 1973
Huber, H.; Kundig, E.P.; Moskovits, M.; Ozin, G.A.,
Binary transition metal dinitrogen complexes. I. Matrix infrared and Raman spectra, structure and bonding of Ni(N2)n and Pd(N2)m(n = 1-4 and m = 1-3),
J. Am. Chem. Soc., 1973, 95, 2, 332, https://doi.org/10.1021/ja00783a007
. [all data]
Klotzbucher and Ozin, 1975
Klotzbucher, W.; Ozin, G.A.,
Binary transition metal dinitrogen complexes. III. Metal-nitrogen stretching modes of Ni(N2)n, Pd(N2)m, and Pt(N2)m (where n = 1-4 and m = 1-3),
J. Am. Chem. Soc., 1975, 97, 10, 2672, https://doi.org/10.1021/ja00843a014
. [all data]
Andrews, Citra, et al., 1998
Andrews, L.; Citra, A.; Chertihin, G.V.; Bare, W.D.; Neurock, M.,
Reactions of Laser-Ablated Co and Ni Atoms with Nitrogen Atoms and Molecules. Infrared Spectra and DFT Calculations of Metal Nitride Molecular Species and Complexes,
J. Phys. Chem. A, 1998, 102, 15, 2561, https://doi.org/10.1021/jp9802836
. [all data]
Manceron, Alikhani, et al., 1998
Manceron, L.; Alikhani, M.E.; Joly, H.A.,
Infrared matrix isolation and DFT study of NiN2,
Chem. Phys., 1998, 228, 1-3, 73, https://doi.org/10.1016/S0301-0104(97)00339-X
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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