Dimethylzinc

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas13.2 ± 1.4kcal/molReviewMartinho Simões 
Δfgas12.6 ± 0.31kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid6.0 ± 1.4kcal/molReviewMartinho SimõesMS
Δfliquid5.38 ± 0.31kcal/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcliquid-482.8 ± 1.4kcal/molCC-SBLong and Norrish, 1949Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid48.18cal/mol*KN/ASheiman, Nistratov, et al., 1984DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
30.88298.15Sheiman, Nistratov, et al., 1984T = 5 to 300 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple230.13KN/ASheiman, Nistratov, et al., 1984, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δvap7.27 ± 0.05kcal/molCC-SBSokolovskii and Baev, 1984Another value for the enthalpy of vaporization has been reported: 7.05 ± 0.1 kcal/mol Long and Cattanach, 1961.; MS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
7.27 ± 0.02273. to 313.N/ABaev, 1997AC
7.15283.BGBamford, Levi, et al., 1946Based on data from 248. to 318. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.63230.1Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
1.21210.3Domalski and Hearing, 1996CAL
7.094230.1

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.2536210.26crystaline, IIcrystaline, ISheiman, Nistratov, et al., 1984DH
1.632230.13crystaline, IliquidSheiman, Nistratov, et al., 1984DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
1.21210.26crystaline, IIcrystaline, ISheiman, Nistratov, et al., 1984DH
7.091230.13crystaline, IliquidSheiman, Nistratov, et al., 1984DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.00 ± 0.02PIDistefano and Dibeler, 1970RDSH
8.86 ± 0.15EIWinters and Kiser, 1967RDSH
9.4PECreber and Bancroft, 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+15.1 ± 0.5?EIWinters and Kiser, 1967RDSH
CH3Zn+10.22 ± 0.02CH3PIDistefano and Dibeler, 1970RDSH
CH3Zn+11.2 ± 0.2CH3EIWinters and Kiser, 1967RDSH
ZnH+13.9 ± 0.4?EIWinters and Kiser, 1967RDSH
Zn+13.13 ± 0.022CH3PIDistefano and Dibeler, 1970RDSH
Zn+13.4 ± 0.32CH3EIWinters and Kiser, 1967RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Norrish, 1949
Long, L.H.; Norrish, R.G.W., Phil. Trans. Roy. Soc. (London), 1949, A241, 587. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Sheiman, Nistratov, et al., 1984
Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Rabinovich, I.B., Low-temperature heat capacity of organic compounds of aluminum and zinc, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, 1984, 2, 457-459. [all data]

Sheiman, Nistratov, et al., 1984, 2
Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Rabinovich, I.B., Low-temperature heat capacity of organic compounds of aluminum and zinc in Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, Akad. Nauk SSSS Inst. Khim. Fiz.: Chernogolovka, USSR, Vol. 2 2, 1984. [all data]

Sokolovskii and Baev, 1984
Sokolovskii, A.E.; Baev, A.K., Zh. Obshch. Khim., 1984, 54, 103. [all data]

Long and Cattanach, 1961
Long, L.H.; Cattanach, J., J. Inorg. Nucl. Chem., 1961, 20, 340. [all data]

Baev, 1997
Baev, A.K., Thermodynamic study of structural changes in solutions of dimethyl-zinc with methyl compounds of Group VIB elements, Zh. Neorg. Khim., 1997, 42, 4, 662. [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., 91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V, J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H., Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References