Sulfur dioxide
- Formula: O2S
- Molecular weight: 64.064
- IUPAC Standard InChIKey: RAHZWNYVWXNFOC-UHFFFAOYSA-N
- CAS Registry Number: 7446-09-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Sulfurous acid anhydride; Fermenicide powder; Fermenticide liquid; Sulfur oxide (SO2); Sulfurous anhydride; Sulfurous oxide; SO2; Sulphur dioxide; Fermenicide liquid; Schwefeldioxyd; Siarki dwutlenek; Sulfur oxide; UN 1079; Sulfur dioxide (SO2); Sulfur superoxide
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 102
- Ion clustering data
- IR Spectrum
- Mass spectrum (electron ionization)
- Gas Chromatography
- Fluid Properties
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Gas phase thermochemistry data
Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -70.939 ± 0.048 | kcal/mol | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
ΔfH°gas | -70.946 | kcal/mol | Review | Chase, 1998 | Data last reviewed in June, 1961 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 59.327 ± 0.012 | cal/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
S°gas,1 bar | 59.324 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1961 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1200. | 1200. to 6000. |
---|---|---|
A | 5.122011 | 13.73850 |
B | 17.77030 | 0.241235 |
C | -13.80310 | -0.018234 |
D | 3.909021 | 0.001237 |
E | 0.020729 | -0.966874 |
F | -73.08050 | -77.53681 |
G | 60.91950 | 72.36611 |
H | -70.94699 | -70.94699 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in June, 1961 | Data last reviewed in June, 1961 |
Phase change data
Go To: Top, Gas phase thermochemistry data, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 200.75 | K | N/A | Hoffman and Vanderwerf, 1946 | Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 197.64 | K | N/A | Giauque and Stephenson, 1938 | Uncertainty assigned by TRC = 0.05 K; Temp. Scale based on T0 = 273.10 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.0165 | atm | N/A | Giauque and Stephenson, 1938 | Uncertainty assigned by TRC = 0.000066 atm; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 430.34 | K | N/A | Travers and Usher, 1906 | Uncertainty assigned by TRC = 0.4 K; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
5.95 | 263. | N/A | Giauque and Stephenson, 1938, 2 | Based on data from 200. to 263. K.; AC |
5.95 | 263. | C | Giauque and Stephenson, 1938, 2 | AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
177.7 to 263. | 3.48015 | 668.225 | -72.252 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
263. to 414.9 | 4.37227 | 966.575 | -42.071 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Henry's Law data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
1.4 | 2900. | L | N/A | |
1.5 | 3200. | Q | N/A | Only the tabulated data between T = 273. K and T = 303. K from missing citation was used to derive kH and -Δ kH/R. Above T = 303. K the tabulated data could not be parameterized by equation (reference missing) very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by missing citation. The quantities A and α from missing citation were assumed to be identical. |
1.2 | 3100. | C | N/A | |
1.2 | 3200. | C | N/A | |
1.2 | 3100. | T | N/A | |
1.2 | 3100. | Q | N/A | missing citation refer to several references in their list of Henry's law constants but they don't assign them to specific species. |
1.3 | 3100. | N/A | N/A | |
1.2 | 3200. | X | N/A | The value is taken from the compilation of solubilities by W. Asman (unpublished). |
1.2 | X | N/A | Value given here as quoted by missing citation. | |
1.2 | C | N/A | ||
1.3 | 2800. | X | N/A | |
1.2 | 3000. | L | N/A | |
1.4 | 2800. | L | N/A | |
1.2 | 3100. | X | N/A | The value is taken from the compilation of solubilities by W. Asman (unpublished). |
1.1 | c | N/A | ||
1.2 | 3100. | c | N/A | |
1.2 | 3200. | X | N/A | The value is taken from the compilation of solubilities by W. Asman (unpublished). |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to O2S+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 12.349 ± 0.001 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 160.7 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 153.8 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.1070 ± 0.0080 | LPES | Nimlos and Ellison, 1986 | B |
1.097 ± 0.036 | LPES | Celotta, Bennett, et al., 1974 | B |
1.10 ± 0.10 | TDEq | Chowdhury, Heinis, et al., 1986 | ΔGea(423 K) = -26.1 kcal/mol; ΔSea (estimated) = +2.0 eu. Original: Caldwell and Kebarle, 19842. Not direct measurement, but anchor for extensiveEA equilibrium scale. See text.; B |
1.10 ± 0.20 | IMRB | Grabowski, VanDoren, et al., 1984 | B |
1.04998 | Endo | Refaey and Franklin, 1976 | B |
1.00 ± 0.10 | Endo | Hughes, Lifschitz, et al., 1973 | B |
1.00 ± 0.050 | PD | Feldman, 1970 | B |
1.06 ± 0.10 | IMRB | Kraus, Muller-Duysing, et al., 1961 | Between NH2-, C-; B |
1.14 ± 0.15 | NBIE | Rothe, Tang, et al., 1975 | B |
Gas basicity at 298K
Gas basicity (review) (kcal/mol) | Reference | Comment |
---|---|---|
<149. | Milligan, Fairley, et al., 1998 | Irreversible PT from SO2H+ to C2N2 shows GB(SO2) < GB(C2N2), and using GB(C2N2) for reference from this paper; MM |
<145. | Milligan, Fairley, et al., 1998 | Irreversible PT from SO2H+ to C2H2 shows GB(SO2) < (GB(C2H2) + 4.5 kcal/mol); MM |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
12.5 ± 0.1 | EI | Snow and Thomas, 1990 | LL |
12.3494 ± 0.0002 | PE | Wang, Lee, et al., 1987 | LBLHLM |
12.5 ± 0.3 | EI | Orient and Srivastava, 1984 | LBLHLM |
12.4 ± 0.2 | EI | Smith and Stevenson, 1981 | LLK |
12.3 | PE | Lloyd and Roberts, 1973 | LLK |
12.31 | PE | Bock, Solouki, et al., 1973 | LLK |
12.30 ± 0.01 | PE | Eland and Danby, 1968 | RDSH |
12.32 ± 0.01 | PI | Dibeler and Liston, 1968 | RDSH |
12.34 | S | Golomb, Watanabe, et al., 1962 | RDSH |
12.34 ± 0.02 | PI | Watanabe, 1957 | RDSH |
12.50 | PE | Kimura, Katsumata, et al., 1981 | Vertical value; LLK |
12.54 | PE | Kroner, Strack, et al., 1973 | Vertical value; LLK |
12.50 | PE | Chadwick, Frost, et al., 1973 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
O+ | 23.5 ± 0.5 | SO | EI | Orient and Srivastava, 1984 | LBLHLM |
O+ | 20.6 | SO | EI | Reese, Dibeter, et al., 1958 | RDSH |
OS+ | 16.5 ± 0.5 | O | EI | Orient and Srivastava, 1984 | LBLHLM |
OS+ | 16.2 ± 0.2 | O | EI | Smith and Stevenson, 1981 | LLK |
OS+ | 15.930 ± 0.005 | O | PE | Weiss, Hsieh, et al., 1979 | LLK |
SO+ | 15.81 ± 0.02 | O | PI | Dibeler and Liston, 1968 | RDSH |
O2+ | 17.5 ± 0.3 | S | EI | Reese, Dibeter, et al., 1958 | RDSH |
S+ | 16.5 ± 0.5 | O2/2O | EI | Orient and Srivastava, 1984 | LBLHLM |
S+ | 22. | 2O | EI | Smith and Stevenson, 1981 | LLK |
S+ | 16.334 | O2/2O | PE | Weiss, Hsieh, et al., 1979 | LLK |
S+ | 17.5 ± 0.3 | O2 | EI | Reese, Dibeter, et al., 1958 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Hoffman and Vanderwerf, 1946
Hoffman, K.R.; Vanderwerf, C.A.,
Addition Compounds of Sulfur Dioxide with Pyridine and the Picolines,
J. Am. Chem. Soc., 1946, 68, 997. [all data]
Giauque and Stephenson, 1938
Giauque, W.F.; Stephenson, C.C.,
Sulfur Dioxide. The Heat Capacity of Solid and Liquid. Vapor Pressure. Heat of Vap. The Entropy Values from Termal and Molecular Data,
J. Am. Chem. Soc., 1938, 60, 1389. [all data]
Travers and Usher, 1906
Travers, M.W.; Usher, F.L.,
The behavior of certain substance at the critical point,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1906, 57, 365-81. [all data]
Giauque and Stephenson, 1938, 2
Giauque, W.F.; Stephenson, C.C.,
Sulfur Dioxide. The Heat Capacity of Solid and Liquid. Vapor Pressure. Heat of Vaporization. The Entropy Values from Thermal and Molecular Data,
J. Am. Chem. Soc., 1938, 60, 6, 1389-1394, https://doi.org/10.1021/ja01273a034
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B.,
Photoelectron spectroscopy of SO2-, S3-, and S2O-,
J. Phys. Chem., 1986, 90, 2574. [all data]
Celotta, Bennett, et al., 1974
Celotta, R.S.; Bennett, R.A.; Hall, J.L.,
Laser Photodetachment Determination of the Electron Affinities of OH, NH2, NH, SO2, and S2,
J. Chem. Phys., 1974, 60, 5, 1740, https://doi.org/10.1063/1.1681268
. [all data]
Chowdhury, Heinis, et al., 1986
Chowdhury, S.; Heinis, T.; Grimsrud, E.P.; Kebarle, P.,
Entropy Changes and Electron Affinities from Gas-Phase Electron Transfer Equilibria: A- + B = A + B-,
J. Phys. Chem., 1986, 90, 12, 2747, https://doi.org/10.1021/j100403a037
. [all data]
Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P.,
Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements,
J. Am. Chem. Soc., 1984, 106, 967. [all data]
Grabowski, VanDoren, et al., 1984
Grabowski, J.J.; VanDoren, J.M.; DePuy, C.H.; Bierbaum, V.M.,
Flowing Afterglow Studies of the Electron Affinity of SO2,
J. Chem. Phys., 1984, 80, 1, 575, https://doi.org/10.1063/1.446412
. [all data]
Refaey and Franklin, 1976
Refaey, K.M.A.; Franklin, J.L.,
Endoergic ion-molecule-collision processes of negative ions. I. Collision of I- on SO2,
J. Chem. Phys., 1976, 65, 1994. [all data]
Hughes, Lifschitz, et al., 1973
Hughes, B.M.; Lifschitz, C.; Tiernan, T.O.,
Electron affinities from endothermic negative-ion charge-transfer reactions. III. NO, NO2, S2, CS2, Cl2, Br2, I2, and C2H,
J. Chem. Phys., 1973, 59, 3162. [all data]
Feldman, 1970
Feldman, D.,
Photoablosung von Elektronen bei einigen Stabilen Negativen Ionen,
Z. Naturfor., 1970, 25A, 621. [all data]
Kraus, Muller-Duysing, et al., 1961
Kraus, K.; Muller-Duysing, W.; Neuert, H.,
Uber Stosse Langsamer Negativer Ionen mit Ladungsubertragung,
Z. Naturfor., 1961, 16A, 1385. [all data]
Rothe, Tang, et al., 1975
Rothe, E.W.; Tang, S.Y.; Reck, G.P.,
Measurement of electron affinities of O3, SO2, and SO3 by collisional ionization,
J. Chem. Phys., 1975, 62, 3829. [all data]
Milligan, Fairley, et al., 1998
Milligan, D.B.; Fairley, D.A.; Meot-Ner (Mautner), M.; McEwan, M.J.,
Proton affinity of cyanogen and association reactions of C2N2H+ and C2N2CH3+,
Int. J. Mass Spectrom., 1998, 180, 285. [all data]
Snow and Thomas, 1990
Snow, K.B.; Thomas, T.F.,
Mass spectrum, ionization potential, and appearance potentials for fragment ions of sulfuric acid vapor,
Int. J. Mass Spectrom. Ion Processes, 1990, 96, 49. [all data]
Wang, Lee, et al., 1987
Wang, L.; Lee, Y.T.; Shirley, D.A.,
Molecular beam photoelectron spectroscopy of SO2: Geometry, spectroscopy, and dynamics of SO2,
J. Chem. Phys., 1987, 87, 2489. [all data]
Orient and Srivastava, 1984
Orient, O.J.; Srivastava, S.K.,
Mass spectrometric determination of partial and total electron impact ionization cross sections of SO2 from threshold up to 200 eV,
J. Chem. Phys., 1984, 80, 140. [all data]
Smith and Stevenson, 1981
Smith, O.I.; Stevenson, J.S.,
Determination of cross sections for formation of parent and fragment ions by electron impact from SO2 and SO3,
J. Chem. Phys., 1981, 74, 6777. [all data]
Lloyd and Roberts, 1973
Lloyd, D.R.; Roberts, P.J.,
The assignment of the photoelectron spectrum of sulphur dioxide,
Mol. Phys., 1973, 26, 225. [all data]
Bock, Solouki, et al., 1973
Bock, H.; Solouki, B.; Rosmus, P.; Steudel, R.,
Photoelectron spectra and molecular properties: SSO and OSO,
Angew. Chem. Int. Ed. Engl., 1973, 12, 933. [all data]
Eland and Danby, 1968
Eland, J.H.D.; Danby, C.J.,
Photoelectron spectra and ionic structure of carbon dioxide, carbon disulphide and sulphur dioxide,
Intern. J. Mass Spectrom. Ion Phys., 1968, 1, 111. [all data]
Dibeler and Liston, 1968
Dibeler, V.H.; Liston, S.K.,
Mass-spectrometric study of photoionization. XI.Hydrogen sulfide and sulfur dioxide,
J. Chem. Phys., 1968, 49, 482. [all data]
Golomb, Watanabe, et al., 1962
Golomb, D.; Watanabe, K.; Marmo, F.F.,
Absorption coefficients of sulfur dioxide in the vacuum ultraviolet,
J. Chem. Phys., 1962, 36, 958. [all data]
Watanabe, 1957
Watanabe, K.,
Ionization potentials of some molecules,
J. Chem. Phys., 1957, 26, 542. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]
Kroner, Strack, et al., 1973
Kroner, J.; Strack, W.; Holsboer, F.; Kosbahn, W.,
Zur elektronenstruktur der thiokumulene,
Z. Naturforsch. B:, 1973, 28, 188. [all data]
Chadwick, Frost, et al., 1973
Chadwick, D.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N.,
Photoelectron spectra of sulfuryl and thionyl halides,
Can. J. Chem., 1973, 51, 1893. [all data]
Reese, Dibeter, et al., 1958
Reese, R.M.; Dibeter, V.H.; Franklin, J.L.,
Electron impact studies of sulfur dioxide and sulfuryl fluoride,
J. Chem. Phys., 1958, 29, 880. [all data]
Weiss, Hsieh, et al., 1979
Weiss, M.J.; Hsieh, T.-C.; Meisels, G.G.,
Fragmentation of SO2+ prepared in state selected vibrational levels,
J. Chem. Phys., 1979, 71, 567. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy Ptriple Triple point pressure S°gas,1 bar Entropy of gas at standard conditions (1 bar) Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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