Nitrosyl hydride
- Formula: HNO
- Molecular weight: 31.0140
- IUPAC Standard InChIKey: ODUCDPQEXGNKDN-UHFFFAOYSA-N
- CAS Registry Number: 14332-28-6
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 23.80 | kcal/mol | Review | Chase, 1998 | Data last reviewed in March, 1993 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 52.753 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1993 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1200. | 1200. to 6000. |
---|---|---|
A | 4.746501 | 12.48960 |
B | 11.47430 | 0.742321 |
C | -6.073292 | -0.142961 |
D | 1.251110 | 0.009537 |
E | 0.054999 | -1.781081 |
F | 22.11050 | 16.24260 |
G | 55.64529 | 62.91900 |
H | 23.80000 | 23.80000 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in March, 1993 | Data last reviewed in March, 1993 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
View reactions leading to HNO+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.338 ± 0.015 | LPES | Ellis and Ellison, 1983 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.1 | DER | Lias, Bartmess, et al., 1988 | LL |
De-protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 361.27 ± 0.15 | kcal/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 354.68 ± 0.34 | kcal/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Ellis and Ellison, 1983
Ellis, H.B., Jr.; Ellison, G.B.,
Photoelectron spectroscopy of HNO- and DNO-,
J. Chem. Phys., 1983, 78, 6541. [all data]
Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G.,
Gas-phase ion and neutral thermochemistry,
J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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