Dimolybdenum hexakis(dimethylamide)
- Formula: C12H36Mo2N6
- Molecular weight: 456.37
- CAS Registry Number: 51956-20-8
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 30.6 ± 2.9 | kcal/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 4.0 ± 2.2 | kcal/mol | Review | Martinho Simões |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 27. ± 2. | kcal/mol | C | Adedeji, Cavell, et al., 1979 | See also Cavell, Connor, et al., 1981.; AC |
ΔsubH° | 26.5 ± 1.9 | kcal/mol | RSC | Adedeji, Cavell, et al., 1979 | MS |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C12H36Mo2N6+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.74 | PE | Bursten, Cotton, et al., 1980 | Vertical value; LLK |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Adedeji, Cavell, et al., 1979
Adedeji, F.A.; Cavell, K.J.; Cavell, S.; Connor, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T.,
J. Chem. Soc. Faraday Trans. 1, 1979, 75, 603. [all data]
Cavell, Connor, et al., 1981
Cavell, K.J.; Connor, J.A.; Pilcher, G.; Ribeiro da Silva, M.A.V.; Ribiero da Silva, D.M.C.; Vipmani, Y.; Zafarani-Moattar, M.T.,
J. Chem. Soc. Faraday Trans. 1, 1981, 77, 1585. [all data]
Bursten, Cotton, et al., 1980
Bursten, B.E.; Cotton, F.A.; Green, J.C.; Seddon, E.A.; Stanley, G.G.,
Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 1. The d3-d3 Mo2L6 compounds (L = OR, NR2, CH2R),
J. Am. Chem. Soc., 1980, 102, 4579. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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