Dimolybdenum hexakis(dimethylamide)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas30.6 ± 2.9kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid4.0 ± 2.2kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub27. ± 2.kcal/molCAdedeji, Cavell, et al., 1979See also Cavell, Connor, et al., 1981.; AC
Δsub26.5 ± 1.9kcal/molRSCAdedeji, Cavell, et al., 1979MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C12H36Mo2N6+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
6.74PEBursten, Cotton, et al., 1980Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Adedeji, Cavell, et al., 1979
Adedeji, F.A.; Cavell, K.J.; Cavell, S.; Connor, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1979, 75, 603. [all data]

Cavell, Connor, et al., 1981
Cavell, K.J.; Connor, J.A.; Pilcher, G.; Ribeiro da Silva, M.A.V.; Ribiero da Silva, D.M.C.; Vipmani, Y.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1981, 77, 1585. [all data]

Bursten, Cotton, et al., 1980
Bursten, B.E.; Cotton, F.A.; Green, J.C.; Seddon, E.A.; Stanley, G.G., Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 1. The d3-d3 Mo2L6 compounds (L = OR, NR2, CH2R), J. Am. Chem. Soc., 1980, 102, 4579. [all data]


Notes

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