Acetylene

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Gas phase thermochemistry data

Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas226.73kJ/molReviewChase, 1998Data last reviewed in March, 1961
Δfgas227.4 ± 0.8kJ/molReviewManion, 2002adopted recommendation of Gurvich, Veyts, et al., 1991; DRB
Δfgas226.7 ± 0.79kJ/molCcbWagman, Kilpatrick, et al., 1945Unpublished work of E. J. Prosen; ALS
Quantity Value Units Method Reference Comment
gas,1 bar200.93J/mol*KReviewChase, 1998Data last reviewed in March, 1961

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
29.35100.Gurvich, Veyts, et al., 1989p=1 bar.; GT
35.57200.
44.04298.15
44.17300.
50.39400.
54.75500.
58.12600.
60.97700.
63.51800.
65.83900.
67.961000.
69.911100.
71.691200.
73.301300.
74.761400.
76.081500.
77.271600.
78.351700.
79.321800.
80.211900.
81.012000.
81.742100.
82.412200.
83.032300.
83.602400.
84.122500.
84.612600.
85.062700.
85.492800.
85.892900.
86.263000.

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 1100.1100. to 6000.
A 40.6869767.47244
B 40.7327911.75110
C -16.17840-2.021470
D 3.6697410.136195
E -0.658411-9.806418
F 210.7067185.4550
G 235.0052253.5337
H 226.7314226.7314
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1961 Data last reviewed in March, 1961

Phase change data

Go To: Top, Gas phase thermochemistry data, Henry's Law data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil189.KN/ABuckingham and Donaghy, 1982BS
Tboil189.6KN/AMaass and Wright, 1921Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tfus171.65KN/AMorehouse and Maass, 1931Uncertainty assigned by TRC = 0.5 K; TRC
Tfus191.4KN/AMaass and Russell, 1918Uncertainty assigned by TRC = 1. K; TRC
Tfus191.65KN/AMcIntosh, 1907Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple192.4KN/AClark and Din, 1950Uncertainty assigned by TRC = 0.5 K; TRC
Ttriple191.35KN/AMaass and Wright, 1921Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Ptriple1.2825barN/AClark and Din, 1950Uncertainty assigned by TRC = 0.0039 bar; TRC
Quantity Value Units Method Reference Comment
Tc308.3 ± 0.1KN/ATsonopoulos and Ambrose, 1996 
Tc308.35KN/AGoloborod'ko and Khodeeva, 1972Visual, as Goloborod'ko and Khodeeva Zh.Fiz.Khim. 1969,43,1340; TRC
Tc308.66KN/AKhodeeva, 1966TRC
Tc309.7KN/AMaass and Wright, 1921Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Pc61.38 ± 0.10barN/ATsonopoulos and Ambrose, 1996 
Quantity Value Units Method Reference Comment
Vc0.1122l/molN/ATsonopoulos and Ambrose, 1996 
Vc0.113l/molN/AKhodeeva, 1966Visual, samples thoroughly purified; TRC
Quantity Value Units Method Reference Comment
ρc8.91 ± 0.010mol/lN/ATsonopoulos and Ambrose, 1996 

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
16.3273.AStephenson and Malanowski, 1987Based on data from 258. to 308. K.; AC
16.7207.AStephenson and Malanowski, 1987Based on data from 192. to 308. K.; AC
16.7210.AStephenson and Malanowski, 1987Based on data from 192. to 225. K.; AC
17.0214.N/AReid, 1972AC
16.4230.N/AAmbrose and Townsend, 1964Based on data from 215. to 308. K.; AC
16.8200.N/AAmbrose, 1956Based on data from 193. to 207. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
214.64 to 308.334.66141909.0797.947Ambrose and Townsend, 1964, 2Coefficents calculated by NIST from author's data.
192.59 to 206.304.19598699.53-21.47Ambrose, 1956, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
23.5130.AStephenson and Malanowski, 1987Based on data from 98. to 145. K.; AC
21.8162.N/AJones, 1960Based on data from 133. to 191. K.; AC
25.2193.N/AAmbrose, 1956Based on data from 151. to 193. K.; AC
22.7160.AStull, 1947Based on data from 130. to 189. K.; AC
22.1129.ABurbo, 1943Based on data from 89. to 169. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
3.76192.4Miskiewicz, Rieser, et al., 2010AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
17.8142.7Miskiewicz, Rieser, et al., 1976CAL
19.5192.4

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Henry's Law data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.039 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.0411800.LN/A 
0.042 VN/A 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman

View reactions leading to C2H2+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.400 ± 0.002eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)641.4kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity616.7kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
11.41 ± 0.01EIPlessis and Marmet, 1986LBLHLM
11.40PIHayaishi, Iwata, et al., 1982LBLHLM
11.4EVALRosmus, Botschwina, et al., 1981LLK
11.40PEKimura, Katsumata, et al., 1981LLK
11.40PEBieri, Schmelzer, et al., 1980LLK
11.4 ± 0.1EISuzuki and Maeda, 1978LLK
11.4 ± 0.1EISuzuki and Maeda, 1977LLK
11.40 ± 0.02PEBieri, Burger, et al., 1977LLK
~11.3EIVan Veen and Plantenga, 1976LLK
11.37 ± 0.05EIReeher, Flesch, et al., 1976LLK
11.403 ± 0.0003PECarlier, Dubois, et al., 1975LLK
11.394 ± 0.005PIParr and Taylor, 1973LLK
11.398 ± 0.005PIDibeler and Walker, 1973LLK
11.40PEBrogli, Heilbronner, et al., 1973LLK
11.39 ± 0.02EILossing, 1970RDSH
11.395 ± 0.015PIOmura, Kaneko, et al., 1969RDSH
11.39 ± 0.05EIWilliams and Hamill, 1968RDSH
11.41 ± 0.01EICollins, Winters, et al., 1968RDSH
11.40 ± 0.01PEBaker and Turner, 1968RDSH
11.400 ± 0.005PIBrehm, 1966RDSH
11.396 ± 0.003PINicholson, 1965RDSH
11.40 ± 0.02EIMelton and Hamill, 1964RDSH
11.406 ± 0.006PIDibeler and Reese, 1964RDSH
11.41 ± 0.01PIWatanabe and Namioka, 1956RDSH
11.2 ± 0.1EIKusch, Hustrulid, et al., 1937RDSH
11.41SPrice, 1935RDSH
11.49PEBieri and Asbrink, 1980Vertical value; LLK
11.43PECavell and Allison, 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C+21.20 ± 0.05CH2EILocht and Davister, 1995LL
C+24. ± 1.?PICooper, Ibuki, et al., 1988LL
C+20.43 ± 0.05CH2EIPlessis and Marmet, 1986LBLHLM
C+22.5 ± 0.3C+2HEISuzuki and Maeda, 1977LLK
C+23.6?EIBloch, 1963RDSH
C+24.5 ± 1.0C+2HEIKusch, Hustrulid, et al., 1937RDSH
CH+20.85 ± 0.05CHEIDavister and Locht, 1995LL
CH+20.54 ± 0.05CHEIPlessis and Marmet, 1986LBLHLM
CH+23.9 ± 0.2C+HEIPlessis and Marmet, 1986LBLHLM
CH+24.1C+HPIHayaishi, Iwata, et al., 1982LBLHLM
CH+20.7 ± 0.1CHPIHayaishi, Iwata, et al., 1982LBLHLM
CH+20.9 ± 0.2CHEISuzuki and Maeda, 1977LLK
CH+21.5 ± 0.2CHEIKloster-Jensen, Pascual, et al., 1970RDSH
CH+21.9CHEIHaney and Franklin, 1968RDSH
CH+22.2 ± 0.5CHEIKusch, Hustrulid, et al., 1937RDSH
CH2+19.74 ± 0.20CEILocht and Davister, 1995LL
CH2+18.17 ± 0.09C-EIPlessis and Marmet, 1986LBLHLM
CH2+19.40 ± 0.12CEIPlessis and Marmet, 1986LBLHLM
CH2+19.4 ± 0.1CPIHayaishi, Iwata, et al., 1982LBLHLM
CH2+20.5 ± 0.2?EISuzuki and Maeda, 1977LLK
CH2+21.CEIFranklin and Munson, 1965RDSH
C2+19. ± 1.H2CIELReid, Ballantine, et al., 1995LL
C2+18.44 ± 0.07H2EILocht and Davister, 1995LL
C2+22.60 ± 0.122HEIPlessis and Marmet, 1986LBLHLM
C2+18.16 ± 0.05H2EIPlessis and Marmet, 1986LBLHLM
C2+18.1 ± 0.1H2PIHayaishi, Iwata, et al., 1982LBLHLM
C2+22.7 ± 0.12HPIHayaishi, Iwata, et al., 1982LBLHLM
C2+19.2 ± 0.2?EISuzuki and Maeda, 1977LLK
C2+23.62H?EIMomigny and Derouane, 1968RDSH
C2+19.5H2EIBloch, 1963RDSH
C2+23.82H?EIBloch, 1963RDSH
C2+22.72H?EIField, Franklin, et al., 1957RDSH
C2+18.2H2EIField, Franklin, et al., 1957RDSH
C2+23.3 ± 0.52H?EICoats and Anderson, 1957RDSH
C2+23.8 ± 0.32HEIKusch, Hustrulid, et al., 1937RDSH
C2H+17.35 ± 0.04HPIPECOServais and Locht, 1995LL
C2H+17.360HPIPECOWeitzel, Mahnert, et al., 1994LL
C2H+17.30 ± 0.08HEIDavister and Locht, 1994LL
C2H+17.33 ± 0.05HPIPECONorwood and Ng, 1989LL
C2H+16.70 ± 0.10HEIPlessis and Marmet, 1986LBLHLM
C2H+16.8 ± 0.1HPIHayaishi, Iwata, et al., 1982LBLHLM
C2H+16.79 ± 0.03HPIOno and Ng, 1981LLK
C2H+17.3HPIPECOEland, 1979LLK
C2H+17.5 ± 0.1HEISuzuki and Maeda, 1977LLK
C2H+17.36 ± 0.01HPIDibeler, Walker, et al., 1973LLK
C2H+17.22HPIBotter, Dibeler, et al., 1966RDSH
C2H+17.3HEIField, Franklin, et al., 1957RDSH
C2H+17.8 ± 0.2HEIKusch, Hustrulid, et al., 1937RDSH
H+18.83 ± 0.23C2HEIDavister and Locht, 1994LL
H+23. ± 1.?PICooper, Ibuki, et al., 1988LL
H+19.35 ± 0.05C2HPIShiromaru, Achiba, et al., 1987LBLHLM
H+20.6 ± 0.3?EISuzuki and Maeda, 1977LLK
H+21.7 ± 1.0C2+HEIKusch, Hustrulid, et al., 1937RDSH
H+25.6 ± 1.0CH+CEIKusch, Hustrulid, et al., 1937RDSH

De-protonation reactions

C2H- + Hydrogen cation = Acetylene

By formula: C2H- + H+ = C2H2

Quantity Value Units Method Reference Comment
Δr1580. ± 20.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr1550. ± 20.kJ/molAVGN/AAverage of 7 values; Individual data points

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Gurvich, Veyts, et al., 1991
Thermodynamic Properties of Individual Substances, 4th edition, Volume 2, Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.;, ed(s)., Hemisphere, New York, 1991. [all data]

Wagman, Kilpatrick, et al., 1945
Wagman, D.D.; Kilpatrick, J.E.; Pitzer, K.S.; Rossini, F.D., Heats, equilibrium constants, and free energies of formation of the acetylene hydrocarbons through the pentynes, to 1,500° K, J. Res. NBS, 1945, 35, 467-496. [all data]

Gurvich, Veyts, et al., 1989
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Thermodynamic Properties of Individual Substances, 4th ed.; Vols. 1 and 2, Hemisphere, New York, 1989. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Maass and Wright, 1921
Maass, O.; Wright, C.H., SOME PHYSICAL PROPERTIES OF HYDROCARBONS CONTAINING TWO AND THREE CARBON ATOMS., J. Am. Chem. Soc., 1921, 43, 5, 1098-1111, https://doi.org/10.1021/ja01438a013 . [all data]

Morehouse and Maass, 1931
Morehouse, F.R.; Maass, O., The Preparationa and Physical Properties of Ethyl and Methyl Acetylene, Can. J. Res., 1931, 5, 306. [all data]

Maass and Russell, 1918
Maass, O.; Russell, J., Unsaturation and molecular compound formation, J. Am. Chem. Soc., 1918, 40, 1561-1573. [all data]

McIntosh, 1907
McIntosh, D., The physical properties of liquid and solid acetylene., J. Phys. Chem., 1907, 11, 306-17. [all data]

Clark and Din, 1950
Clark, A.M.; Din, F., Equilibria Between Solid, Liquid, and Gaseous Phases at Low Temperature binary systems acetylene - carbon dioxide, acetylene - ethylene and acetylene - ethane, Trans. Faraday Soc., 1950, 46, 901. [all data]

Tsonopoulos and Ambrose, 1996
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 6. Unsaturated Aliphatic Hydrocarbons, J. Chem. Eng. Data, 1996, 41, 645-656. [all data]

Goloborod'ko and Khodeeva, 1972
Goloborod'ko, N.P.; Khodeeva, S.M., Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 235-7. [all data]

Khodeeva, 1966
Khodeeva, S.M., Visual Observation of Gas-Gas Mixture, Russ. J. Phys. Chem. (Engl. Transl.), 1966, 40, 1061-3. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Ambrose and Townsend, 1964
Ambrose, D.; Townsend, R., Vapour pressure of acetylene, Trans. Faraday Soc., 1964, 60, 1025, https://doi.org/10.1039/tf9646001025 . [all data]

Ambrose, 1956
Ambrose, D., The vapour pressures and critical temperatures of acetylene and carbon dioxide, Trans. Faraday Soc., 1956, 52, 772, https://doi.org/10.1039/tf9565200772 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Ambrose and Townsend, 1964, 2
Ambrose, D.; Townsend, R., Vapour Pressure of Acetylene, Trans. Faraday Soc., 1964, 60, 1025-1029, https://doi.org/10.1039/tf9646001025 . [all data]

Ambrose, 1956, 2
Ambrose, D., The Vapour Pressures and Critical Temperatures of Acetylene and Carbon Dioxide, Trans. Faraday Soc., 1956, 52, 772-781, https://doi.org/10.1039/tf9565200772 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Burbo, 1943
Burbo, P.Z., Russ. J. Phys. Chem., 1943, 7, 286. [all data]

Miskiewicz, Rieser, et al., 2010
Miskiewicz, Stefan; Rieser, Klaus; Dorfmüller, Thomas, Thermodynamische Untersuchungen an kondensierten Phasen, Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 80, 5, 395-405, https://doi.org/10.1002/bbpc.19760800504 . [all data]

Miskiewicz, Rieser, et al., 1976
Miskiewicz, S.; Rieser, K.; Dorfmuller, T., Thermodynamische Untersuchungen an kondensierten Phasen, Ber. Bunsen-Ges. Physik. Chem., 1976, 80, 5, 395, https://doi.org/10.1002/bbpc.19760800504 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Plessis and Marmet, 1986
Plessis, P.; Marmet, P., Electroionization study of acetylene and fragment ions, Int. J. Mass Spectrom. Ion Processes, 1986, 70, 23. [all data]

Hayaishi, Iwata, et al., 1982
Hayaishi, T.; Iwata, S.; Sasanuma, M.; Ishiguro, E.; Morioka, Y.; Iida, Y.; Nakamura, M., Photoionisation mass spectrometric study of acetylene in the VUV region, J. Phys. B:, 1982, 15, 79. [all data]

Rosmus, Botschwina, et al., 1981
Rosmus, P.; Botschwina, P.; Maier, J.P., On the ionic states of vinylidene and acetylene, Chem. Phys. Lett., 1981, 84, 71. [all data]

Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]

Bieri, Schmelzer, et al., 1980
Bieri, G.; Schmelzer, A.; Asbrink, L.; Jonsson, M., Fluorine and the fluoroderivatives of acetylene and diacetylene studied by 30.4 nm He(II) photoelectron spectroscopy, Chem. Phys., 1980, 49, 213. [all data]

Suzuki and Maeda, 1978
Suzuki, I.H.; Maeda, K., Ionization efficiency curves of acetylene by mono-energetic electron impact, Adv. Mass Spectrom., 1978, 7, 182. [all data]

Suzuki and Maeda, 1977
Suzuki, I.H.; Maeda, K., Ionization efficiency curves of acetylene by electron impact, Mass Spectrosc. (Tokyo), 1977, 25, 223. [all data]

Bieri, Burger, et al., 1977
Bieri, G.; Burger, F.; Heilbronner, E.; Maier, J.P., Valence ionization enrgies of hydrocarbons, Helv. Chim. Acta, 1977, 60, 2213. [all data]

Van Veen and Plantenga, 1976
Van Veen, E.H.; Plantenga, F.L., Low-energy electron-impact excitation spectra of acetylene, Chem. Phys. Lett., 1976, 38, 493. [all data]

Reeher, Flesch, et al., 1976
Reeher, J.R.; Flesch, G.D.; Svec, H.J., The mass spectra and ionization potentials of the neutral fragments produced during the electron bombardment of aromatic compounds, Org. Mass Spectrom., 1976, 11, 154. [all data]

Carlier, Dubois, et al., 1975
Carlier, P.; Dubois, J.E.; Masclet, P.; Mouvier, G., Spectres de photoelectrons des alcynes, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 55. [all data]

Parr and Taylor, 1973
Parr, G.R.; Taylor, J.W., A photoionization mass spectrometer utilizing a high intensity molecular beam sampling system and synchrotron radiation, Rev. Sci. Instrum., 1973, 44, 1578. [all data]

Dibeler and Walker, 1973
Dibeler, V.H.; Walker, J.A., Photoionization of acetylene near threshold, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 49. [all data]

Brogli, Heilbronner, et al., 1973
Brogli, F.; Heilbronner, E.; Hornung, V.; Kloster-Jensen, E., 230. Die photoelektronen-spektren methyl-substituierter Acetylene, Helv. Chim. Acta, 1973, 56, 2171. [all data]

Lossing, 1970
Lossing, F.P., Threshold ionization of acetylene by monoenergetic electron impact, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 190. [all data]

Omura, Kaneko, et al., 1969
Omura, I.; Kaneko, T.; Yamada, Y.; Tanaka, K., Mass spectrometric studies of photoionization. IV. Acetylene and propyne, J. Phys. Soc. Japan, 1969, 27, 178. [all data]

Williams and Hamill, 1968
Williams, J.M.; Hamill, W.H., Ionization potentials of molecules and free radicals and appearance potentials by electron impact in the mass spectrometer, J. Chem. Phys., 1968, 49, 4467. [all data]

Collins, Winters, et al., 1968
Collins, J.H.; Winters, R.E.; Engerholm, G.G., Fine structure in energy-distribution-difference ionizationefficiency curves, J. Chem. Phys., 1968, 49, 2469. [all data]

Baker and Turner, 1968
Baker, C.; Turner, D.W., High resolution molecular photoelectron spectroscopy. III.Acetylenes and azaacetylenes, Proc. Roy. Soc. (London), 1968, A308, 19. [all data]

Brehm, 1966
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Notes

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