Ethyne, 1-trimethylsilyl-
- Formula: C2H4Si
- Molecular weight: 56.1387
- IUPAC Standard InChIKey: CWMFRHBXRUITQE-UHFFFAOYSA-N
- CAS Registry Number: 1066-27-9
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
5.26 | 233. | Ebsworth and Frankiss, 1963 | Based on data from 215. to 251. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.73 | PE | Ensslin, Bock, et al., 1974 | Vertical value; LLK |
De-protonation reactions
C2H3Si- + =
By formula: C2H3Si- + H+ = C2H4Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 367.7 ± 2.3 | kcal/mol | G+TS | Gal, Decouzon, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 360.2 ± 2.0 | kcal/mol | IMRE | Gal, Decouzon, et al., 2001 | gas phase; B |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ebsworth and Frankiss, 1963
Ebsworth, E.A.V.; Frankiss, S.G.,
104. The preparation and properties of silylacetylene, and the structures of silyl cyanides,
J. Chem. Soc., 1963, 661, https://doi.org/10.1039/jr9630000661
. [all data]
Ensslin, Bock, et al., 1974
Ensslin, W.; Bock, H.; Becker, G.,
Photoelectron spectra and molecular properties. XXX. π interactions in H3Si- H3C-substituted acetylenes,
J. Am. Chem. Soc., 1974, 96, 2757. [all data]
Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C.,
Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes,
J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j
. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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