Disulfur monoxide
- Formula: OS2
- Molecular weight: 80.129
- IUPAC Standard InChIKey: TXKMVPPZCYKFAC-UHFFFAOYSA-N
- CAS Registry Number: 20901-21-7
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 10.584 ± 0.005 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.8770 ± 0.0080 | LPES | Nimlos and Ellison, 1986 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.584 ± 0.005 | PIPECO | Norwood and Ng, 1989 | LL |
10.58 ± 0.01 | PI | Berkowitz, Eland, et al., 1977 | LLK |
10.53 ± 0.02 | PE | Frost, Lee, et al., 1973 | LLK |
10.52 | PE | Bock, Solouki, et al., 1973 | LLK |
10.62 | PE | McDowell, 1972 | LLK |
10.3 ± 0.1 | EI | Hagemann, 1962 | RDSH |
10.52 | PE | Rosmus, Dacre, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
OS+ | 13.745 ± 0.006 | S | PI | Berkowitz, Eland, et al., 1977 | LLK |
SO+ | 14.5 ± 0.2 | S | EI | Hagemann, 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B.,
Photoelectron spectroscopy of SO2-, S3-, and S2O-,
J. Phys. Chem., 1986, 90, 2574. [all data]
Norwood and Ng, 1989
Norwood, K.; Ng, C.Y.,
Photoion-photoelectron coincidence spectroscopy of the transient molecules SO and S2O,
Chem. Phys. Lett., 1989, 156, 145. [all data]
Berkowitz, Eland, et al., 1977
Berkowitz, J.; Eland, J.H.D.; Appelman, E.H.,
Photoionization mass spectrometry and heat of formation of S2O,
J. Chem. Phys., 1977, 66, 2183. [all data]
Frost, Lee, et al., 1973
Frost, D.C.; Lee, S.T.; McDowell, C.A.,
The HeI photoelectron spectrum of S2O,
Chem. Phys. Lett., 1973, 22, 243. [all data]
Bock, Solouki, et al., 1973
Bock, H.; Solouki, B.; Rosmus, P.; Steudel, R.,
Photoelectron spectra and molecular properties: SSO and OSO,
Angew. Chem. Int. Ed. Engl., 1973, 12, 933. [all data]
McDowell, 1972
McDowell, C.A.,
General disscussion,
Faraday Discuss. Chem. Soc., 1972, 54, 68. [all data]
Hagemann, 1962
Hagemann, R.,
Determination de la chaleur de formation de S2O par spectrometrie de masse,
Compt. Rend., 1962, 255, 1102. [all data]
Rosmus, Dacre, et al., 1974
Rosmus, P.; Dacre, P.D.; Solouki, B.; Bock, H.,
Hartree-Fock calculations photoelectron spectra of SSO NSF,
Theor. Chim. Acta, 1974, 35, 129. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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