Nickel hydride (NiH)

• Formula: HNi
• Molecular weight: 59.7013
• CAS Registry Number: 14332-32-2
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Constants of diatomic molecules
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Ni^- +  = HNi

By formula: Ni^- + H⁺ = HNi

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman

Electron affinity determinations

Ionization energy determinations

De-protonation reactions

Ni^- +  = HNi

By formula: Ni^- + H⁺ = HNi

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through April, 1975

Notes

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scheer, Brodie, et al., 1998
Scheer, M.; Brodie, C.A.; Bilodeau, R.C.; Haugen, H.K., Laser spectroscopic measurements of binding energies and fine-structure splittings of Co-, Ni-, Rh-, and Pd-, Phys. Rev. A, 1998, 58, 3, 2051-2062, https://doi.org/10.1103/PhysRevA.58.2051 . [all data]

Miller, Feigerle, et al., 1987
Miller, A.E.S.; Feigerle, C.S.; Lineberger, W.C., Laser photoelectron spectroscopy of CrH^-, CoH^-, and NiH^-: Periodic trends in the electronic structure of the transition-metal hydrides, J. Chem. Phys., 1987, 86, 1549. [all data]

Kickel and Armentrout, 1995
Kickel, B.L.; Armentrout, P.B., Reactions of Fe⁺, Co⁺, and Ni⁺ with silane. Electronic state effects, comparison to reactions with methane, and M⁺-SiH_x (x = 0-3) bond energies, J. Am. Chem. Soc., 1995, 117, 764. [all data]

Armentrout and Kicket, 1995
Armentrout, P.B.; Kicket, B.L., Reactions of Fe⁺, Co⁺, and Ni⁺ with silane. Electronic state effects, comparison to reactions with methane, and M⁺-SiH_x (x = 0-3) bond energies, J. Am. Chem. Soc., 1995, 117, 764. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]

Smith, 1973
Smith, R.E., Diatomic hydride and deuteride spectra of the second row transition metals, Proc. R. Soc. London A, 1973, 332, 113. [all data]

Andersen, Lagerqvist, et al., 1963
Andersen, E.; Lagerqvist, A.; Neuhaus, H.; Aslund, N., Bands of NiH and NiD in the violet region of the spectrum, Proc. Phys. Soc. London, 1963, 82, 637. [all data]

Aslund, Neuhaus, et al., 1965
Aslund, N.; Neuhaus, H.; Lagerqvist, A.; Andersen, E., Rotational analysis of violet bands of NiH and NiD, Ark. Fys., 1965, 28, 271. [all data]

Heimer, 1937
Heimer, A., Dissertation, Stockholm, 1937, 0. [all data]

Heimer, 1937, 2
Heimer, A., Das rote bandenspektrum des nickelhydrids, Z. Phys., 1937, 105, 56. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  EA	Electron affinity
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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