Nickel monochloride

• Formula: ClNi
• Molecular weight: 94.146
• IUPAC Standard InChI: InChI=1S/ClH.Ni/h1H;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: GGVOVPORYPQPCE-UHFFFAOYSA-M Copy
• CAS Registry Number: 13931-83-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Nickel chloride
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • Constants of diatomic molecules
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to ClNi⁺ (ion structure unspecified)

Ionization energy determinations

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through March, 1975

Notes

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

McKinley, 1964
McKinley, J.D., Mass-spectrometric investigation of the high-temperature reaction between nickel and chlorine, J. Chem. Phys., 1964, 40, 120. [all data]

More, 1938
More, K.R., Spectra of the monochlorides of nickel, cobalt and iron, Phys. Rev., 1938, 54, 122. [all data]

Mesnage, 1939
Mesnage, P., Recherches sur les decharges de haute frequence et leur application a la spectroscopie moleculaire, Ann. Phys. (Paris), 1939, 12, 5. [all data]

Reddy and Rao, 1960
Reddy, S.P.; Rao, P.T., The band spectra of NiCl and NiBr in the visible, Proc. Phys. Soc. London, 1960, 75, 275. [all data]

Rao and Rao, 1969
Rao, N.V.K.; Rao, P.T., The emission spectrum of nickel monochloride, Curr. Sci., 1969, 38, 589. [all data]

Rao, Reddy, et al., 1962
Rao, S.V.K.; Reddy, S.P.; Rao, P.T., New band systems of NiCl in the photographic infrared, Z. Phys., 1962, 166, 261. [all data]

Bulewicz, Phillips, et al., 1961
Bulewicz, E.M.; Phillips, L.F.; Sugden, T.M., Determination of dissociation constants and heats of formation of simple molecules by flame photometry. Part 8. Stabilities of the gaseous diatomic halides of certain metals, Trans. Faraday Soc., 1961, 57, 921. [all data]

Krishnamurty, 1952
Krishnamurty, V.G., The complex band spectrum of nickel chloride (NiCl), Indian J. Phys., 1952, 26, 207. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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