Hydrogen cyanide

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Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas32.299kcal/molReviewChase, 1998Data last reviewed in December, 1969
Quantity Value Units Method Reference Comment
gas,1 bar48.236cal/mol*KReviewChase, 1998Data last reviewed in December, 1969

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1200.1200. to 6000.
A 7.81399012.51560
B 5.3996301.329660
C -1.044250-0.227826
D -0.0974420.013554
E -0.067495-1.807860
F 29.5126924.82130
G 55.7504158.51931
H 32.3000032.30000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1969 Data last reviewed in December, 1969

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

CN- + Hydrogen cyanide = (CN- • Hydrogen cyanide)

By formula: CN- + CHN = (CN- • CHN)

Quantity Value Units Method Reference Comment
Δr21.7 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Δr20.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; B
Δr20.7kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.7kcal/molPHPMSMeot-ner, 1988gas phase; M,B,B,M
Quantity Value Units Method Reference Comment
Δr20.6cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.6cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr20.6cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr26.9cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(H2O), Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Δr14.5 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Δr13.7 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Δr14.5 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Fluorine anion + Hydrogen cyanide = (Fluorine anion • Hydrogen cyanide)

By formula: F- + CHN = (F- • CHN)

Quantity Value Units Method Reference Comment
Δr39.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M
Quantity Value Units Method Reference Comment
Δr22.2cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Δr32.9 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) • Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ • CHN)

Quantity Value Units Method Reference Comment
Δr36.4kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Δr36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Δr28.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Chlorine anion + Hydrogen cyanide = (Chlorine anion • Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- • CHN)

Quantity Value Units Method Reference Comment
Δr21.8 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B,B,M
Δr21.0 ± 2.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr23.7cal/mol*KN/ALarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr16.2 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Δr16.1 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Δr13.9 ± 2.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,M

CN- + Hydrogen cation = Hydrogen cyanide

By formula: CN- + H+ = CHN

Quantity Value Units Method Reference Comment
Δr349.8 ± 1.0kcal/molCIDTAkin and Ervin, 2006gas phase; B
Δr350.50 ± 0.17kcal/molD-EABradforth, Kim, et al., 1993gas phase; B
Δr351.1 ± 2.1kcal/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Δr342.5 ± 1.1kcal/molH-TSAkin and Ervin, 2006gas phase; B
Δr343.17 ± 0.27kcal/molH-TSBradforth, Kim, et al., 1993gas phase; B
Δr343.8 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

HCO2 anion + Hydrogen cyanide = (HCO2 anion • Hydrogen cyanide)

By formula: CHO2- + CHN = (CHO2- • CHN)

Quantity Value Units Method Reference Comment
Δr22.0kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Δr21.4cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.6 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy of 22.0 eu assumed.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
11.8473.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(HCO2 anion • Hydrogen cyanide) + Hydrogen cyanide = (HCO2 anion • 2Hydrogen cyanide)

By formula: (CHO2- • CHN) + CHN = (CHO2- • 2CHN)

Quantity Value Units Method Reference Comment
Δr17.8kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Δr23.6cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10.70kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.6350.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(NH4+ • 3Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 4Hydrogen cyanide • Ammonia)

By formula: (H4N+ • 3CHN • H3N) + CHN = (H4N+ • 4CHN • H3N)

Quantity Value Units Method Reference Comment
Δr8.6kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.7292.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M

(Chlorine anion • 8Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 9Hydrogen cyanide)

By formula: (Cl- • 8CHN) + CHN = (Cl- • 9CHN)

Quantity Value Units Method Reference Comment
Δr7.5 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr0.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2171.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(MeCO2 anion • 4Hydrogen cyanide) + Hydrogen cyanide = (MeCO2 anion • 5Hydrogen cyanide)

By formula: (C2H3O2- • 4CHN) + CHN = (C2H3O2- • 5CHN)

Quantity Value Units Method Reference Comment
Δr9.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr2.40kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5213.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(CN- • 6Hydrogen cyanide) + Hydrogen cyanide = (CN- • 7Hydrogen cyanide)

By formula: (CN- • 6CHN) + CHN = (CN- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr1.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.0238.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(CN- • 2Hydrogen cyanide) + Hydrogen cyanide = (CN- • 3Hydrogen cyanide)

By formula: (CN- • 2CHN) + CHN = (CN- • 3CHN)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr12.6kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr21.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr21.2cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr6.30kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 3Hydrogen cyanide) + Hydrogen cyanide = (CN- • 4Hydrogen cyanide)

By formula: (CN- • 3CHN) + CHN = (CN- • 4CHN)

Quantity Value Units Method Reference Comment
Δr10.9kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr10.9kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr24.8cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr24.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr24.8cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • Hydrogen cyanide) + Hydrogen cyanide = (CN- • 2Hydrogen cyanide)

By formula: (CN- • CHN) + CHN = (CN- • 2CHN)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr16.4kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr21.8cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr21.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr21.8cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.90kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

CH2N+ + Hydrogen cyanide = (CH2N+ • Hydrogen cyanide)

By formula: CH2N+ + CHN = (CH2N+ • CHN)

Quantity Value Units Method Reference Comment
Δr26.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; ΔrH, ΔrS too small compared with other nitrile dimers; M
Δr30.0kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr23.0cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; ΔrH, ΔrS too small compared with other nitrile dimers; M
Δr32.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; M

(CN- • Water • 2Hydrogen cyanide) + Water = (CN- • 2Water • 2Hydrogen cyanide)

By formula: (CN- • H2O • 2CHN) + H2O = (CN- • 2H2O • 2CHN)

Quantity Value Units Method Reference Comment
Δr8.9 ± 1.0kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr2.9 ± 1.4kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.7262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • 3Hydrogen cyanide) + Water = (CN- • Water • 3Hydrogen cyanide)

By formula: (CN- • 3CHN) + H2O = (CN- • H2O • 3CHN)

Quantity Value Units Method Reference Comment
Δr9.4 ± 1.0kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr3.4 ± 1.4kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.2262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ • Hydrogen cyanide • Water) + Hydrogen cyanide = (CH2N+ • 2Hydrogen cyanide • Water)

By formula: (CH2N+ • CHN • H2O) + CHN = (CH2N+ • 2CHN • H2O)

Quantity Value Units Method Reference Comment
Δr15.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KN/AMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.4kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M

(NH4+ • Ammonia • 2Hydrogen cyanide) + Ammonia = (NH4+ • 2Ammonia • 2Hydrogen cyanide)

By formula: (H4N+ • H3N • 2CHN) + H3N = (H4N+ • 2H3N • 2CHN)

Quantity Value Units Method Reference Comment
Δr12.9kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.6315.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

(NH4+ • Hydrogen cyanide • 2Ammonia) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide • 2Ammonia)

By formula: (H4N+ • CHN • 2H3N) + CHN = (H4N+ • 2CHN • 2H3N)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.9315.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

(CN- • 4Hydrogen cyanide) + Hydrogen cyanide = (CN- • 5Hydrogen cyanide)

By formula: (CN- • 4CHN) + CHN = (CN- • 5CHN)

Quantity Value Units Method Reference Comment
Δr9.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Δr9.8kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(NH4+ • Hydrogen cyanide) + Ammonia = (NH4+ • Ammonia • Hydrogen cyanide)

By formula: (H4N+ • CHN) + H3N = (H4N+ • H3N • CHN)

Quantity Value Units Method Reference Comment
Δr18.8kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.4429.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Bromine anion + Hydrogen cyanide = (Bromine anion • Hydrogen cyanide)

By formula: Br- + CHN = (Br- • CHN)

Quantity Value Units Method Reference Comment
Δr19.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Δr16.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; Extrapolated from other halide data; B
Quantity Value Units Method Reference Comment
Δr19.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr13.5 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

C4H9O2+ + Hydrogen cyanide = (C4H9O2+ • Hydrogen cyanide)

By formula: C4H9O2+ + CHN = (C4H9O2+ • CHN)

Quantity Value Units Method Reference Comment
Δr19.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.9455.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

C3H7+ + Hydrogen cyanide = (C3H7+ • Hydrogen cyanide)

By formula: C3H7+ + CHN = (C3H7+ • CHN)

Quantity Value Units Method Reference Comment
Δr39.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Δr30.8kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+; M
Quantity Value Units Method Reference Comment
Δr45.2cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Δr32.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+; M

HS- + Hydrogen cyanide = (HS- • Hydrogen cyanide)

By formula: HS- + CHN = (HS- • CHN)

Quantity Value Units Method Reference Comment
Δr21.0 ± 1.0kcal/molIMREMeot-ner, 1988gas phase; See also H2S..CN-; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.0 ± 1.0kcal/molIMREMeot-ner, 1988gas phase; See also H2S..CN-; B

NH4+ + Hydrogen cyanide = (NH4+ • Hydrogen cyanide)

By formula: H4N+ + CHN = (H4N+ • CHN)

Quantity Value Units Method Reference Comment
Δr21.9kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Δr20.5kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Δr20.2cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

(CN- • Water • Hydrogen cyanide) + Water = (CN- • 2Water • Hydrogen cyanide)

By formula: (CN- • H2O • CHN) + H2O = (CN- • 2H2O • CHN)

Quantity Value Units Method Reference Comment
Δr9.5 ± 1.0kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr17.5cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr4.2 ± 1.4kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • 2Hydrogen cyanide) + Water = (CN- • Water • 2Hydrogen cyanide)

By formula: (CN- • 2CHN) + H2O = (CN- • H2O • 2CHN)

Quantity Value Units Method Reference Comment
Δr7.7 ± 1.0kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr12.5cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr4.0 ± 1.4kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • Hydrogen cyanide) + Water = (CN- • Water • Hydrogen cyanide)

By formula: (CN- • CHN) + H2O = (CN- • H2O • CHN)

Quantity Value Units Method Reference Comment
Δr12.4 ± 1.0kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.7cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr6.5 ± 1.4kcal/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(Chlorine anion • 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 8Hydrogen cyanide)

By formula: (Cl- • 7CHN) + CHN = (Cl- • 8CHN)

Quantity Value Units Method Reference Comment
Δr8.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr27.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.0 ± 2.2kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • Hydrogen cyanide • 2Water) + Hydrogen cyanide = (CN- • 2Hydrogen cyanide • 2Water)

By formula: (CN- • CHN • 2H2O) + CHN = (CN- • 2CHN • 2H2O)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.4262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • 2Hydrogen cyanide • Water) + Hydrogen cyanide = (CN- • 3Hydrogen cyanide • Water)

By formula: (CN- • 2CHN • H2O) + CHN = (CN- • 3CHN • H2O)

Quantity Value Units Method Reference Comment
Δr12.3kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.1262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(Chlorine anion • 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 3Hydrogen cyanide)

By formula: (Cl- • 2CHN) + CHN = (Cl- • 3CHN)

Quantity Value Units Method Reference Comment
Δr13.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 4Hydrogen cyanide)

By formula: (Cl- • 3CHN) + CHN = (Cl- • 4CHN)

Quantity Value Units Method Reference Comment
Δr11.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr4.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 2Hydrogen cyanide)

By formula: (Cl- • CHN) + CHN = (Cl- • 2CHN)

Quantity Value Units Method Reference Comment
Δr17.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr11.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 2Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 3Hydrogen cyanide)

By formula: (I- • 2CHN) + CHN = (I- • 3CHN)

Quantity Value Units Method Reference Comment
Δr11.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.0cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr4.90kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 2Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 3Hydrogen cyanide)

By formula: (Br- • 2CHN) + CHN = (Br- • 3CHN)

Quantity Value Units Method Reference Comment
Δr12.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr6.30kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 3Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 4Hydrogen cyanide)

By formula: (Br- • 3CHN) + CHN = (Br- • 4CHN)

Quantity Value Units Method Reference Comment
Δr10.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 5Hydrogen cyanide)

By formula: (Cl- • 4CHN) + CHN = (Cl- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr2.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 6Hydrogen cyanide)

By formula: (Cl- • 5CHN) + CHN = (Cl- • 6CHN)

Quantity Value Units Method Reference Comment
Δr8.7 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr24.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 7Hydrogen cyanide)

By formula: (Cl- • 6CHN) + CHN = (Cl- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.00kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 3Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 4Hydrogen cyanide)

By formula: (I- • 3CHN) + CHN = (I- • 4CHN)

Quantity Value Units Method Reference Comment
Δr9.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 4Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 5Hydrogen cyanide)

By formula: (I- • 4CHN) + CHN = (I- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 5Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 6Hydrogen cyanide)

By formula: (I- • 5CHN) + CHN = (I- • 6CHN)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 6Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 7Hydrogen cyanide)

By formula: (I- • 6CHN) + CHN = (I- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 7Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 8Hydrogen cyanide)

By formula: (I- • 7CHN) + CHN = (I- • 8CHN)

Quantity Value Units Method Reference Comment
Δr6.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 2Hydrogen cyanide)

By formula: (I- • CHN) + CHN = (I- • 2CHN)

Quantity Value Units Method Reference Comment
Δr13.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 4Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 5Hydrogen cyanide)

By formula: (Br- • 4CHN) + CHN = (Br- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.1 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.5cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr2.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 2Hydrogen cyanide)

By formula: (Br- • CHN) + CHN = (Br- • 2CHN)

Quantity Value Units Method Reference Comment
Δr16.3 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CHN+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)13.60 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)170.4kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity162.9kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.00156N/AArd, Garrett, et al., 2009B
>1.00171EIAETsuda, Yokohata, et al., 1971From CH3CN; G3MP2B3 calculations indicate that the anion is unbound by ca. 1 eV. Possibly C2H3- instead.; B

Ionization energy determinations

IE (eV) Method Reference Comment
13.71EILageot, 1972LLK
13.59 ± 0.01PIDibeler and Liston, 1968RDSH
13.60 ± 0.01PEBaker and Turner, 1968RDSH
13.73 ± 0.09EIVarsel, Morrell, et al., 1960RDSH
13.7 ± 0.1EIKusch, Hustrulid, et al., 1937RDSH
13.61PEKreile, Schweig, et al., 1982Vertical value; LBLHLM
13.607 ± 0.002PEFridh and Asbrink, 1975Vertical value; LLK
13.60PEPotts and Williams, 1974Vertical value; LLK
13.61 ± 0.01PEFrost, Lee, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C+23.8 ± 0.5?EIKusch, Hustrulid, et al., 1937RDSH
CH+21.8 ± 0.5NEIKusch, Hustrulid, et al., 1937RDSH
CN+19.43 ± 0.01HPIBerkowitz, Chupka, et al., 1969RDSH
CN+19.40 ± 0.02HPIDibeler and Liston, 1968RDSH
CN+20.1 ± 0.2HEIKusch, Hustrulid, et al., 1937RDSH
H+15.18 ± 0.02CN-PIBerkowitz, Chupka, et al., 1969RDSH
H+19.00 ± 0.01CNPIBerkowitz, Chupka, et al., 1969RDSH
NH+24.9 ± 0.5CEIKusch, Hustrulid, et al., 1937RDSH
N+25.6 ± 0.5CHEIKusch, Hustrulid, et al., 1937RDSH

De-protonation reactions

CN- + Hydrogen cation = Hydrogen cyanide

By formula: CN- + H+ = CHN

Quantity Value Units Method Reference Comment
Δr349.8 ± 1.0kcal/molCIDTAkin and Ervin, 2006gas phase; B
Δr350.50 ± 0.17kcal/molD-EABradforth, Kim, et al., 1993gas phase; B
Δr351.1 ± 2.1kcal/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Δr342.5 ± 1.1kcal/molH-TSAkin and Ervin, 2006gas phase; B
Δr343.17 ± 0.27kcal/molH-TSBradforth, Kim, et al., 1993gas phase; B
Δr343.8 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Hydrogen cyanide = (Bromine anion • Hydrogen cyanide)

By formula: Br- + CHN = (Br- • CHN)

Quantity Value Units Method Reference Comment
Δr19.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Δr16.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; Extrapolated from other halide data; B
Quantity Value Units Method Reference Comment
Δr19.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr13.5 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 2Hydrogen cyanide)

By formula: (Br- • CHN) + CHN = (Br- • 2CHN)

Quantity Value Units Method Reference Comment
Δr16.3 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 2Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 3Hydrogen cyanide)

By formula: (Br- • 2CHN) + CHN = (Br- • 3CHN)

Quantity Value Units Method Reference Comment
Δr12.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr6.30kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 3Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 4Hydrogen cyanide)

By formula: (Br- • 3CHN) + CHN = (Br- • 4CHN)

Quantity Value Units Method Reference Comment
Δr10.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion • 4Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion • 5Hydrogen cyanide)

By formula: (Br- • 4CHN) + CHN = (Br- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.1 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.5cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr2.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

HCO2 anion + Hydrogen cyanide = (HCO2 anion • Hydrogen cyanide)

By formula: CHO2- + CHN = (CHO2- • CHN)

Quantity Value Units Method Reference Comment
Δr22.0kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Δr21.4cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.6 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy of 22.0 eu assumed.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
11.8473.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(HCO2 anion • Hydrogen cyanide) + Hydrogen cyanide = (HCO2 anion • 2Hydrogen cyanide)

By formula: (CHO2- • CHN) + CHN = (CHO2- • 2CHN)

Quantity Value Units Method Reference Comment
Δr17.8kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Δr23.6cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10.70kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.6350.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

CH2N+ + Hydrogen cyanide = (CH2N+ • Hydrogen cyanide)

By formula: CH2N+ + CHN = (CH2N+ • CHN)

Quantity Value Units Method Reference Comment
Δr26.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; ΔrH, ΔrS too small compared with other nitrile dimers; M
Δr30.0kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr23.0cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; ΔrH, ΔrS too small compared with other nitrile dimers; M
Δr32.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; M

(CH2N+ • Hydrogen cyanide) + Hydrogen cyanide = (CH2N+ • 2Hydrogen cyanide)

By formula: (CH2N+ • CHN) + CHN = (CH2N+ • 2CHN)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; M

(CH2N+ • 2Hydrogen cyanide) + Hydrogen cyanide = (CH2N+ • 3Hydrogen cyanide)

By formula: (CH2N+ • 2CHN) + CHN = (CH2N+ • 3CHN)

Quantity Value Units Method Reference Comment
Δr11.8kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; M

(CH2N+ • 3Hydrogen cyanide) + Hydrogen cyanide = (CH2N+ • 4Hydrogen cyanide)

By formula: (CH2N+ • 3CHN) + CHN = (CH2N+ • 4CHN)

Quantity Value Units Method Reference Comment
Δr9.2kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; M
Quantity Value Units Method Reference Comment
Δr26.0cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; M

(CH2N+ • Hydrogen cyanide • Water) + Hydrogen cyanide = (CH2N+ • 2Hydrogen cyanide • Water)

By formula: (CH2N+ • CHN • H2O) + CHN = (CH2N+ • 2CHN • H2O)

Quantity Value Units Method Reference Comment
Δr15.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KN/AMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.4kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M

(CH2N+ • Water) + Hydrogen cyanide = (CH2N+ • Hydrogen cyanide • Water)

By formula: (CH2N+ • H2O) + CHN = (CH2N+ • CHN • H2O)

Quantity Value Units Method Reference Comment
Δr18.8kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.4cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ • 2Water) + Hydrogen cyanide = (CH2N+ • Hydrogen cyanide • 2Water)

By formula: (CH2N+ • 2H2O) + CHN = (CH2N+ • CHN • 2H2O)

Quantity Value Units Method Reference Comment
Δr16.9kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr24.1cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CH2OH+ + Hydrogen cyanide = (CH2OH+ • Hydrogen cyanide)

By formula: CH3O+ + CHN = (CH3O+ • CHN)

Quantity Value Units Method Reference Comment
Δr20.6kcal/molFATanaka, Mackay, et al., 1978gas phase; switching reaction(H2COH+)H2CO; Fehsenfeld, Dotan, et al., 1978, Cunningham, Payzant, et al., 1972; M

CH4NO+ + Hydrogen cyanide = (CH4NO+ • Hydrogen cyanide)

By formula: CH4NO+ + CHN = (CH4NO+ • CHN)

Quantity Value Units Method Reference Comment
Δr19.3kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.5427.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

CH5O+ + Hydrogen cyanide = (CH5O+ • Hydrogen cyanide)

By formula: CH5O+ + CHN = (CH5O+ • CHN)

Quantity Value Units Method Reference Comment
Δr25.7kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr22.1cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

CH6N+ + Hydrogen cyanide = (CH6N+ • Hydrogen cyanide)

By formula: CH6N+ + CHN = (CH6N+ • CHN)

Quantity Value Units Method Reference Comment
Δr20.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr22.9cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

CN- + Hydrogen cyanide = (CN- • Hydrogen cyanide)

By formula: CN- + CHN = (CN- • CHN)

Quantity Value Units Method Reference Comment
Δr21.7 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Δr20.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; B
Δr20.7kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.7kcal/molPHPMSMeot-ner, 1988gas phase; M,B,B,M
Quantity Value Units Method Reference Comment
Δr20.6cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.6cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr20.6cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr26.9cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(H2O), Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Δr14.5 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Δr13.7 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Δr14.5 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • Hydrogen cyanide) + Hydrogen cyanide = (CN- • 2Hydrogen cyanide)

By formula: (CN- • CHN) + CHN = (CN- • 2CHN)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr16.4kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr21.8cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr21.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr21.8cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.90kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 2Hydrogen cyanide) + Hydrogen cyanide = (CN- • 3Hydrogen cyanide)

By formula: (CN- • 2CHN) + CHN = (CN- • 3CHN)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr12.6kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr21.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr21.2cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr6.30kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 3Hydrogen cyanide) + Hydrogen cyanide = (CN- • 4Hydrogen cyanide)

By formula: (CN- • 3CHN) + CHN = (CN- • 4CHN)

Quantity Value Units Method Reference Comment
Δr10.9kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr10.9kcal/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Δr24.8cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr24.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr24.8cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 4Hydrogen cyanide) + Hydrogen cyanide = (CN- • 5Hydrogen cyanide)

By formula: (CN- • 4CHN) + CHN = (CN- • 5CHN)

Quantity Value Units Method Reference Comment
Δr9.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Δr9.8kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr20.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 5Hydrogen cyanide) + Hydrogen cyanide = (CN- • 6Hydrogen cyanide)

By formula: (CN- • 5CHN) + CHN = (CN- • 6CHN)

Quantity Value Units Method Reference Comment
Δr8.5 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr2.40kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- • 6Hydrogen cyanide) + Hydrogen cyanide = (CN- • 7Hydrogen cyanide)

By formula: (CN- • 6CHN) + CHN = (CN- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr1.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.0238.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(CN- • Hydrogen cyanide • Water) + Hydrogen cyanide = (CN- • 2Hydrogen cyanide • Water)

By formula: (CN- • CHN • H2O) + CHN = (CN- • 2CHN • H2O)

Quantity Value Units Method Reference Comment
Δr13.2kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr17.8cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • Hydrogen cyanide • 2Water) + Hydrogen cyanide = (CN- • 2Hydrogen cyanide • 2Water)

By formula: (CN- • CHN • 2H2O) + CHN = (CN- • 2CHN • 2H2O)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.4262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • 2Hydrogen cyanide • Water) + Hydrogen cyanide = (CN- • 3Hydrogen cyanide • Water)

By formula: (CN- • 2CHN • H2O) + CHN = (CN- • 3CHN • H2O)

Quantity Value Units Method Reference Comment
Δr12.3kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.1262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • 3Water) + Hydrogen cyanide = (CN- • Hydrogen cyanide • 3Water)

By formula: (CN- • 3H2O) + CHN = (CN- • CHN • 3H2O)

Quantity Value Units Method Reference Comment
Δr13.1kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.9262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

MeCO2 anion + Hydrogen cyanide = (MeCO2 anion • Hydrogen cyanide)

By formula: C2H3O2- + CHN = (C2H3O2- • CHN)

Quantity Value Units Method Reference Comment
Δr22.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,B,M
Quantity Value Units Method Reference Comment
Δr23.5cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M

(MeCO2 anion • Hydrogen cyanide) + Hydrogen cyanide = (MeCO2 anion • 2Hydrogen cyanide)

By formula: (C2H3O2- • CHN) + CHN = (C2H3O2- • 2CHN)

Quantity Value Units Method Reference Comment
Δr16.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(MeCO2 anion • 2Hydrogen cyanide) + Hydrogen cyanide = (MeCO2 anion • 3Hydrogen cyanide)

By formula: (C2H3O2- • 2CHN) + CHN = (C2H3O2- • 3CHN)

Quantity Value Units Method Reference Comment
Δr14.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.6cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(MeCO2 anion • 3Hydrogen cyanide) + Hydrogen cyanide = (MeCO2 anion • 4Hydrogen cyanide)

By formula: (C2H3O2- • 3CHN) + CHN = (C2H3O2- • 4CHN)

Quantity Value Units Method Reference Comment
Δr12.0 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr27.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.90kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(MeCO2 anion • 4Hydrogen cyanide) + Hydrogen cyanide = (MeCO2 anion • 5Hydrogen cyanide)

By formula: (C2H3O2- • 4CHN) + CHN = (C2H3O2- • 5CHN)

Quantity Value Units Method Reference Comment
Δr9.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr2.40kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5213.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

C2H4N+ + Hydrogen cyanide = (C2H4N+ • Hydrogen cyanide)

By formula: C2H4N+ + CHN = (C2H4N+ • CHN)

Quantity Value Units Method Reference Comment
Δr22.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; CD3CNH+; M
Quantity Value Units Method Reference Comment
Δr23.1cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; CD3CNH+; M

C2H5O+ + Hydrogen cyanide = (C2H5O+ • Hydrogen cyanide)

By formula: C2H5O+ + CHN = (C2H5O+ • CHN)

Quantity Value Units Method Reference Comment
Δr23.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C3H2N+ + Hydrogen cyanide = (C3H2N+ • Hydrogen cyanide)

By formula: C3H2N+ + CHN = (C3H2N+ • CHN)

Quantity Value Units Method Reference Comment
Δr23.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr25.6cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

imidazolide anion + Hydrogen cyanide = (imidazolide anion • Hydrogen cyanide)

By formula: C3H3N2- + CHN = (C3H3N2- • CHN)

Quantity Value Units Method Reference Comment
Δr23.9kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr21.9cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H7+ + Hydrogen cyanide = (C3H7+ • Hydrogen cyanide)

By formula: C3H7+ + CHN = (C3H7+ • CHN)

Quantity Value Units Method Reference Comment
Δr39.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Δr30.8kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+; M
Quantity Value Units Method Reference Comment
Δr45.2cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Δr32.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+; M

C3H7O+ + Hydrogen cyanide = (C3H7O+ • Hydrogen cyanide)

By formula: C3H7O+ + CHN = (C3H7O+ • CHN)

Quantity Value Units Method Reference Comment
Δr20.4kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.6cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C3H10N+ + Hydrogen cyanide = (C3H10N+ • Hydrogen cyanide)

By formula: C3H10N+ + CHN = (C3H10N+ • CHN)

Quantity Value Units Method Reference Comment
Δr16.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.0cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H8N+ + Hydrogen cyanide = (C4H8N+ • Hydrogen cyanide)

By formula: C4H8N+ + CHN = (C4H8N+ • CHN)

Quantity Value Units Method Reference Comment
Δr20.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr22.5cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H9+ + Hydrogen cyanide = (C4H9+ • Hydrogen cyanide)

By formula: C4H9+ + CHN = (C4H9+ • CHN)

Quantity Value Units Method Reference Comment
Δr16.3kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase; may form t-C4H9NCH+; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; may form t-C4H9NCH+; M

C4H9O2+ + Hydrogen cyanide = (C4H9O2+ • Hydrogen cyanide)

By formula: C4H9O2+ + CHN = (C4H9O2+ • CHN)

Quantity Value Units Method Reference Comment
Δr19.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.9455.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

C4H10NO+ + Hydrogen cyanide = (C4H10NO+ • Hydrogen cyanide)

By formula: C4H10NO+ + CHN = (C4H10NO+ • CHN)

Quantity Value Units Method Reference Comment
Δr15.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr22.8cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C7H11O+ + Hydrogen cyanide = (C7H11O+ • Hydrogen cyanide)

By formula: C7H11O+ + CHN = (C7H11O+ • CHN)

Quantity Value Units Method Reference Comment
Δr17.6kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C9H22N+ + Hydrogen cyanide = (C9H22N+ • Hydrogen cyanide)

By formula: C9H22N+ + CHN = (C9H22N+ • CHN)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr29.0cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

Chlorine anion + Hydrogen cyanide = (Chlorine anion • Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- • CHN)

Quantity Value Units Method Reference Comment
Δr21.8 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B,B,M
Δr21.0 ± 2.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr23.7cal/mol*KN/ALarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr16.2 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Δr16.1 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Δr13.9 ± 2.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,M

(Chlorine anion • Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 2Hydrogen cyanide)

By formula: (Cl- • CHN) + CHN = (Cl- • 2CHN)

Quantity Value Units Method Reference Comment
Δr17.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr11.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 3Hydrogen cyanide)

By formula: (Cl- • 2CHN) + CHN = (Cl- • 3CHN)

Quantity Value Units Method Reference Comment
Δr13.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 4Hydrogen cyanide)

By formula: (Cl- • 3CHN) + CHN = (Cl- • 4CHN)

Quantity Value Units Method Reference Comment
Δr11.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr4.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 5Hydrogen cyanide)

By formula: (Cl- • 4CHN) + CHN = (Cl- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr2.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 6Hydrogen cyanide)

By formula: (Cl- • 5CHN) + CHN = (Cl- • 6CHN)

Quantity Value Units Method Reference Comment
Δr8.7 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr24.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 7Hydrogen cyanide)

By formula: (Cl- • 6CHN) + CHN = (Cl- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.00kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 8Hydrogen cyanide)

By formula: (Cl- • 7CHN) + CHN = (Cl- • 8CHN)

Quantity Value Units Method Reference Comment
Δr8.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr27.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.0 ± 2.2kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 8Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 9Hydrogen cyanide)

By formula: (Cl- • 8CHN) + CHN = (Cl- • 9CHN)

Quantity Value Units Method Reference Comment
Δr7.5 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr0.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2171.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

Fluorine anion + Hydrogen cyanide = (Fluorine anion • Hydrogen cyanide)

By formula: F- + CHN = (F- • CHN)

Quantity Value Units Method Reference Comment
Δr39.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M
Quantity Value Units Method Reference Comment
Δr22.2cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Δr32.9 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

HS- + Hydrogen cyanide = (HS- • Hydrogen cyanide)

By formula: HS- + CHN = (HS- • CHN)

Quantity Value Units Method Reference Comment
Δr21.0 ± 1.0kcal/molIMREMeot-ner, 1988gas phase; See also H2S..CN-; B,M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.0 ± 1.0kcal/molIMREMeot-ner, 1988gas phase; See also H2S..CN-; B

(Hydronium cation • 2Water) + Hydrogen cyanide = (Hydronium cation • Hydrogen cyanide • 2Water)

By formula: (H3O+ • 2H2O) + CHN = (H3O+ • CHN • 2H2O)

Quantity Value Units Method Reference Comment
Δr19.8kcal/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr29.3cal/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

NH4+ + Hydrogen cyanide = (NH4+ • Hydrogen cyanide)

By formula: H4N+ + CHN = (H4N+ • CHN)

Quantity Value Units Method Reference Comment
Δr21.9kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Δr20.5kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Δr20.2cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

(NH4+ • Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide)

By formula: (H4N+ • CHN) + CHN = (H4N+ • 2CHN)

Quantity Value Units Method Reference Comment
Δr17.4kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 2Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 3Hydrogen cyanide)

By formula: (H4N+ • 2CHN) + CHN = (H4N+ • 3CHN)

Quantity Value Units Method Reference Comment
Δr13.7kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr21.5cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 3Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 4Hydrogen cyanide)

By formula: (H4N+ • 3CHN) + CHN = (H4N+ • 4CHN)

Quantity Value Units Method Reference Comment
Δr11.0kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr20.9cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 4Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 5Hydrogen cyanide)

By formula: (H4N+ • 4CHN) + CHN = (H4N+ • 5CHN)

Quantity Value Units Method Reference Comment
Δr7.9kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr18.9cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 5Hydrogen cyanide) + Hydrogen cyanide = (NH4+ • 6Hydrogen cyanide)

By formula: (H4N+ • 5CHN) + CHN = (H4N+ • 6CHN)

Quantity Value Units Method Reference Comment
Δr7.4kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide • Ammonia)

By formula: (H4N+ • CHN • H3N) + CHN = (H4N+ • 2CHN • H3N)

Quantity Value Units Method Reference Comment
Δr12.2kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr19.4cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • Hydrogen cyanide • 2Ammonia) + Hydrogen cyanide = (NH4+ • 2Hydrogen cyanide • 2Ammonia)

By formula: (H4N+ • CHN • 2H3N) + CHN = (H4N+ • 2CHN • 2H3N)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.9315.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

(NH4+ • 2Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 3Hydrogen cyanide • Ammonia)

By formula: (H4N+ • 2CHN • H3N) + CHN = (H4N+ • 3CHN • H3N)

Quantity Value Units Method Reference Comment
Δr12.8kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr24.1cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 3Hydrogen cyanide • Ammonia) + Hydrogen cyanide = (NH4+ • 4Hydrogen cyanide • Ammonia)

By formula: (H4N+ • 3CHN • H3N) + CHN = (H4N+ • 4CHN • H3N)

Quantity Value Units Method Reference Comment
Δr8.6kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.7292.PHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated, T = 392 in paper is error; M

(NH4+ • Ammonia) + Hydrogen cyanide = (NH4+ • Hydrogen cyanide • Ammonia)

By formula: (H4N+ • H3N) + CHN = (H4N+ • CHN • H3N)

Quantity Value Units Method Reference Comment
Δr14.2kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr18.5cal/mol*KPHPMSDeakyne, Knuth, et al., 1994gas phase; M

(NH4+ • 2Ammonia) + Hydrogen cyanide = (NH4+ • Hydrogen cyanide • 2Ammonia)

By formula: (H4N+ • 2H3N) + CHN = (H4N+ • CHN • 2H3N)

Quantity Value Units Method Reference Comment
Δr13.4kcal/molPHPMSDeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr18.3cal/mol*KN/ADeakyne, Knuth, et al., 1994gas phase; Entropy change calculated or estimated; M

Iodide + Hydrogen cyanide = (Iodide • Hydrogen cyanide)

By formula: I- + CHN = (I- • CHN)

Quantity Value Units Method Reference Comment
Δr16.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10.4 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 2Hydrogen cyanide)

By formula: (I- • CHN) + CHN = (I- • 2CHN)

Quantity Value Units Method Reference Comment
Δr13.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 2Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 3Hydrogen cyanide)

By formula: (I- • 2CHN) + CHN = (I- • 3CHN)

Quantity Value Units Method Reference Comment
Δr11.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.0cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr4.90kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 3Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 4Hydrogen cyanide)

By formula: (I- • 3CHN) + CHN = (I- • 4CHN)

Quantity Value Units Method Reference Comment
Δr9.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr20.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 4Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 5Hydrogen cyanide)

By formula: (I- • 4CHN) + CHN = (I- • 5CHN)

Quantity Value Units Method Reference Comment
Δr8.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr22.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 5Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 6Hydrogen cyanide)

By formula: (I- • 5CHN) + CHN = (I- • 6CHN)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 6Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 7Hydrogen cyanide)

By formula: (I- • 6CHN) + CHN = (I- • 7CHN)

Quantity Value Units Method Reference Comment
Δr7.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Iodide • 7Hydrogen cyanide) + Hydrogen cyanide = (Iodide • 8Hydrogen cyanide)

By formula: (I- • 7CHN) + CHN = (I- • 8CHN)

Quantity Value Units Method Reference Comment
Δr6.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) • Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ • CHN)

Quantity Value Units Method Reference Comment
Δr36.4kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Δr36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Δr28.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCP Sil 5 CB20.319.9Do and Raulin, 199225. m/0.15 mm/2. μm, H2
CapillaryPoraPLOT Q160.300.Do and Raulin, 198910. m/0.32 mm/10. μm, H2

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane320.Staples, 2006Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN), Inorg. Chem., 1984, 23, 2029. [all data]

Meot-Ner (Mautner) and Speller, 1989
Meot-Ner (Mautner), M.; Speller, C.V., Multicomponent Cluster Ions.3. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 6580. [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F., Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry, J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

Wenthold and Squires, 1995
Wenthold, P.G.; Squires, R.R., Bond dissociation energies of F2(-) and HF2(-). A gas-phase experimental and G2 theoretical study, J. Phys. Chem., 1995, 99, 7, 2002, https://doi.org/10.1021/j100007a034 . [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

Larson and McMahon, 1984, 2
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria, J. Am. Chem. Soc., 1984, 106, 517. [all data]

Larson and McMahon, 1984, 3
Larson, J.W.; McMahon, T.B., Gas phase negative ion chemistry of alkylchloroformates, Can. J. Chem., 1984, 62, 675. [all data]

French, Ikuta, et al., 1982
French, M.A.; Ikuta, S.; Kebarle, P., Hydrogen bonding of O-H and C-H hydrogen donors to Cl-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl- = RHCl-, Can. J. Chem., 1982, 60, 1907. [all data]

Akin and Ervin, 2006
Akin, F.A.; Ervin, K.M., Collision-induced dissociation of HS-(HCN): Unsymmetrical hydrogen bonding in a proton-bound dimer anion, J. Phys. Chem. A, 2006, 110, 4, 1342-1349, https://doi.org/10.1021/jp0540454 . [all data]

Bradforth, Kim, et al., 1993
Bradforth, S.E.; Kim, E.H.; Arnold, D.W.; Neumark, D.M., Photoelectron Spectroscopy of CN-, NCO-, and NCS-, J. Chem. Phys., 1993, 98, 2, 800, https://doi.org/10.1063/1.464244 . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Deakyne, Knuth, et al., 1994
Deakyne, C.A.; Knuth, D.M.; Speller, C.V.; Meot-Ner (Mautner), M.; Sieck, L.W., Filling of Solvent Shells about Ions. Part 3. Isomeric Clusters of (HCN)n(NH3)mH+, J. Mol. Structure (Theochem), 1994, 307, 217, https://doi.org/10.1016/0166-1280(94)80130-4 . [all data]

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M., Solvation of the Proton by HCN and CH3CN. Condensation of HCN with Ions in the Gas Phase., J. Am. Chem. Soc., 1978, 100, 15, 4694, https://doi.org/10.1021/ja00483a012 . [all data]

Meot-Ner (Mautner) M. and Speller, 1989
Meot-Ner (Mautner) M.; Speller, C.V., Multicomponent Cluster Ions. 2. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 9, 3663, https://doi.org/10.1021/j100346a058 . [all data]

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Ard, Garrett, et al., 2009
Ard, S.; Garrett, W.R.; Compton, R.N.; Adamowicz, L.; Stepanian, S.G., Rotational states of dipole-bound anions of hydrogen cyanide., Chem. Phys. Lett., 2009, 473, 4-6, 223, https://doi.org/10.1016/j.cplett.2009.04.007 . [all data]

Tsuda, Yokohata, et al., 1971
Tsuda, S.; Yokohata, A.; Umaba, T., Measurement of negative ions formed by electron impact. VIII. Ionization efficiency curves of negative ions from methyl and ethyl cyanides, Bull. Chem. Soc. Jpn., 1971, 44, 1486. [all data]

Lageot, 1972
Lageot, C., Etude des etats excites de l'ion HCN+, J. Chim. Phys. Phys.-Chim. Biol., 1972, 68, 214. [all data]

Dibeler and Liston, 1968
Dibeler, V.H.; Liston, S.K., Mass-spectrometric study of photoionization. IX. Hydrogen cyanide and acetonitrile, J. Chem. Phys., 1968, 48, 4765. [all data]

Baker and Turner, 1968
Baker, C.; Turner, D.W., High resolution molecular photoelectron spectroscopy. III.Acetylenes and azaacetylenes, Proc. Roy. Soc. (London), 1968, A308, 19. [all data]

Varsel, Morrell, et al., 1960
Varsel, C.J.; Morrell, F.A.; Resnik, F.E.; Powell, W.A., Qualitative and quantitative analysis of organic compounds. Use of low-voltage mass spectrometry, Anal. Chem., 1960, 32, 182. [all data]

Kusch, Hustrulid, et al., 1937
Kusch, P.; Hustrulid, A.; Tate, J.T., The dissociation of HCN, C2H2, C2N2 and C2H4 by electron impact, Phys. Rev., 1937, 52, 843. [all data]

Kreile, Schweig, et al., 1982
Kreile, J.; Schweig, A.; Thiel, W., Experimental and theoretical investigation of the photoionization of hydrogen cyanide, Chem. Phys. Lett., 1982, 87, 473. [all data]

Fridh and Asbrink, 1975
Fridh, C.; Asbrink, L., Photoelectron electron impact spectrum of HCN, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 119. [all data]

Potts and Williams, 1974
Potts, A.W.; Williams, T.A., The observation of "forbidden" transitions in He II photoelectron spectra, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 3. [all data]

Frost, Lee, et al., 1973
Frost, D.C.; Lee, S.T.; McDowell, C.A., The photoelectron spectrum of HCP and comments on the first photoelectron band of HCN, Chem. Phys. Lett., 1973, 23, 472. [all data]

Berkowitz, Chupka, et al., 1969
Berkowitz, J.; Chupka, W.A.; Walter, T.A., Photoionization of HCN: the electron affinity and heat of formation of CN, J. Chem. Phys., 1969, 50, 1497. [all data]

Tanaka, Mackay, et al., 1978
Tanaka, K.; Mackay, G.I.; Bohme, D.K., Rate and Equilibrium Constant Measurements for Gas-Phase Proton-Transfer Reactions Involving H2O, H2S, HCN, and H2CO, Can. J. Chem., 1978, 56, 2, 193, https://doi.org/10.1139/v78-031 . [all data]

Fehsenfeld, Dotan, et al., 1978
Fehsenfeld, F.C.; Dotan, I.; Albritton, D.L.; Howard, C.J.; Ferguson, E.E., Stratospheric Positive Ion Chemistry of Formaldehyde and Methanol, J. Geophys. Res., 1978, 83, C3, 1333, https://doi.org/10.1029/JC083iC03p01333 . [all data]

Cunningham, Payzant, et al., 1972
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Notes

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