Benzene, hexamethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-18.5 ± 0.60kcal/molCcbColomina, Jimenez, et al., 1989see Boned, Colomina, et al., 1964; ALS
Δfgas-18.7kcal/molN/AParks, West, et al., 1946Value computed using ΔfHsolid° value of -163.3±3.1 kj/mol from Parks, West, et al., 1946 and ΔsubH° value of 85.0 kj/mol from Parks, West, et al., 1946.; DRB

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
44.07200.Draeger, 1985Recommended values are in close agreement with experimental data on S(T). Discrepancies with earlier statistically calculated values [ Hastings S.H., 1957] amount to 16 and 13 J/mol*K in S(T) and Cp(T), respectively.; GT
54.33273.15
57.72 ± 0.1298.15
57.98300.
71.30400.
83.48500.
94.12600.
103.3700.
111.1800.
117.9900.
123.81000.
128.81100.
133.21200.
137.01300.
140.21400.
143.11500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-33.94kcal/molCcbOth, 1968ALS
Quantity Value Units Method Reference Comment
Δcliquid-1705.2 ± 1.7kcal/molCcbBanse and Parks, 1933Reanalyzed by Cox and Pilcher, 1970, Original value = -1703.88 kcal/mol; Corresponding Δfliquid = -38.25 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Δfsolid-38.81 ± 0.60kcal/molCcbColomina, Jimenez, et al., 1989see Boned, Colomina, et al., 1964; ALS
Δfsolid-39.03 ± 0.73kcal/molCcbParks, West, et al., 1946Reanalyzed by Cox and Pilcher, 1970, Original value = -39.19 ± 0.02 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-1704.6 ± 0.45kcal/molCcbColomina, Jimenez, et al., 1989see Boned, Colomina, et al., 1964; Corresponding Δfsolid = -38.81 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-1700.1 ± 1.3kcal/molCcbHoldiness, 1984Hf NR; Corresponding Δfsolid = -43.3 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-1704.42 ± 0.72kcal/molCcbParks, West, et al., 1946Reanalyzed by Cox and Pilcher, 1970, Original value = -1704.29 ± 0.68 kcal/mol; Corresponding Δfsolid = -39.03 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar72.373cal/mol*KN/AAtake, Gyoten, et al., 1982DH
solid,1 bar73.210cal/mol*KN/AFrankosky and Aston, 1965crystaline, I phase; DH
solid,1 bar74.00cal/mol*KN/AHuffman, Parks, et al., 1930crystaline, I phase; Extrapolation below 90 K, 82.38 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
88.60455.Kurbatov, 1947T = 183 to 256°C, mean Cp, two temperatures.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
58.17298.15Colomina, Jimenez, et al., 1989DH
60.256300.Atake, Gyoten, et al., 1982T = 3 to 300 K.; DH
58.709298.15Frankosky and Aston, 1965crystaline, I phase; T = 13 to 340 K.; DH
61.21293.81Momotani, Suga, et al., 1956T = 273 to 443 K. Unsmoothed experimental datum.; DH
61.78303.Spaght, Thomas, et al., 1932crystaline, II phase; T = 30 to 200°C.; DH
60.90294.6Huffman, Parks, et al., 1930crystaline, I phase; T = 85 to 294 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil538.2KN/AWeast and Grasselli, 1989BS
Tboil536.85KN/ACooper, Crowne, et al., 1967Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Tfus438. ± 3.KAVGN/AAverage of 13 values; Individual data points
Quantity Value Units Method Reference Comment
Tc758. ± 1.KN/ATsonopoulos and Ambrose, 1995 
Tc758.KN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 2. K; TRC
Tc751.15KN/AGuye and Mallet, 1902Uncertainty assigned by TRC = 10. K; crit. temp. greater than this - sample decomposes at this T; TRC
Quantity Value Units Method Reference Comment
Δvap16.4kcal/molCGCZhao, Unhannanant, et al., 2008AC
Quantity Value Units Method Reference Comment
Δsub20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.6458.AStephenson and Malanowski, 1987Based on data from 443. to 537. K.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
20.4320.AAmbrose, Lawrenson, et al., 1976Based on data from 303. to 338. K.; AC
19.9329.AOverberger, Steele, et al., 1969Based on data from 314. to 364. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
4.931438.7Domalski and Hearing, 1996See also Spaght, Thomas, et al., 1931.; AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
1.09383.7Domalski and Hearing, 1996CAL
11.24438.7

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
382.crystaline, IIIcrystaline, IFujiwara, Inaba, et al., 1992DH
439.crystaline, IliquidFujiwara, Inaba, et al., 1992DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.2629117.5crystaline, IIIcrystaline, IIFujiwara, Inaba, et al., 1992From Atake, Gyoten, et al., 1982; DH
0.3585384.0crystaline, IIcrystaline, IPetropavlov, Tsygankova, et al., 1988DH
0.2636115.5crystaline, IIcrystaline, IYoshimoto, Fujiwara, et al., 1985DH
0.237117.5crystaline, IIIcrystaline, IIAtake, Gyoten, et al., 1982First order transition.; DH
0.26969116.48crystaline, IIcrystaline, IFrankosky and Aston, 1965Entropy obtained as difference of integral of observed Cp over range 115 to 128 K, and integral of extrapolated Cp data.; DH
0.4400383.55crystaline, IIcrystaline, IMomotani, Suga, et al., 1956DH
4.9199438.35crystaline, IliquidMomotani, Suga, et al., 1956DH
0.4221383.7crystaline, IIcrystaline, ISpaght, Thomas, et al., 1932DH
4.9331438.7crystaline, IliquidSpaght, Thomas, et al., 1932DH
0.2431108.crystaline, IIIcrystaline, IIHuffman, Parks, et al., 1930DH
0.0370151.crystaline, IIcrystaline, IHuffman, Parks, et al., 1930DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.2117.5crystaline, IIIcrystaline, IIFujiwara, Inaba, et al., 1992From; DH
0.93384.0crystaline, IIcrystaline, IPetropavlov, Tsygankova, et al., 1988DH
2.28115.5crystaline, IIcrystaline, IYoshimoto, Fujiwara, et al., 1985DH
2.0117.5crystaline, IIIcrystaline, IIAtake, Gyoten, et al., 1982First; DH
2.409116.48crystaline, IIcrystaline, IFrankosky and Aston, 1965Entropy; DH
1.15383.55crystaline, IIcrystaline, IMomotani, Suga, et al., 1956DH
11.20438.35crystaline, IliquidMomotani, Suga, et al., 1956DH
1.10383.7crystaline, IIcrystaline, ISpaght, Thomas, et al., 1932DH
11.2438.7crystaline, IliquidSpaght, Thomas, et al., 1932DH
2.3108.crystaline, IIIcrystaline, IIHuffman, Parks, et al., 1930DH
0.24151.crystaline, IIcrystaline, IHuffman, Parks, et al., 1930DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hexamethyltetracyclo[2.2.0(2,6).0(3,5)]hexane = Benzene, hexamethyl-

By formula: C12H18 = C12H18

Quantity Value Units Method Reference Comment
Δr-82.5 ± 0.8kcal/molCmAdam and Chang, 1969liquid phase; solvent: Pure phase; Heat of isomerization; ALS
Δr-91.2kcal/molEqkOth, 1968liquid phase; Heat of isomerization, see Oth, 1969; ALS
Δr-91.5kcal/molCmOth, 1968liquid phase; solvent: Toluene-d8; Heat of isomerization at 150°C; ALS

Dewar benzene, hexamethyl- = Benzene, hexamethyl-

By formula: C12H18 = C12H18

Quantity Value Units Method Reference Comment
Δr-56.2 ± 0.6kcal/molCmAdam and Chang, 1969liquid phase; solvent: Pure phase; ALS
Δr-59.5kcal/molEqkOth, 1968liquid phase; Heat of isomerization, see Oth, 1969; ALS

C6H7N+ + Benzene, hexamethyl- = (C6H7N+ • Benzene, hexamethyl-)

By formula: C6H7N+ + C12H18 = (C6H7N+ • C12H18)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr17.1kcal/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr24.3cal/mol*KPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; M

Anti-1,2,3,5,6-pentamethyl-4-methylenebicyclo[3.1.0]hex-2-ene = Benzene, hexamethyl-

By formula: C12H18 = C12H18

Quantity Value Units Method Reference Comment
Δr-42.7kcal/molCisoChilds and Mulholland, 1983liquid phase; ALS

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C12H18+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.85 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)205.7kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity199.8kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
<0.121 ± 0.017ECDWojnarovits and Foldiak, 1981EA is an upper limit: Chen and Wentworth, 1989. G3MP2B3 calculations indicate an EA of ca. -0.1 eV, anion unbound.; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.85PEHowell, Goncalves, et al., 1984LBLHLM
7.87EIKuznesof, Stafford, et al., 1967RDSH
7.85 ± 0.02PIVilesov, 1961RDSH
7.85PIBralsford, Harris, et al., 1960RDSH
7.8CTSFoster, 1959RDSH
7.95CTSBriegleb and Czekalla, 1959RDSH
7.85PEHowell, Goncalves, et al., 1984Vertical value; LBLHLM
7.9PEKovac, Mohraz, et al., 1980Vertical value; LLK

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H7N+ + Benzene, hexamethyl- = (C6H7N+ • Benzene, hexamethyl-)

By formula: C6H7N+ + C12H18 = (C6H7N+ • C12H18)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr17.1kcal/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase
Quantity Value Units Method Reference Comment
Δr24.3cal/mol*KPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

IR spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 223
NIST MS number 228195

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

UVVis spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Source missing citation
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 8969
Instrument Zeiss PMQ II
Melting point 166.5
Boiling point 263.4

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryHP-5120.1452.4Pérez-Parajón, Santiuste, et al., 200460. m/0.25 mm/0.25 μm
CapillaryOV-101100.1416.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101120.1428.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101140.1442.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101100.1415.6Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillaryOV-101120.1428.2Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillaryOV-101140.1441.6Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillarySqualane100.1415.Engewald and Wennrich, 1976N2; Column length: 100. m; Column diameter: 0.23 mm

Kovats' RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-1011431.Hayes and Pitzer, 1982110. m/0.25 mm/0.20 μm, He, 1. K/min; Tstart: 35. C; Tend: 200. C

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M100.1778.0Engewald and Wennrich, 1976N2; Column length: 100. m; Column diameter: 0.23 mm

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH1437.White, Hackett, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryOV-1011431.Hayes and Pitzer, 1981108. m/0.25 mm/0.2 μm, 1. K/min; Tstart: 35. C; Tend: 200. C

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH1437.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.1431.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colomina, Jimenez, et al., 1989
Colomina, M.; Jimenez, P.; Roux, M.V.; Turrion, C., Thermochemical properties of 1,2,4,5-tetramethylbenzene, pentamethylbenzene, and hexamethylbenzene, J. Chem. Thermodyn., 1989, 21, 275-281. [all data]

Boned, Colomina, et al., 1964
Boned, M.L.; Colomina, M.; Perez-Ossorio, R.; Turrion, C., Investigaciones termoquimicas sobre los polimetilbencenos superiores, Anal. Fisc. Quim. B, 1964, 60, 459-468. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Draeger, 1985
Draeger, J.A., The methylbenzenes II. Fundamental vibrational shifts, statistical thermodynamic functions, and properties of formation, J. Chem. Thermodyn., 1985, 17, 263-275. [all data]

Hastings S.H., 1957
Hastings S.H., Thermodynamic properties of selected methylbenzenes from 0 to 1000 K, J. Phys. Chem., 1957, 61, 730-735. [all data]

Oth, 1968
Oth, J.F.M., The kinetics and thermochemistry of the thermal rearrangement of hexamethylbicyclo[2.2.0]hexa-2,5-diene (hexamethyldewarbenzene) and of hexamethyltetracyclo[2.2.0,0(2,6).0(3,5)]hexane (hexamethylprismane), Chem. Ber., 1968, 47, 1185-1195. [all data]

Banse and Parks, 1933
Banse, H.; Parks, G.S., Thermal data on organic compounds. XII. The heats of combustion of nine hydrocarbons, J. Am. Chem. Soc., 1933, 55, 3223-3227. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Holdiness, 1984
Holdiness, M.R., Resonance energy of hexaethylbenzene and hexamethylbenzene, Thermochim. Acta, 1984, 78, 435-436. [all data]

Atake, Gyoten, et al., 1982
Atake, T.; Gyoten, H.; Chihara, H., A concealed anomaly at 117.5 K in the heat capacity of hexamethylbenzene, J. Chem. Phys., 1982, 76(11), 5535-5540. [all data]

Frankosky and Aston, 1965
Frankosky, M.; Aston, J.G., The heat capacity and entropy of hexamethylbenzene from 13 to 340 K. An estimate of the internal rotation barrier, J. Phys. Chem., 1965, 69, 3126-3132. [all data]

Huffman, Parks, et al., 1930
Huffman, H.M.; Parks, G.S.; Daniels, A.C., Thermal data on organic compounds. VII. The heat capacities, entropies and free energies of twelve aromatic hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1547-1558. [all data]

Kurbatov, 1947
Kurbatov, V.Ya., Specific heat of liquids. I. Specific heat of benzenoid hydrocarbons, Zhur. Obshch. Khim., 1947, 17, 1999-2003. [all data]

Momotani, Suga, et al., 1956
Momotani, M.; Suga, H.; Seki, S.; Nitta, I., Phase transitions in crystals composed of organic molecules with methyl groups at the molecular periperies, Proceed. National Academy of Sci. (India), XXV(Section A, part, 1956, II), 74-82. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Cooper, Crowne, et al., 1967
Cooper, A.R.; Crowne, C.W.P.; Farrell, P.G., Gas-Liquid Chromatographic Studies of Electron-Donor-Acceptor Systems, Trans. Faraday Soc., 1967, 63, 447. [all data]

Tsonopoulos and Ambrose, 1995
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 3. Aromatic Hydrocarbons, J. Chem. Eng. Data, 1995, 40, 547-558. [all data]

Ambrose, Broderick, et al., 1974
Ambrose, D.; Broderick, B.E.; Townsend, R., The Critical Temperatures and Pressures of Thirty Organic Compounds, J. Appl. Chem. Biotechnol., 1974, 24, 359. [all data]

Guye and Mallet, 1902
Guye, P.A.; Mallet, E., Measurement of Critical Constants, Arch. Sci. Phys. Nat., 1902, 13, 274-296. [all data]

Zhao, Unhannanant, et al., 2008
Zhao, Hui; Unhannanant, Patamaporn; Hanshaw, William; Chickos, James S., Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects, J. Chem. Eng. Data, 2008, 53, 7, 1545-1556, https://doi.org/10.1021/je800091s . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ambrose, Lawrenson, et al., 1976
Ambrose, D.; Lawrenson, I.J.; Sprake, C.H.S., The vapour pressure of hexamethylbenzene, The Journal of Chemical Thermodynamics, 1976, 8, 5, 503-504, https://doi.org/10.1016/0021-9614(76)90071-9 . [all data]

Overberger, Steele, et al., 1969
Overberger, John E.; Steele, William A.; Aston, John G., The vapor pressure of hexamethylbenzene the standard entropy of hexamethylbenzene vapor and the barrier to internal rotation, The Journal of Chemical Thermodynamics, 1969, 1, 6, 535-542, https://doi.org/10.1016/0021-9614(69)90014-7 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Spaght, Thomas, et al., 1931
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some Heat-Capacity Data on Organic Compounds obtained with a Radiation Calorimeter, J. Phys. Chem., 1931, 36, 3, 882-888, https://doi.org/10.1021/j150333a009 . [all data]

Fujiwara, Inaba, et al., 1992
Fujiwara, T.; Inaba, A.; Atake, T.; Chihara, H., Thermodynamic properties of deuterated hexamethylbenzene and of its solid solutions with the hydrogenated analog. A large isotope effect on the phase transition at the temperature 117 K, J. Chem. Thermodynam., 1992, 24, 863-881. [all data]

Petropavlov, Tsygankova, et al., 1988
Petropavlov, N.N.; Tsygankova, I.G.; Teslenko, L.A., Microcalorimetric investigation of polymorphic transitions in organic crystals, Sov. Phys. Crystallogr., 1988, 33(6), 853-855. [all data]

Yoshimoto, Fujiwara, et al., 1985
Yoshimoto, Y.; Fujiwara, T.; Atake, T.; Chihara, H., Solid-solid transition in hexamethylbenzene that depends on thermal history, Chem. Lett., 1985, (9), 1347-1350. [all data]

Adam and Chang, 1969
Adam, W.; Chang, J.C., Kinetics and thermochemistry of valence isomerization by differential scanning calorimetry: the case of hexamethylprismane and hexamethyldewarbenzene, Int. J. Chem. Kinet., 1969, 1, 487-492. [all data]

Oth, 1969
Oth, J.F.M., The kinetics and thermochemistry of the thermal rearrangement of hexamethyl(Dewar benzene) and of hexamethylprismane, Angew. Chem. Int. Ed. Engl., 1969, 7, 646. [all data]

Meot-Ner (Mautner) and El-Shall, 1986
Meot-Ner (Mautner), M.; El-Shall, M.S., Ionic Charge Transfer Complexes. 1. Cationic Complexes with Delocalized and Partially Localized pi Systems, J. Am. Chem. Soc., 1986, 108, 15, 4386, https://doi.org/10.1021/ja00275a026 . [all data]

Childs and Mulholland, 1983
Childs, R.F.; Mulholland, D.L., Thermochemical relationships between some bicyclohexenyl and benzenium cations, J. Am. Chem. Soc., 1983, 105, 96-99. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Wojnarovits and Foldiak, 1981
Wojnarovits, L.; Foldiak, G., Electron capture detection of aromatic hydrocarbons, J. Chromatogr. Sci., 1981, 206, 511. [all data]

Chen and Wentworth, 1989
Chen, E.C.M.; Wentworth, W.E., Experimental Determination of Electron Affinities of Organic Molecules, Mol. Cryst. Liq. Cryst., 1989, 171, 271. [all data]

Howell, Goncalves, et al., 1984
Howell, J.O.; Goncalves, J.M.; Amatore, C.; Klasinc, L.; Wightman, R.M.; Kochi, J.K., Electron transfer from aromatic hydrocarbons and their π-complexes with metals. Comparison of the standard oxidation potentials and vertical ionization potentials, J. Am. Chem. Soc., 1984, 106, 3968. [all data]

Kuznesof, Stafford, et al., 1967
Kuznesof, P.M.; Stafford, F.E.; Shriver, D.F., Electron impact ionization potentials of methyl-substituted borazines, J. Phys. Chem., 1967, 71, 1939. [all data]

Vilesov, 1961
Vilesov, F.I., Photoionisation of organic vapours in the vacuum ultra-violet, Zh. Fiz. Khim., 1961, 35, 2010, In original 986. [all data]

Bralsford, Harris, et al., 1960
Bralsford, R.; Harris, P.V.; Price, W.C., The effect of fluorine on the electronic spectra and ionization potentials of molecules, Proc. Roy. Soc. (London), 1960, A258, 459. [all data]

Foster, 1959
Foster, R., Ionization potentials of electron donors, Nature (London), 1959, 183, 1253. [all data]

Briegleb and Czekalla, 1959
Briegleb, G.; Czekalla, J., Die Bestimmung von lonisierungsenergien aus den Spektren von Elektronenubergangskomplexen, Z.Elektrochem., 1959, 63, 6. [all data]

Kovac, Mohraz, et al., 1980
Kovac, B.; Mohraz, M.; Heilbronner, E.; Boekelheide, V.; Hopf, H., Photoelectron spectra of the cyclophanes, J. Am. Chem. Soc., 1980, 102, 4314. [all data]

Pérez-Parajón, Santiuste, et al., 2004
Pérez-Parajón, J.M.; Santiuste, J.M.; Takács, J.M., Sensitivity of the methylbenzenes and chlorobenzenes retention index to column temperature, stationary phase polarity, and number and chemical nature of substituents, J. Chromatogr. A, 2004, 1048, 2, 223-232, https://doi.org/10.1016/j.chroma.2004.07.028 . [all data]

Gerasimenko and Nabivach, 1982
Gerasimenko, V.A.; Nabivach, V.M., Relationship between molecular structure and gas chromatographic retention of alkylbenzenes C8-C1 2 on polydimethylsiloxane, Zh. Anal. Khim., 1982, 37, 110-116. [all data]

Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M., Capillary gas chromatography of aromatic compounds found in coal tar fractions, J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4 . [all data]

Engewald and Wennrich, 1976
Engewald, W.; Wennrich, L., Molekülstruktur und Retentionsverhalten. VIII. Zum Retentionsverhalten höherer Alkylbenzole bei der Gas-Verteilungs-Chromatographie, Chromatographia, 1976, 9, 11, 540-547, https://doi.org/10.1007/BF02275960 . [all data]

Hayes and Pitzer, 1982
Hayes, P.C., Jr.; Pitzer, E.W., Characterizing petroleum- and shale-derived jet fuel distillates via temperature-programmed Kováts indices, J. Chromatogr., 1982, 253, 179-198, https://doi.org/10.1016/S0021-9673(01)88376-X . [all data]

White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211 . [all data]

Hayes and Pitzer, 1981
Hayes, P.C., Jr.; Pitzer, E.W., Kovats indices as a tool in characterizing hydrocarbon fuels in temperature programmed glass capillary gas chromatography. Part 1. Qualitative identification, Inhouse rpt. for Air Force Wright Aeronautical Labs., Air Force Wright Aeronautical Labs., Wright-Patterson AFB, Ohio, 1981, 75. [all data]

Supelco, 2012
Supelco, CatalogNo. 24160-U, Petrocol DH Columns. Catalog No. 24160-U, 2012, retrieved from http://www.sigmaaldrich.com/etc/medialib/docs/Supelco/Datasheet/1/w97949.Par.0001.File.tmp/w97949.pdf. [all data]

Waggott and Davies, 1984
Waggott, A.; Davies, I.W., Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References