CS2+
- Formula: CS2+
- Molecular weight: 76.140
- CAS Registry Number: 56283-12-6
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Ion clustering data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: CS2+ + COS = (CS2+ • COS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.8 | kcal/mol | PI | Ono, Osuch, et al., 1981 | gas phase |
By formula: CS2+ + CS2 = (CS2+ • CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 24.9 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrH° | 21.9 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase |
ΔrH° | 17.5 | kcal/mol | PI | Ono, Linn, et al., 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrS° | 21.9 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase |
By formula: (CS2+ • CS2) + CS2 = (CS2+ • 2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.5 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrH° | 4.4 | kcal/mol | PI | Ono, Linn, et al., 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (CS2+ • 2CS2) + CS2 = (CS2+ • 3CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.9 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
ΔrH° | 3.9 | kcal/mol | PI | Ono, Linn, et al., 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17. | cal/mol*K | N/A | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (CS2+ • 3CS2) + CS2 = (CS2+ • 4CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.6 | kcal/mol | PI | Ono, Linn, et al., 1980 | gas phase |
Vibrational and/or electronic energy levels
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 49064 | gas | C-B | 658 | 724 | Frey, Gotchev, et al., 1978 | ||
Danis, Wyttenbach, et al., 1988 | |||||||
Evard, Wyttenbach, et al., 1989 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 652 ± 2 | gas | PI PE | Frey, Gotchev, et al., 1978 Potts and Fattahallah, 1980 Kovac, 1983 | |
1 | Sym. stretch | 652 ± 2 | gas | PF MP | Danis, Wyttenbach, et al., 1988 Wang, Reutt, et al., 1988 Evard, Wyttenbach, et al., 1989 Baltzer, Wannberg, et al., 1996 Zhuang, Zhang, et al., 2006 | ||
Πu | 2 | Bend | 348 ± 9 | gas | PF PE | Danis, Wyttenbach, et al., 1988 Wang, Reutt, et al., 1988 Baltzer, Wannberg, et al., 1996 Zhuang, Zhang, et al., 2006 | |
Σu+ | 3 | Asym. stretch | 1024 ± 6 | T | gas | PE | Wang, Reutt, et al., 1988 |
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 35238.01 | gas | B-X | 277 | 307 | Callomon, 1958 | ||
Zhuang, Zhang, et al., 2006 | |||||||
To = 35270 | Ne | B-X | Bondybey and English, 1980 | ||||
To = 35226 | Ne | B-X | Bondybey and English, 1980 | ||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 613 | gas | PE MPD | Balfour, 1976 Baltzer, Wannberg, et al., 1996 Zhuang, Zhang, et al., 2006 | |
Πu | 2 | Bend | 351 ± 5 | gas | PE | Wang, Reutt, et al., 1988 Baltzer, Wannberg, et al., 1996 Zhuang, Zhang, et al., 2006 | |
Σu+ | 3 | Asym. stretch | 1320 ± 5 | gas | PE | Wang, Reutt, et al., 1988 Baltzer, Wannberg, et al., 1996 | |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 20973.30 | gas | A-X | 426 | 512 | Balfour, 1976 | ||
Venkitachalam, 1999 | |||||||
He and Clouthier, 2006 | |||||||
To = 21010.6 | Ne | A-X | 400 | 642 | Bondybey, English, et al., 1979 | ||
Bondybey and English, 1980 | |||||||
Cheng, Lo, et al., 1995 | |||||||
Lorenz and Bondybey, 2000 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 612.47 | gas | PE LF | Liu, Hochlaf, et al., 2001 He and Clouthier, 2006 | |
1 | Sym. stretch | 551 | Ne | LF | Bondybey, English, et al., 1979 Bondybey and English, 1980 Zen and Lee, 1995 Lorenz and Bondybey, 2000 | ||
Πu | 2 | Bend (κ 2Su-) | 510 ± 5 | gas | PE | Liu, Hochlaf, et al., 2001 | |
2 | Bend (2Du,5/2) | 286 ± 5 | gas | PE | Liu, Hochlaf, et al., 2001 | ||
2 | Bend | 309 | H | Ne | LF | Bondybey, English, et al., 1979 Bondybey and English, 1980 Zen and Lee, 1995 | |
Σu+ | 3 | Asym. stretch | 1723 ± 5 | gas | PE | Liu, Hochlaf, et al., 2001 | |
3 | Asym. stretch | 1644 | H | Ne | LF | Bondybey and English, 1980 | |
State: X
Additional references: Jacox, 1994, page 79; Jacox, 1998, page 186; Jacox, 2003, page 125; Smith, 1969; Eland, Devoret, et al., 1976; Maier and Thommen, 1980; Dunbar and Turner, 1981; Ibuki and Sugita, 1984
Notes
H | (1/2)(2ν) |
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y.,
Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2,
J. Chem. Phys., 1981, 74, 1645. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S.,
Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-,
J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014
. [all data]
Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H.,
Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry,
J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706
. [all data]
Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y.,
Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters,
J. Chem. Phys., 1980, 73, 2523. [all data]
Frey, Gotchev, et al., 1978
Frey, R.; Gotchev, B.; Peatman, W.B.; Pollak, H.; Schlag, E.W.,
Photoionization resonance study of the X(2π), A(2π), B(2Σ+) and C(2Σ+) states of CS2+ and COS+,
Int. J. Mass Spectrom. Ion Phys., 1978, 26, 137. [all data]
Danis, Wyttenbach, et al., 1988
Danis, P.O.; Wyttenbach, T.; Maier, J.P.,
Two-photon absorption spectroscopy of mass-selected ions: N2O+ and CS+2,
J. Chem. Phys., 1988, 88, 6, 3451, https://doi.org/10.1063/1.453893
. [all data]
Evard, Wyttenbach, et al., 1989
Evard, D.D.; Wyttenbach, T.; Maier, J.P.,
Two-photon absorption spectroscopy of ion beams: carbon disulfide(1+) ~C2.SIGMA.g+ state characterization,
J. Phys. Chem., 1989, 93, 9, 3522, https://doi.org/10.1021/j100346a032
. [all data]
Potts and Fattahallah, 1980
Potts, A.W.; Fattahallah, G.H.,
High-resolution ultraviolet photoelectron spectroscopy of CO2, COS and CS2,
J. Phys. B:, 1980, 13, 2545. [all data]
Kovac, 1983
Kovac, B.,
The He i photoelectron spectra of CO2, CS2, and OCS: Vibronic coupling,
J. Chem. Phys., 1983, 78, 4, 1684, https://doi.org/10.1063/1.444967
. [all data]
Wang, Reutt, et al., 1988
Wang, L.; Reutt, J.E.; Lee, Y.T.; Shirley, D.A.,
High resolution UV photoelectron spectroscopy of CO2, COS, and CS2 using supersonic molecular beams,
J. Electron Spectrosc. Relat. Phenom., 1988, 47, 167. [all data]
Baltzer, Wannberg, et al., 1996
Baltzer, P.; Wannberg, B.; Lundqvist, M.; Karlsson, L.; Holland, D.M.P.; MacDonald, M.A.; Hayes, M.A.; Tomasello, P.; von Niessen, W.,
An experimental and theoretical study of the valence shell photoelectron spectrum of carbon disulphide,
Chem. Phys., 1996, 202, 1, 185, https://doi.org/10.1016/0301-0104(95)00303-7
. [all data]
Zhuang, Zhang, et al., 2006
Zhuang, X.; Zhang, L.; Wang, J.; Ma, Y.; Yu, S.; Liu, S.; Ma, X.,
Study on the Photodissociation Spectra of CS,
J. Phys. Chem. A, 2006, 110, 19, 6256, https://doi.org/10.1021/jp060533f
. [all data]
Callomon, 1958
Callomon, J.H.,
Electronic Emission Spectra of the Carbon Disulphide Ion, CSFormula,
Proc. Roy. Soc. (London) A244, 1958, 244, 1237, 220, https://doi.org/10.1098/rspa.1958.0038
. [all data]
Bondybey and English, 1980
Bondybey, V.E.; English, J.H.,
Spectroscopy and relaxation of CS2+ in solid Ne,
J. Chem. Phys., 1980, 73, 7, 3098, https://doi.org/10.1063/1.440544
. [all data]
Balfour, 1976
Balfour, W.J.,
The and band systems of the CS,
Can. J. Phys., 1976, 54, 19, 1969, https://doi.org/10.1139/p76-235
. [all data]
Venkitachalam, 1999
Venkitachalam, T.V.,
A tentative multiphoton ionization of CS2 molecule: Spectroscopy of Ã2πu state of CS 2 + ion,
Pramana, 1999, 52, 2, 177, https://doi.org/10.1007/BF02831493
. [all data]
He and Clouthier, 2006
He, S.-G.; Clouthier, D.J.,
The molecular structure and a Renner-Teller analysis of the ground and first excited electronic states of the jet-cooled CS[sub 2][sup +] molecular ion,
J. Chem. Phys., 2006, 12, 8, 084312, https://doi.org/10.1063/1.2172612
. [all data]
Bondybey, English, et al., 1979
Bondybey, V.E.; English, J.H.; Miller, T.A.,
Laser induced fluorescence spectrum of matrix isolated CS+2,
J. Chem. Phys., 1979, 70, 4, 1621, https://doi.org/10.1063/1.437702
. [all data]
Cheng, Lo, et al., 1995
Cheng, B.-M.; Lo, W.-J.; Hung, W.-C.,
Photoionization threshold of CS2 in solid neon,
Chem. Phys. Lett., 1995, 236, 3, 355, https://doi.org/10.1016/0009-2614(95)00224-R
. [all data]
Lorenz and Bondybey, 2000
Lorenz, M.; Bondybey, V.E.,
Deposition of mass-selected ions in neon matrices: CS[sub 2][sup +] and C[sub 6]F[sub 6][sup +],
Low Temp. Phys., 2000, 26, 9, 778, https://doi.org/10.1063/1.1312407
. [all data]
Liu, Hochlaf, et al., 2001
Liu, J.; Hochlaf, M.; Chambaud, G.; Rosmus, P.; Ng, C.Y.,
High Resolution Pulsed Field Ionization-Photoelectron Bands for CS,
J. Phys. Chem. A, 2001, 105, 11, 2183, https://doi.org/10.1021/jp001998n
. [all data]
Zen and Lee, 1995
Zen, C.-C.; Lee, Y.-P.,
Laser-induced fluorescence of the A2πu-X2πg transition of CS2+ in solid Ne. Reanalysis of vibronic spectra,
Chem. Phys. Lett., 1995, 244, 1-2, 177, https://doi.org/10.1016/0009-2614(95)00919-U
. [all data]
Fischer, Lochschmidt, et al., 1993
Fischer, I.; Lochschmidt, A.; Strobel, A.; Niedner-Schatteburg, G.; Muller-Dethlefs, K.; Bondybey, V.E.,
The non-resonant two-photon zero kinetic energy photoelectron spectrum of CS2,
Chem. Phys. Lett., 1993, 202, 542. [all data]
Huang, Cheung, et al., 1997
Huang, J.-C.; Cheung, Y.-S.; Evans, M.; Liao, C.-X.; Ng, C.Y.; Hsu, C.-W.; Heimann, P.; Lefebvre-Brion, H.; Cossart-Magos, C.,
A high-resolution vacuum ultraviolet photoionization, photoelectron, and pulsed field ionization study of CS2 near the CS[sub 2][sup +](X 2Π3/2,1/2) thresholds,
J. Chem. Phys., 1997, 106, 3, 864, https://doi.org/10.1063/1.473967
. [all data]
Halasinski, Godbout, et al., 1996
Halasinski, T.M.; Godbout, J.T.; Allison, J.; Leroi, G.E.,
Matrix Isolation and Cold Diffusion of Mass-Selected CS,
J. Phys. Chem., 1996, 100, 36, 14865, https://doi.org/10.1021/jp960862f
. [all data]
Zhou and Andrews, 2000
Zhou, M.; Andrews, L.,
Infrared spectra of the CS[sub 2][sup -], CS[sub 2][sup +], and C[sub 2]S[sub 4][sup +] molecular ions in solid neon and argon,
J. Chem. Phys., 2000, 112, 15, 6576, https://doi.org/10.1063/1.481230
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Smith, 1969
Smith, W.H.,
Radiative Lifetimes and Total Transition Probabilities for Some Polyatomic Species,
J. Chem. Phys., 1969, 51, 8, 3410, https://doi.org/10.1063/1.1672528
. [all data]
Eland, Devoret, et al., 1976
Eland, J.H.D.; Devoret, M.; Leach, S.,
Quantum yields and lifetimes of molecular ion fluorescence,
Chem. Phys. Lett., 1976, 43, 1, 97, https://doi.org/10.1016/0009-2614(76)80765-8
. [all data]
Maier and Thommen, 1980
Maier, J.P.; Thommen, F.,
Fluorescence quantum yields and cascade-free lifetimes of state selected CO+2, COS+, CS+2 and N2O+ determined by photoelectron---photon coincidence spectroscopy,
Chem. Phys., 1980, 51, 3, 319, https://doi.org/10.1016/0301-0104(80)80106-6
. [all data]
Dunbar and Turner, 1981
Dunbar, R.C.; Turner, D.W.,
Wavelength-resolved fluorescence lifetimes of gas-phase ions: CO2+ and CS2+,
Chem. Phys., 1981, 57, 3, 377, https://doi.org/10.1016/0301-0104(81)80216-9
. [all data]
Ibuki and Sugita, 1984
Ibuki, T.; Sugita, N.,
Lifetimes of N2O+(A), CS+2(A), and CS+2(B) states produced by pulsed EUV photons,
J. Chem. Phys., 1984, 80, 10, 4625, https://doi.org/10.1063/1.446547
. [all data]
Notes
Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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