PNP

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 28300 Ar A-X Andrews and Mielke, 1990
Andrews, Mielke, et al., 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 560 ± 20 Ar AB Andrews and Mielke, 1990
Andrews, Mielke, et al., 1994

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 3 Asym. stretch 1179.3 Ar IR Andrews, Mielke, et al., 1994

Additional references: Jacox, 1998, page 187

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andrews and Mielke, 1990
Andrews, L.; Mielke, Z., Vibronic absorption spectra of phosphorus molecules (P4+ and P3) in solid argon, J. Phys. Chem., 1990, 94, 6, 2348, https://doi.org/10.1021/j100369a029 . [all data]

Andrews, Mielke, et al., 1994
Andrews, L.; Mielke, Z.; Taylor, P.R.; Martin, J.M.L., Matrix Infrared Spectrum and ab Initio Calculations on the PNP Radical, J. Phys. Chem., 1994, 98, 42, 10706, https://doi.org/10.1021/j100093a007 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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