C6F6+

• Formula: C₆F₆⁺
• Molecular weight: 186.0541
• CAS Registry Number: 34528-23-9
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   B

State:   X

Additional references: Jacox, 1994, page 438; Allan, Maier, et al., 1977; Bondybey, Vaughn, et al., 1981; Winkoun, Chapoulard, et al., 1984

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier and Thommen, 1981
Maier, J.P.; Thommen, F., Fluorescence quantum yields and lifetimes of fluorobenzene cations in selected levels of their B and C states determined by photoelectron-photoion coincidence spectroscopy, Chem. Phys., 1981, 57, 319. [all data]

Allan and Maier, 1975
Allan, M.; Maier, J.P., Emission spectra of the radical cations of hexa-, penta-, tetra-, and tri-fluorobenzenes, Chem. Phys. Lett., 1975, 34, 3, 442, https://doi.org/10.1016/0009-2614(75)85535-7 . [all data]

Cossart-Magos, Cossart, et al., 1979
Cossart-Magos, C.; Cossart, D.; Leach, S., Emission spectra of seven fluorobenzene cations, Mol. Phys., 1979, 37, 3, 793, https://doi.org/10.1080/00268977900103201 . [all data]

Bondybey and Miller, 1979
Bondybey, V.E.; Miller, T.A., Laser induced fluorescence from fluorobenzene radical cations in the gas phase, J. Chem. Phys., 1979, 70, 1, 138, https://doi.org/10.1063/1.437231 . [all data]

Sears, Miller, et al., 1981
Sears, T.; Miller, T.A.; Bondybey, V.E., Laser excitation and emission spectra of the hexafluorobenzene cation in the gas phase, J. Am. Chem. Soc., 1981, 103, 2, 326, https://doi.org/10.1021/ja00392a014 . [all data]

Tuckett, 1981
Tuckett, R.P., Fluorescence spectra of fluorobenzene cations excited in a supersonic molecular beam, Chem. Phys., 1981, 58, 2, 151, https://doi.org/10.1016/0301-0104(81)80052-3 . [all data]

Kennedy, Miller, et al., 1986
Kennedy, R.A.; Miller, T.A.; Scharf, B., Novel effects in the laser induced fluorescence spectrum of C6F+6, J. Chem. Phys., 1986, 85, 3, 1336, https://doi.org/10.1063/1.451221 . [all data]

Yu, Foster, et al., 1990
Yu, L.; Foster, S.C.; Williamson, J.M.; Miller, T.A., High-resolution electronic spectroscopy of jet-cooled hexafluorobenzene and 1,3,5-trifluorobenzene cations, C6F+6 and C6F3H+3, J. Chem. Phys., 1990, 92, 10, 5794, https://doi.org/10.1063/1.458399 . [all data]

Bondybey, Miller, et al., 1980
Bondybey, V.E.; Miller, T.A.; English, J.H., Observation of Slow Vibrational Relaxation in Halogenated Benzene Radical Cations in Rare-Gas Solids, Phys. Rev. Lett., 1980, 44, 20, 1344, https://doi.org/10.1103/PhysRevLett.44.1344 . [all data]

Bondybey and Miller, 1980
Bondybey, V.E.; Miller, T.A., Absorption and laser induced fluorescence spectra of C6F6+ inert gas matrices, J. Chem. Phys., 1980, 73, 7, 3053, https://doi.org/10.1063/1.440563 . [all data]

Hauge, Kafafi, et al., 1987
Hauge, R.H.; Kafafi, Z.H.; Margrave, J.L., Physics and Chemistry of Small Clusters, P. Jena, B.K. Rao, and S.N. Khanna, Eds., p.787, Plenum, 1987. [all data]

Bondybey, English, et al., 1978
Bondybey, V.E.; English, J.H.; Miller, T.A., Laser fluorescence spectra of the hexafluorobenzene cation in solid argon, J. Am. Chem. Soc., 1978, 100, 16, 5251, https://doi.org/10.1021/ja00484a079 . [all data]

Bondybey, Miller, et al., 1979
Bondybey, V.E.; Miller, T.A.; English, J.H., Matrix laser fluorescence spectra of several fluorobenzene radical cations, J. Am. Chem. Soc., 1979, 101, 5, 1248, https://doi.org/10.1021/ja00499a033 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Allan, Maier, et al., 1977
Allan, M.; Maier, J.P.; Marthaler, O., Radative relaxation of the B(π-1)EXCITED ELECTRONIC STATES OF THE RADICAL CATIONS OF REXAFLUOROBENZENE, PENTAFLUOROBENZENE, 1,2,3,4-, 1,2,3,5-, 1,2,4,5-TETRAFLUOROBENZENE, 1,3,5-, 1,2,4-TRIFLUOROBENZENE AND 1,3-DIFLUOROBENZENE, Chem. Phys., 1977, 26, 1, 131, https://doi.org/10.1016/0301-0104(77)87099-7 . [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.; Miller, T.A.; English, J.H.; Shiley, R.H., Spectroscopy and decay dynamics of several methyl- and fluorine-substituted benzene radical cations, J. Am. Chem. Soc., 1981, 103, 21, 6303, https://doi.org/10.1021/ja00411a006 . [all data]

Winkoun, Chapoulard, et al., 1984
Winkoun, D.; Chapoulard, D.; Dujardin, G.; Leach, S., Vibrational dependence of electronic nonradiative processes in the state of and, Can. J. Phys., 1984, 62, 12, 1361, https://doi.org/10.1139/p84-183 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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