Boron monochloride
- Formula: BCl
- Molecular weight: 46.264
- IUPAC Standard InChIKey: GKCOJTRGYAUVSR-UHFFFAOYSA-N
- CAS Registry Number: 20583-55-5
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to BCl+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.2 | DER | Lias, Bartmess, et al., 1988 | LL |
12. ± 1. | EI | Srivastava and Farber, 1971 | LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
B+ | 13.6 ± 0.2 | Cl | EI | Marriott and Craggs, 1957 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G.,
Gas-phase ion and neutral thermochemistry,
J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]
Srivastava and Farber, 1971
Srivastava, R.D.; Farber, M.,
Thermodynamic properties of the B-Cl-F system from mass spectrometer investigations,
J. Chem. Soc. Faraday Trans., 1971, 67, 2298. [all data]
Marriott and Craggs, 1957
Marriott, J.; Craggs, J.D.,
Ionization and dissociation by electron impact. II. Boron trifluoride and boron trichloride,
J. Electron. Control, 1957, 3, 194. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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