Methane, nitro-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-81. ± 1.kJ/molCcbKnobel, Miroshnichenko, et al., 1971 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-113. ± 0.4kJ/molCcbLebedeva and Ryadenko, 1973ALS
Δfliquid-113.1 ± 0.63kJ/molCcbCass, Fletcher, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -93. ± 1. kJ/mol; ALS
Δfliquid-89.04 ± 0.75kJ/molCcbHolcomb and Dorsey, 1949ALS
Quantity Value Units Method Reference Comment
Δcliquid-709.6 ± 0.4kJ/molCcbLebedeva and Ryadenko, 1973ALS
Δcliquid-703. ± 1.kJ/molCcbKnobel, Miroshnichenko, et al., 1971ALS
Δcliquid-709.15 ± 0.59kJ/molCcbCass, Fletcher, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -730. ± 1. kJ/mol; ALS
Δcliquid-733.25 ± 0.75kJ/molCcbHolcomb and Dorsey, 1949ALS
Δcliquid-709.2kJ/molCcbSwientoslawski, 1910ALS
Quantity Value Units Method Reference Comment
liquid171.75J/mol*KN/AJones and Giauque, 1947DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
106.22308.Berman and West, 1969T = 308 to 473 K.; DH
108.8313.Hough, Mason, et al., 1950T = 313 to 363 K.; DH
105.98298.15Jones and Giauque, 1947T = 15 to 300 K.; DH
100.298.Williams, 1925T = 288 to 343 K. Equation only.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH2NO2- + Hydrogen cation = Methane, nitro-

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Δr1498. ± 21.kJ/molD-EAMetz, Cyr, et al., 1991gas phase; B
Δr1491. ± 9.2kJ/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Δr1495. ± 12.kJ/molG+TSCumming and Kebarle, 1978gas phase; B
Quantity Value Units Method Reference Comment
Δr1463. ± 8.4kJ/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Δr1467. ± 8.4kJ/molIMRECumming and Kebarle, 1978gas phase; B
Δr1467. ± 8.4kJ/molIMREMacKay and Bohme, 1978gas phase; EA: < NO2; B

Chlorine anion + Methane, nitro- = (Chlorine anion • Methane, nitro-)

By formula: Cl- + CH3NO2 = (Cl- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr65.3 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Δr69.87 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Δr68. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984; B
Quantity Value Units Method Reference Comment
Δr71.5J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr38.5kJ/molTDAsWincel, 2003gas phase; B
Δr48.53 ± 0.42kJ/molTDAsSieck, 1985gas phase; B

(Chlorine anion • Methane, nitro-) + Methane, nitro- = (Chlorine anion • 2Methane, nitro-)

By formula: (Cl- • CH3NO2) + CH3NO2 = (Cl- • 2CH3NO2)

Quantity Value Units Method Reference Comment
Δr54.4 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Δr54.81 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr76.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.8kJ/molTDAsWincel, 2003gas phase; B
Δr31.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Methane, nitro- = (Nitrogen oxide anion • Methane, nitro-)

By formula: NO2- + CH3NO2 = (NO2- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr60.7 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Δr59.83 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr64.9J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr32.6kJ/molTDAsWincel, 2003gas phase; B
Δr40.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

C6H7N+ + Methane, nitro- = (C6H7N+ • Methane, nitro-)

By formula: C6H7N+ + CH3NO2 = (C6H7N+ • CH3NO2)

Quantity Value Units Method Reference Comment
Δr60.2kJ/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr75.J/mol*KN/AMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.343.PHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

(CH3NO2- • Methane, nitro-) + Methane, nitro- = (CH3NO2- • 2Methane, nitro-)

By formula: (CH3NO2- • CH3NO2) + CH3NO2 = (CH3NO2- • 2CH3NO2)

Quantity Value Units Method Reference Comment
Δr50. ± 150.kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; shift in electron detachment from less solvated ion; B
Δr53.6 ± 1.3kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr24.7kJ/molTDAsWincel, 2003gas phase; B

CH6N+ + Methane, nitro- = (CH6N+ • Methane, nitro-)

By formula: CH6N+ + CH3NO2 = (CH6N+ • CH3NO2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Δr85.8kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner, 1984gas phase; M

CH2NO2- + Methane, nitro- = C2H5N2O4-

By formula: CH2NO2- + CH3NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Δr66.5 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr35.1kJ/molTDAsWincel, 2003gas phase; B

C3H9N3O6- + 3Methane, nitro- = C4H12N4O8-

By formula: C3H9N3O6- + 3CH3NO2 = C4H12N4O8-

Quantity Value Units Method Reference Comment
Δr43.5 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr15.9kJ/molTDAsWincel, 2003gas phase; B

C2H5N2O4- + 2Methane, nitro- = C3H8N3O6-

By formula: C2H5N2O4- + 2CH3NO2 = C3H8N3O6-

Quantity Value Units Method Reference Comment
Δr55.6 ± 2.9kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr24.3kJ/molTDAsWincel, 2003gas phase; B

C3H8N3O6- + 3Methane, nitro- = C4H11N4O8-

By formula: C3H8N3O6- + 3CH3NO2 = C4H11N4O8-

Quantity Value Units Method Reference Comment
Δr52.7 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr13.0kJ/molTDAsWincel, 2003gas phase; B

C4H11N4O8- + 4Methane, nitro- = C5H14N5O10-

By formula: C4H11N4O8- + 4CH3NO2 = C5H14N5O10-

Quantity Value Units Method Reference Comment
Δr47.70 ± 0.84kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr6.69kJ/molTDAsWincel, 2003gas phase; B

C2H6N2O6- + 2Methane, nitro- = C3H9N3O8-

By formula: C2H6N2O6- + 2CH3NO2 = C3H9N3O8-

Quantity Value Units Method Reference Comment
Δr45.6 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr15.5kJ/molTDAsWincel, 2003gas phase; B

C4H12N4O8- + 4Methane, nitro- = C5H15N5O10-

By formula: C4H12N4O8- + 4CH3NO2 = C5H15N5O10-

Quantity Value Units Method Reference Comment
Δr35.1 ± 0.84kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr10.0kJ/molTDAsWincel, 2003gas phase; B

C3H9N3O8- + 3Methane, nitro- = C4H12N4O10-

By formula: C3H9N3O8- + 3CH3NO2 = C4H12N4O10-

Quantity Value Units Method Reference Comment
Δr39.7 ± 3.8kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr9.62kJ/molTDAsWincel, 2003gas phase; B

CH3N2O4- + 2Methane, nitro- = C2H6N3O6-

By formula: CH3N2O4- + 2CH3NO2 = C2H6N3O6-

Quantity Value Units Method Reference Comment
Δr51.9 ± 2.1kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr22.6kJ/molTDAsWincel, 2003gas phase; B

C2H6ClN2O4- + 3Methane, nitro- = C3H9ClN3O6-

By formula: C2H6ClN2O4- + 3CH3NO2 = C3H9ClN3O6-

Quantity Value Units Method Reference Comment
Δr46.4 ± 2.1kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr15.5kJ/molTDAsWincel, 2003gas phase; B

C11H10+ + Methane, nitro- = (C11H10+ • Methane, nitro-)

By formula: C11H10+ + CH3NO2 = (C11H10+ • CH3NO2)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSEl-Shall and Meot-Ner (Mautner), 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSEl-Shall and Meot-Ner (Mautner), 1987gas phase; M

C2H6N3O6- + 3Methane, nitro- = C3H9N4O8-

By formula: C2H6N3O6- + 3CH3NO2 = C3H9N4O8-

Quantity Value Units Method Reference Comment
Δr47.3 ± 3.3kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr13.8kJ/molTDAsWincel, 2003gas phase; B

C3H9N4O8- + 4Methane, nitro- = C4H12N5O10-

By formula: C3H9N4O8- + 4CH3NO2 = C4H12N5O10-

Quantity Value Units Method Reference Comment
Δr40.6 ± 1.3kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr6.69kJ/molTDAsWincel, 2003gas phase; B

C5H10NO2+ + Methane, nitro- = (C5H10NO2+ • Methane, nitro-)

By formula: C5H10NO2+ + CH3NO2 = (C5H10NO2+ • CH3NO2)

Quantity Value Units Method Reference Comment
Δr73.2kJ/molHPMSMeot-Ner and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KHPMSMeot-Ner and Field, 1974gas phase; M

C5H12NO2+ + Methane, nitro- = (C5H12NO2+ • Methane, nitro-)

By formula: C5H12NO2+ + CH3NO2 = (C5H12NO2+ • CH3NO2)

Quantity Value Units Method Reference Comment
Δr82.8kJ/molHPMSMeot-Ner and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr116.J/mol*KHPMSMeot-Ner and Field, 1974gas phase; M

C3H9ClN3O6- + 4Methane, nitro- = C4H12ClN4O8-

By formula: C3H9ClN3O6- + 4CH3NO2 = C4H12ClN4O8-

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr11.3kJ/molTDAsWincel, 2003gas phase; B

C4H12N4O10- + 4Methane, nitro- = C5H15N5O12-

By formula: C4H12N4O10- + 4CH3NO2 = C5H15N5O12-

Quantity Value Units Method Reference Comment
Δr25.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Δr2.5kJ/molTDAsWincel, 2003gas phase; B

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) • Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)

Quantity Value Units Method Reference Comment
Δr165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

CH3NO2- + Methane, nitro- = (CH3NO2- • Methane, nitro-)

By formula: CH3NO2- + CH3NO2 = (CH3NO2- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr63.60 ± 0.84kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; Shift in electron detachment from non-solvated ion; B

Bromine anion + Methane, nitro- = CH3BrNO2-

By formula: Br- + CH3NO2 = CH3BrNO2-

Quantity Value Units Method Reference Comment
Δr40. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Iodide + Methane, nitro- = (Iodide • Methane, nitro-)

By formula: I- + CH3NO2 = (I- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr51.0 ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)11.08 ± 0.04eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)754.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity721.6kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.1720 ± 0.0060LPESAdams, Schneider, et al., 2009B
0.260 ± 0.080LPESCompton, Carman Jr., et al., 1996dipole-bound state: 12±3 meV.; B
0.01201N/ALecomte, Carles, et al., 2000Dipole-bound state; B
0.500 ± 0.020ECDChen, Welk, et al., 1999Reanalysis of Chen and Wentworth, 1983; B
0.49 ± 0.11IMREGrimsrud, Caldwell, et al., 1985ΔGea(423 K) = -12.1 kcal/mol; ΔSea (estimated) = +2.0 eu.; B
0.451 ± 0.052ECDChen and Wentworth, 1983B
0.44 ± 0.20NBIECompton, Reinhardt, et al., 1978B
0.960 ± 0.010LPESGoebbert, Pichugin, et al., 2009Stated electron affinity is the Vertical Detachment Energy; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.07PEPasa-Tolic, Klasine, et al., 1990LL
11.1 ± 0.05PILifshitz, Rejwan, et al., 1988LL
10.7PEOgden, Shaw, et al., 1983LBLHLM
11.12PEGilman, Hsieh, et al., 1983LBLHLM
11.05PEKatsumata, Shiromaru, et al., 1982LBLHLM
11.28 ± 0.08EIAllam, Migahed, et al., 1982LBLHLM
11.28PEKimura, Katsumata, et al., 1981LLK
11.1PEAsbrink, Svensson, et al., 1981LLK
11.28 ± 0.08EIAllam, Migahed, et al., 1981LLK
11.07 ± 0.01PERabalais, 1972LLK
11.040 ± 0.017PINicholson, 1970RDSH
11.23 ± 0.01PEDewar, Shanshal, et al., 1969RDSH
11.130 ± 0.006PINicholson, 1965RDSH
11.08 ± 0.03PIWatanabe, Nakayama, et al., 1962RDSH
11.29PEBajic, Humski, et al., 1985Vertical value; LBLHLM
11.47PEKatsumata, Shiromaru, et al., 1982Vertical value; LBLHLM
11.31PEKobayashi, 1978Vertical value; LLK
11.8PERao, 1975Vertical value; LLK
11.29PEKobayashi and Nagakura, 1974Vertical value; LLK
11.31 ± 0.015PEKobayashi and Nagakura, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C+22.83 ± 0.05?EIKandel, 1955RDSH
CH2NO2+11.8 ± 0.1HPILifshitz, Rejwan, et al., 1988LL
CH2NO2+11.97 ± 0.02HEIKandel, 1955RDSH
CH3+13.6NO2EIHaney and Franklin, 1968RDSH
CH3+12.6NO2EITsuda and Hamill, 1966RDSH
CH3NO+11.75 ± 0.05OPILifshitz, Rejwan, et al., 1988LL
CH3NO+11.95OPIPECOGilman, Hsieh, et al., 1983LBLHLM
NO+11.75 ± 0.05CH3OPILifshitz, Rejwan, et al., 1988LL
NO+11.5CH3OPEOgden, Shaw, et al., 1983LBLHLM
NO+11.76CH3OPIPECOGilman, Hsieh, et al., 1983LBLHLM
NO+11.7CH3OPIPECONiwa, Tajima, et al., 1981LLK
NO+11.75 ± 0.01?PINicholson, 1970RDSH
NO2+12.1 ± 0.1CH3PILifshitz, Rejwan, et al., 1988LL
NO2+11.97CH3PEOgden, Shaw, et al., 1983LBLHLM
NO2+12.1CH3PIPECONiwa, Tajima, et al., 1981LLK
NO2+13. ± 0.CH3EICollin, 1959RDSH
O+14.50 ± 0.16?EIKandel, 1955RDSH

De-protonation reactions

CH2NO2- + Hydrogen cation = Methane, nitro-

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Δr1498. ± 21.kJ/molD-EAMetz, Cyr, et al., 1991gas phase; B
Δr1491. ± 9.2kJ/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Δr1495. ± 12.kJ/molG+TSCumming and Kebarle, 1978gas phase; B
Quantity Value Units Method Reference Comment
Δr1463. ± 8.4kJ/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Δr1467. ± 8.4kJ/molIMRECumming and Kebarle, 1978gas phase; B
Δr1467. ± 8.4kJ/molIMREMacKay and Bohme, 1978gas phase; EA: < NO2; B

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knobel, Miroshnichenko, et al., 1971
Knobel, Y.K.; Miroshnichenko, E.A.; Lebedev, Y.A., Heats of combustion of nitromethane and dinitromethane: enthalpies of formation of nitromethyl radicals and energies of dissociation of bonds in nitro derivatives of methane, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971, 425-428. [all data]

Lebedeva and Ryadenko, 1973
Lebedeva, N.D.; Ryadenko, V.L.R., Enthalpies of formation of nitroalkanes, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 1382. [all data]

Cass, Fletcher, et al., 1958
Cass, R.C.; Fletcher, S.E.; Mortimer, C.T.; Quincey, P.G.; Springall, H.D., Heats of combustion and molecular structure. Part IV. Aliphatic nitroalkanes and nitric esters, J. Chem. Soc., 1958, 958-962. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Holcomb and Dorsey, 1949
Holcomb, D.E.; Dorsey, C.L., Jr., Thermodynamic properties of nitroparaffins, Ind. Eng. Chem., 1949, 41, 2788-2792. [all data]

Swientoslawski, 1910
Swientoslawski, W., Thermochemische Untersuchungen der organischen Verbindungen. Dritte Mitteilung. Stickstoffhaltige Verbindungen., Z. Phys. Chem., 1910, 72, 49-83. [all data]

Jones and Giauque, 1947
Jones, W.M.; Giauque, W.F., The entropy of nitromethane. Heat capacity of solid and liquid. Vapor pressure, heats of fusion and vaporization, J. Am. Chem. Soc., 1947, 69, 983-987. [all data]

Berman and West, 1969
Berman, H.A.; West, E.D., Heat capacity of liquid nitromethane from 35 to 200°C, J. Chem. Eng. Data, 1969, 14, 107-109. [all data]

Hough, Mason, et al., 1950
Hough, E.W.; Mason, D.M.; Sage, B.H., Heat capacities of several organic liquids, J. Am. Chem. Soc., 1950, 72, 5775-5777. [all data]

Williams, 1925
Williams, J.W., A study of the physical properties of nitromethane, J. Am. Chem. Soc., 1925, 47, 2644-2652. [all data]

Metz, Cyr, et al., 1991
Metz, R.B.; Cyr, D.R.; Neumark, D.M., Study of the 2B1 and 2A2 States of CH2NO2 via Ultraviolet Photoelectron Spectroscopy of the CH2NO2- Anion, J. Phys. Chem., 1991, 95, 7, 2900, https://doi.org/10.1021/j100160a047 . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P., Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A), Can. J. Chem., 1978, 56, 1. [all data]

MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]

Wincel, 2003
Wincel, H., Gas-phase Solvation of Cl-, NO2-, CH2NO2-, CH3NO2-, and CH3NO4- by CH3NO2, Int. J. Mass Spectrom., 2003, 226, 3, 341-353, https://doi.org/10.1016/S1387-3806(03)00066-6 . [all data]

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Riveros, Breda, et al., 1973
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Notes

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