Trichloromethane

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-24.661kcal/molReviewChase, 1998Data last reviewed in December, 1968
Δfgas-24.59 ± 0.60kcal/molReviewManion, 2002derived from recommended ΔfHliquid° and ΔvapH°; DRB
Quantity Value Units Method Reference Comment
gas,1 bar70.652cal/mol*KReviewChase, 1998Data last reviewed in December, 1968

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1200.1200. to 6000.
A 10.5753024.25339
B 27.407600.819731
C -21.22810-0.157110
D 6.1902300.010446
E -0.124954-2.234230
F -29.27560-37.23709
G 75.4648992.53241
H -24.65990-24.65990
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1968 Data last reviewed in December, 1968

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-32.05 ± 0.60kcal/molReviewManion, 2002adopted combustion calorimetry data of Hu and Sinke, 1969 with increased uncertainty to reflect other data; DRB
Δfliquid-32.10kcal/molCcrHu and Sinke, 1969, 2ALS
Quantity Value Units Method Reference Comment
Δcliquid-113.10kcal/molCcrHu and Sinke, 1969, 2ALS
Δcliquid-113.3 ± 2.0kcal/molCcbSmith, Bjellerup, et al., 1953Reanalyzed by Cox and Pilcher, 1970, Original value = -113. ± 2. kcal/mol; ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
27.306298.15Grolier, Roux-Desgranges, et al., 1993DH
27.06298.15Shehatta, 1993DH
27.323298.15Barta, Kooner, et al., 1989DH
27.330298.15Barta, Kooner, et al., 1989, 2DH
27.61298.15Petrov, Peshekhodov, et al., 1989T = 258.15, 278.15, 298.15, 318.15 K.; DH
27.211298.15Grolier, Roux-Desgranges, et al., 1987DH
27.61298.15Al'per, Peshekhodov, et al., 1986DH
27.182298.15Hepler, Kooner, et al., 1985DH
27.309298.15Inglese, Castagnolo, et al., 1981DH
27.77293.Rastorguev and Ganiev, 1967T = 293 to 333 K.; DH
27.10300.Harrison and Moelwyn-Hughes, 1957T = 243 to 303 K.; DH
27.25303.2Harrison and Moelwyn-Hughes, 1957T = 245 to 303 K. Unsmoothed experimental datum.; DH
27.290298.Staveley, Tupman, et al., 1955T = 284 to 329 K.; DH
27.99298.Kurbatov, 1948T = -52 to 51°C. Mean Cp, four temperatures.; DH
33.39303.6Phillip, 1939DH
27.01298.1Richards and Wallace, 1932T = 293 to 323 K.; DH
27.61293.2Williams and Daniels, 1925T = 20 to 50°C.; DH
27.89303.Willams and Daniels, 1924T = 295 to 315 K. Equation only.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Trichloromethane = (Chlorine anion • Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- • CHCl3)

Quantity Value Units Method Reference Comment
Δr15.2 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr19.5 ± 2.0kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr18.10kcal/molMoblGiles and Grimsrud, 1993gas phase; B
Δr18.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Δr19.10 ± 0.70kcal/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KN/ALarson and McMahon, 1984gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Δr24.5cal/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Δr14.8cal/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr11. ± 1.kcal/molAVGN/AAverage of 6 values; Individual data points

CCl3- + Hydrogen cation = Trichloromethane

By formula: CCl3- + H+ = CHCl3

Quantity Value Units Method Reference Comment
Δr360.33kcal/molAcidPaulino and Squires, 1991gas phase; B
Δr357.6 ± 2.1kcal/molG+TSPaulino and Squires, 1991gas phase; B
Δr357.0 ± 6.1kcal/molG+TSBohme, Lee-Ruff, et al., 1972gas phase; > acetone, <= C5H6; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Δr349.9 ± 2.0kcal/molIMRBPaulino and Squires, 1991gas phase; B
Δr349.9 ± 3.0kcal/molIMRBBorn, Ingemann, et al., 2000gas phase; B
Δr349.3 ± 6.0kcal/molIMRBBohme, Lee-Ruff, et al., 1972gas phase; > acetone, <= C5H6; value altered from reference due to change in acidity scale; B

CN- + Trichloromethane = (CN- • Trichloromethane)

By formula: CN- + CHCl3 = (CN- • CHCl3)

Quantity Value Units Method Reference Comment
Δr18.2 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr24.8cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Δr10.8 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M

C8H6MoO3 (solution) + Carbon Tetrachloride (solution) = Molybdenum, tricarbonylchloro(η5-2,4-cyclopentadien-1-yl)- (solution) + Trichloromethane (solution)

By formula: C8H6MoO3 (solution) + CCl4 (solution) = C8H5ClMoO3 (solution) + CHCl3 (solution)

Quantity Value Units Method Reference Comment
Δr-31.81 ± 0.91kcal/molRSCNolan, López de la Vega, et al., 1986solvent: Tetrahydrofuran; The enthalpy of solution of Mo(Cp)(CO)3(H)(cr) was measured as 2.1 ± 0.1 kcal/mol Nolan, López de la Vega, et al., 1986, 2. Reaction temperature: 323 K; MS

Bromine anion + Trichloromethane = (Bromine anion • Trichloromethane)

By formula: Br- + CHCl3 = (Br- • CHCl3)

Quantity Value Units Method Reference Comment
Δr15.80kcal/molMoblGiles and Grimsrud, 1993gas phase; B
Quantity Value Units Method Reference Comment
Δr9.50kcal/molMoblGiles and Grimsrud, 1993gas phase; B

CHCl4- + 2Trichloromethane = C2H2Cl7-

By formula: CHCl4- + 2CHCl3 = C2H2Cl7-

Quantity Value Units Method Reference Comment
Δr14.70kcal/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr7.25kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C2H2Cl7- + 3Trichloromethane = C3H3Cl10-

By formula: C2H2Cl7- + 3CHCl3 = C3H3Cl10-

Quantity Value Units Method Reference Comment
Δr11.80kcal/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr5.24kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C4H9+ + Trichloromethane = (C4H9+ • Trichloromethane)

By formula: C4H9+ + CHCl3 = (C4H9+ • CHCl3)

Quantity Value Units Method Reference Comment
Δr9.1kcal/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.6cal/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

Sodium hydroxide + Chloral = sodium formate + Trichloromethane

By formula: HNaO + C2HCl3O = CHNaO2 + CHCl3

Quantity Value Units Method Reference Comment
Δr-24.58kcal/molCmPritchard and Skinner, 1950liquid phase; Heat of hydrolysis; ALS

Trichloromethane + Chlorine = Carbon Tetrachloride + Hydrogen chloride

By formula: CHCl3 + Cl2 = CCl4 + HCl

Quantity Value Units Method Reference Comment
Δr-22.30kcal/molCmKirkbride, 1956liquid phase; Heat of chlorination; ALS

Iodide + Trichloromethane = (Iodide • Trichloromethane)

By formula: I- + CHCl3 = (I- • CHCl3)

Quantity Value Units Method Reference Comment
Δr14.1 ± 1.0kcal/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M

Trichloromethane + Bromine = Hydrogen bromide + Methane, bromotrichloro-

By formula: CHCl3 + Br2 = HBr + CBrCl3

Quantity Value Units Method Reference Comment
Δr-1.4 ± 0.1kcal/molEqkMendenhall, Golden, et al., 1973gas phase; ALS

2Fluorodichloromethane = Trichloromethane + Difluorochloromethane

By formula: 2CHCl2F = CHCl3 + CHClF2

Quantity Value Units Method Reference Comment
Δr-3.39 ± 0.48kcal/molEqkHess and Kemnitz, 1992gas phase; Gas Phase; ALS

C10H12Mo (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2Mo (cr) + 2Trichloromethane (l)

By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Δr-76.8 ± 1.1kcal/molRSCCalado, Dias, et al., 1979MS

C10H12W (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2W (cr) + 2Trichloromethane (l)

By formula: C10H12W (cr) + 2CCl4 (l) = C10H10Cl2W (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Δr-71.96 ± 0.81kcal/molRSCCalado, Dias, et al., 1979MS

Hydrogen bromide + Methane, bromotrichloro- = Trichloromethane + Bromine

By formula: HBr + CBrCl3 = CHCl3 + Br2

Quantity Value Units Method Reference Comment
Δr1.4kcal/molKinSullivan and Davidson, 1951gas phase; ALS

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman

Quantity Value Units Method Reference Comment
IE (evaluated)11.37 ± 0.02eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.62 ± 0.16IMRBStaneke, Groothuis, et al., 1995EA > EA(CH2S-.), and Cl-A(CHCl2.) < Cl-A(CHCl3). May be ion-molecule complex.; B
1.756 ± 0.052SIGaines, Kay, et al., 1966The Magnetron method, lacking mass analysis, is not considered reliable.; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.41 ± 0.02PIWang and Leroi, 1983LBLHLM
11.3PEVon Niessen, Asbrink, et al., 1982LBLHLM
11.48PEKimura, Katsumata, et al., 1981LLK
11.37 ± 0.02PIWerner, Tsai, et al., 1974LLK
11.40PEDewar and Worley, 1969RDSH
11.50CICermak, 1968RDSH
11.42 ± 0.03PIWatanabe, 1957RDSH
11.5PEVon Niessen, Asbrink, et al., 1982Vertical value; LBLHLM
11.48PEDixon, Murrell, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C+24.62?EIReed and Snedden, 1956RDSH
CCl+16.3 ± 0.2?EIHobrock and Kiser, 1964RDSH
CCl2+12.2?EIShapiro and Lossing, 1968RDSH
CCl3+11.70 ± 0.09HEIMartin, Lampe, et al., 1966RDSH
CH+16.8 ± 1.0Cl2+ClEIOgawa, Miyoshi, et al., 1982LBLHLM
CH+23.9 ± 0.3?EIHobrock and Kiser, 1964RDSH
CHCl+17.5 ± 0.2?EIHobrock and Kiser, 1964RDSH
CHCl2+11.52ClEIHolmes, Lossing, et al., 1988LL
CHCl2+11.49 ± 0.02ClPIWerner, Tsai, et al., 1974LLK
CHCl2+11.52ClEILossing, 1972LLK
CHCl2+11.64 ± 0.20ClEIHobrock and Kiser, 1964RDSH
CHCl2+11.7 ± 0.1ClEIHarrison and Shannon, 1962RDSH
CHCl2+12.43 ± 0.02ClEIReed and Snedden, 1956RDSH
Cl+22.0 ± 0.3?EIHobrock and Kiser, 1964RDSH
H+20.5 ± 1.74H+CCl3EIOgawa, Miyoshi, et al., 1982LBLHLM

De-protonation reactions

CCl3- + Hydrogen cation = Trichloromethane

By formula: CCl3- + H+ = CHCl3

Quantity Value Units Method Reference Comment
Δr360.33kcal/molAcidPaulino and Squires, 1991gas phase; B
Δr357.6 ± 2.1kcal/molG+TSPaulino and Squires, 1991gas phase; B
Δr357.0 ± 6.1kcal/molG+TSBohme, Lee-Ruff, et al., 1972gas phase; > acetone, <= C5H6; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Δr349.9 ± 2.0kcal/molIMRBPaulino and Squires, 1991gas phase; B
Δr349.9 ± 3.0kcal/molIMRBBorn, Ingemann, et al., 2000gas phase; B
Δr349.3 ± 6.0kcal/molIMRBBohme, Lee-Ruff, et al., 1972gas phase; > acetone, <= C5H6; value altered from reference due to change in acidity scale; B

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Hu and Sinke, 1969
Hu, A.T.; Sinke, G.C., Combustion calorimetry of some chlorinated organic compounds, J. Chem. Thermodyn., 1969, 1, 6, 507, https://doi.org/10.1016/0021-9614(69)90010-X . [all data]

Hu and Sinke, 1969, 2
Hu, A.T.; Sinke, G.C., Combustion calorimetry of some chlorinated organic compounds, J. Chem. Thermodyn., 1969, 1, 507-513. [all data]

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide, J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]

Shehatta, 1993
Shehatta, I., Heat capacity at constant pressure of some halogen compounds, Thermochim. Acta, 1993, 213, 1-10. [all data]

Barta, Kooner, et al., 1989
Barta, L.; Kooner, Z.S.; Hepler, L.G.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermodynamics of complex formation in chloroform and 1,4-dioxane, Can. J. Chem., 1989, 67, 1225-1229. [all data]

Barta, Kooner, et al., 1989, 2
Barta, L.; Kooner, Z.S.; Hepler, L.G.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermal and volumetric properties of chloroform dimethylsulfoxide: Thermodynamic analysis using the ideal associated solution model, J. Solution Chem., 1989, 18(7), 663-673. [all data]

Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A., Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Grolier, Roux-Desgranges, et al., 1987
Grolier, J.-P.E.; Roux-Desgranges, G.; Kooner, Z.S.; Smith, J.F.; Hepler, L.G., Thermal and volumetric properties of chloroform + benzene mixtures and the ideal associated solution model of complex formation, J. Solution Chem., 1987, 16, 745-752. [all data]

Al'per, Peshekhodov, et al., 1986
Al'per, G.A.; Peshekhodov, P.B.; Nikiforov, M.Yu.; Petrov, A.N.; Krestov, G.A., Specific heats and features of the intermolecular interactions in the system chloroform-acetone, Zhur. Obshchei Khim., 1986, 56(8), 1688-1691. [all data]

Hepler, Kooner, et al., 1985
Hepler, L.G.; Kooner, Z.S.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermal and volumetric properties of chloroform + triethylamine mixtures and the ideal associated solution model of complex formation, J. Solution Chem., 1985, 14(8), 579-594. [all data]

Inglese, Castagnolo, et al., 1981
Inglese, A.; Castagnolo, M.; Dell'Atti, A.; DeGiglio, A., Thermochim. Acta, 1981, 77-87. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Harrison and Moelwyn-Hughes, 1957
Harrison, D.; Moelwyn-Hughes, E.A., The heat capacities of certain liquids, Proc. Roy. Soc. (London), 1957, A239, 230-246. [all data]

Staveley, Tupman, et al., 1955
Staveley, L.A.K.; Tupman, W.I.; Hart, K.R., Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide, Trans. Faraday Soc., 1955, 51, 323-342. [all data]

Kurbatov, 1948
Kurbatov, V.Ya., Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons, Zh. Obshch. Kim., 1948, 18, 372-389. [all data]

Phillip, 1939
Phillip, N.M., Adiabatic and isothermal compressibilities of liquids, Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]

Richards and Wallace, 1932
Richards, W.T.; Wallace, J.H., Jr., The specific heats of five organic liquids from their adiabatic temperature-pressure coefficients, J. Am. Chem. Soc., 1932, 54, 2705-2713. [all data]

Williams and Daniels, 1925
Williams, J.W.; Daniels, F., The specific heats of binary mixtures, J. Am. Chem. Soc., 1925, 47, 1490-1503. [all data]

Willams and Daniels, 1924
Willams, J.W.; Daniels, F., The specific heats of certain organic liquids at elevated temperatures, J. Am. Chem. Soc., 1924, 46, 903-917. [all data]

Yamdagni and Kebarle, 1971
Yamdagni, R.; Kebarle, P., Hydrogen bonding energies to negative ions from gas phase measurements of ionic equilibria, J. Am. Chem. Soc., 1971, 93, 7139. [all data]

Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S., Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes, J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n . [all data]

Giles and Grimsrud, 1993
Giles, K.; Grimsrud, E.P., Measurements of Equilibria and Reactivity of Cluster Ions at Atmospheric Pressure - Reactions of Cl-(CHCl3)0-2 with CH3Br and CH3I, J. Phys. Chem., 1993, 97, 7, 1318, https://doi.org/10.1021/j100109a012 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria, J. Am. Chem. Soc., 1984, 106, 517. [all data]

Dougherty, Dalton, et al., 1974
Dougherty, R.C.; Dalton, J.; Roberts, J.D., SN2 reactions in the gas phase: Structure of the transition state, Org. Mass Spectrom., 1974, 8, 77. [all data]

Larson and McMahon, 1984, 2
Larson, J.W.; McMahon, T.B., Gas phase negative ion chemistry of alkylchloroformates, Can. J. Chem., 1984, 62, 675. [all data]

Paulino and Squires, 1991
Paulino, J.A.; Squires, R.R., Carbene Thermochemistry from Collision-Induced Dissociation Threshold Energy Measurements - The Heats of Formation of X1A1 CF2 and X1A1 CCl2, J. Am. Chem. Soc., 1991, 113, 15, 5573, https://doi.org/10.1021/ja00015a009 . [all data]

Bohme, Lee-Ruff, et al., 1972
Bohme, D.K.; Lee-Ruff, E.; Young, L.B., Acidity order of selected bronsted acids in the gas phase at 300K, J. Am. Chem. Soc., 1972, 94, 5153. [all data]

Born, Ingemann, et al., 2000
Born, M.; Ingemann, S.; Nibbering, N.M.M., Thermochemical properties of halogen-substituted methanes, methyl radicals, and carbenes in the gas phase, Int. J. Mass Spectrom., 2000, 194, 2-3, 103-113, https://doi.org/10.1016/S1387-3806(99)00125-6 . [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Organometal. Chem., 1986, 315, 187. [all data]

Nolan, López de la Vega, et al., 1986, 2
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., Organometallics, 1986, 5, 2529. [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heats of hydrolysis of chloral and bromal, and the C-C bond dissociation energies in chloral and bromal, J. Am. Chem. Soc., 1950, 1928-1931. [all data]

Kirkbride, 1956
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Notes

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