Sodium trimer
- Formula: Na3
- Molecular weight: 68.96930784
- CAS Registry Number: 37279-42-8
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.019 ± 0.060 | LPES | McHugh, Eaton, et al., 1989 | Vertical Detachment Energy: 1.158±0.010 eV; B |
| 1.02001 | LPES | Arnold, Eaton, et al., 1989 | Stated electron affinity is the Vertical Detachment Energy; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.97 ± 0.05 | PI | Herrmann, Leutwyler, et al., 1978 | LLK |
| 3.9 ± 0.1 | PI | Robbins, Leckenby, et al., 1967 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
McHugh, Eaton, et al., 1989
McHugh, K.M.; Eaton, J.G.; Lee, G.H.; Sarkas, H.W.; Kidder, L.H.; Snodgrass, J.T.; Manaa, M.R.; Bowen, K.H.,
Photoelectron Spectra of the alkali metal cluster Anions: Na-,n=2-5, K-,n=2-7, Rb-,n=2-3, and Cs-,n=2-3,
J. Chem. Phys., 1989, 91, 6, 3792, https://doi.org/10.1063/1.456861
. [all data]
Arnold, Eaton, et al., 1989
Arnold, S.T.; Eaton, J.G.; Patel-Misra, D.; Sarkas, H.W.; Bowen, K.H.,
Ion and Cluster Ion Spectroscopy and Structure,, J.P. Maier, Ed., Elsevier, Amsterdam,, 1989, 417. [all data]
Herrmann, Leutwyler, et al., 1978
Herrmann, A.; Leutwyler, S.; Schumacher, E.; Woste, L.,
38. On metal-atom clusters IV. Photoionization thresholds and multiphoton ionization spectra of alkali-metal molecules,
Helv. Chim. Acta, 1978, 61, 453. [all data]
Robbins, Leckenby, et al., 1967
Robbins, E.J.; Leckenby, R.E.; Willis, P.,
The ionization potentials of clustered sodium atoms,
Advan. Phys., 1967, 16, 739. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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