Strontium monoxide


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-123.64kcal/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
liquid,1 bar19.32cal/mol*KReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
Δfsolid-141.50kcal/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
solid13.25cal/mol*KReviewChase, 1998Data last reviewed in December, 1972

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2938. to 5000.
A 16.00000
B 2.773980×10-8
C -6.244652×10-9
D 4.854432×10-10
E 4.238672×10-8
F -132.6130
G 32.83970
H -123.6360
ReferenceChase, 1998
Comment Data last reviewed in December, 1972

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 2938.
A 11.60400
B 2.090831
C -0.213663
D 0.027499
E -0.121368
F -145.4670
G 25.99161
H -141.5000
ReferenceChase, 1998
Comment Data last reviewed in December, 1972

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)6.6 ± 0.2eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)289.0kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity282.19kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
6.60 ± 0.18END/DERDalleska and Armentrout, 1994LL
6.4 ± 0.25EVALBelyaev, Gotkis, et al., 1990LL
6.60 ± 0.05PEDyke, Feher, et al., 1987LBLHLM
7.0 ± 0.15DERMurad, 1983LBLHLM
7.0 ± 0.2EIMurad, 1981LLK
7. ± 1.EIFarber and Srivastava, 1976LLK
6.1EIDrowart, Exsteen, et al., 1964RDSH
6.91 ± 0.02PEDyke, Feher, et al., 1987Vertical value; LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Dalleska and Armentrout, 1994
Dalleska, N.F.; Armentrout, P.B., Guided ion beam studies of reactions of alkaline earth ions with O2, Int. J. Mass Spectrom. Ion Processes, 1994, 134, 203. [all data]

Belyaev, Gotkis, et al., 1990
Belyaev, V.N.; Gotkis, I.S.; Lebedeva, N.L.; Krasnov, K.S., Ionization potentials of MX molecules (M = Ca, Sr, Ba; X = F, Cl, Br, I, OH, O), Russ. J. Phys. Chem., 1990, 64, 773. [all data]

Dyke, Feher, et al., 1987
Dyke, J.M.; Feher, M.; Gravenor, B.W.J.; Morris, A., High-temperature photoelectron spectroscopy: A study of the alkaline earth oxides SrO and BaO, J. Phys. Chem., 1987, 91, 4476. [all data]

Murad, 1983
Murad, E., Abstraction reactions of Ca+ and Sr+ ions, J. Chem. Phys., 1983, 78, 6611. [all data]

Murad, 1981
Murad, E., Thermochemical properties of the gaseous alkaline earth monohydroxides, J. Chem. Phys., 1981, 75, 4080. [all data]

Farber and Srivastava, 1976
Farber, M.; Srivastava, R.D., The dissociation energies of calcium oxide and strontium oxide, High Temp. Sci., 1976, 8, 73. [all data]

Drowart, Exsteen, et al., 1964
Drowart, J.; Exsteen, G.; Verhaegen, G., Mass spectrometric determination of the dissociation energy of the molecules MgO, CaO, SrO and Sr2O, J. Chem. Soc. Faraday Trans., 1964, 60, 1920. [all data]


Notes

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