Ethylene
- Formula: C2H4
- Molecular weight: 28.0532
- IUPAC Standard InChIKey: VGGSQFUCUMXWEO-UHFFFAOYSA-N
- CAS Registry Number: 74-85-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Ethene; Acetene; Bicarburretted hydrogen; Elayl; Olefiant gas; C2H4; Athylen; Liquid ethyene; UN 1038; UN 1962
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Condensed phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°liquid | 117.8 | J/mol*K | N/A | Chao, Hall, et al., 1983 |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
67.4 | 170. | Chao, Hall, et al., 1983 | T = 16 to 169 K. |
67.24 | 170. | Egan and Kemp, 1937 | T = 15 to 170 K. |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
C2H3- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1704. ± 9. | kJ/mol | AVG | N/A | Average of 5 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1677.8 ± 2.1 | kJ/mol | IMRE | Ervin, Gronert, et al., 1990 | gas phase; B |
ΔrG° | 1670. ± 8.8 | kJ/mol | H-TS | DePuy, Gronert, et al., 1989 | gas phase; B |
ΔrG° | 1668. ± 21. | kJ/mol | H-TS | Peerboom, Rademaker, et al., 1992 | gas phase; B |
ΔrG° | >1661.0 | kJ/mol | IMRB | Froelicher, Freiser, et al., 1986 | gas phase; B |
C7H4CrO5 (g) = C5CrO5 (g) + (g)
By formula: C7H4CrO5 (g) = C5CrO5 (g) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 105. ± 4. | kJ/mol | KinG | McNamara, Becher, et al., 1994 | The reaction enthalpy was identified with the activation energy.; MS |
ΔrH° | 103. ± 10. | kJ/mol | KinG | Wells, House, et al., 1994 | The reaction enthalpy relies on the measured activation energy and on the assumption of a negligible barrier for product recombination Wells, House, et al., 1994.; MS |
By formula: Ag+ + C2H4 = (Ag+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 141. | kJ/mol | HPMS | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92.5 | J/mol*K | N/A | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
71.5 | 750. | HPMS | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: H4N+ + C2H4 = (H4N+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 294. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
By formula: Co+ + C2H4 = (Co+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. ± 9.2 | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
179. (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
27. (+13.,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: C2H5Cl = C2H4 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 92.0 | kJ/mol | Eqk | Levanova, Bushneva, et al., 1979 | liquid phase; ALS |
ΔrH° | 71.5 | kJ/mol | Eqk | Levanova, Bushneva, et al., 1979 | gas phase; ALS |
ΔrH° | 72.6 ± 2.1 | kJ/mol | Eqk | Howlett, 1955 | gas phase; ALS |
ΔrH° | 71.5 | kJ/mol | Eqk | Lane, Linnett, et al., 1953 | gas phase; ALS |
By formula: Cr+ + C2H4 = (Cr+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 96. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
125. (+19.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Ni+ + C2H4 = (Ni+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 182. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
138. (+19.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Cu+ + C2H4 = (Cu+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
95. (+11.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Sc+ + C2H4 = (Sc+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
131. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH >=, guided ion beam CID; M |
By formula: La+ + C2H4 = (La+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
90.0 | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Y+ + C2H4 = (Y+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
109. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Ti+ + C2H4 = (Ti+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 146. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
119. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: V+ + C2H4 = (V+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 125. ± 7.9 | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
117. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Fe+ + C2H4 = (Fe+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 145. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
145. (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: C2H4 + Br2 = C2H4Br2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -120.9 ± 1.3 | kJ/mol | Cm | Conn, Kistiakowsky, et al., 1938 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -121.6 ± 1.3 kJ/mol; At 355 °K; ALS |
By formula: C2H4 + I2 = C2H4I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -48.1 ± 0.8 | kJ/mol | Eqk | Abrams and Davis, 1954 | gas phase; ALS |
ΔrH° | -56. ± 2. | kJ/mol | Eqk | Cutherbertson and Kistiakowsky, 1935 | gas phase; Heat of dissociation; ALS |
By formula: (Ag+ • C2H4) + C2H4 = (Ag+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. | kJ/mol | HPMS | Guo and Castleman, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 126. | J/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -136. ± 2. | kJ/mol | Chyd | Kistiakowsky and Nickle, 1951 | gas phase; ALS |
ΔrH° | -136.3 ± 0.3 | kJ/mol | Chyd | Kistiakowsky, Romeyn, et al., 1935 | gas phase; ALS |
By formula: C2H5Br = HBr + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 80.3 ± 2.1 | kJ/mol | Eqk | Lane, Linnett, et al., 1953 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 79.9 kJ/mol; ALS |
By formula: C3H9Si+ + C2H4 = (C3H9Si+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.7 | kJ/mol | PHPMS | Li and Stone, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 161. | J/mol*K | PHPMS | Li and Stone, 1989 | gas phase; M |
By formula: C2H4+ + C2H4 = (C2H4+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.1 | kJ/mol | PI | Ono, Linn, et al., 1984 | gas phase; M |
ΔrH° | 76.1 | kJ/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase; M |
C6H4FeO4 (l) = 4 (g) + (cr) + (g)
By formula: C6H4FeO4 (l) = 4CO (g) + Fe (cr) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 192.5 ± 8.4 | kJ/mol | HAL-HFC | Brown, Connor, et al., 1976 | MS |
ΔrH° | 185.4 | kJ/mol | TD-HFC | Brown, Connor, et al., 1976 | MS |
By formula: C8H12 = C6H8 + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. | kJ/mol | Kin | Huybrechts, Rigaux, et al., 1980 | gas phase; Diels-Alder addition at 560°K, see Van Mele, Boon, et al., 1986; ALS |
By formula: F- + C2H4 = (F- • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 25. ± 13. | kJ/mol | IMRB | Sullivan and Beauchamp, 1976 | gas phase; Structure: Roy and McMahon, 1985; B |
By formula: Rh+ + C2H4 = (Rh+ • C2H4)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
161. (+3.,-0.) | CID | Chen and Armetrout, 1995 | gas phase; guided ion beam CID; M |
C7H9Cl2NPd (solution) + (l) = (PdCl2(C5H5N)2) (solution) + (solution)
By formula: C7H9Cl2NPd (solution) + C4H4N2 (l) = (PdCl2(C5H5N)2) (solution) + C2H4 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -57.7 ± 1.7 | kJ/mol | RSC | Partenheimer and Durham, 1974 | solvent: Dichloromethane; MS |
(solution) + (solution) = C13H19O2Rh (solution) + 2 (solution)
By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -9.0 ± 0.4 | kJ/mol | RSC | Jesse, Cordfunke, et al., 1979 | solvent: n-Heptane; MS |
(g) + C2H3BrMg (solution) = (solution) + Br2Mg (solution)
By formula: HBr (g) + C2H3BrMg (solution) = C2H4 (solution) + Br2Mg (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -294.1 ± 2.2 | kJ/mol | RSC | Holm, 1981 | solvent: Tetrahydrofuran; MS |
By formula: C6HCrO6+ + C2H4 = (C6HCrO6+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 ± 5.0 | kJ/mol | ICRCD | Hop and McMahon, 1991 | gas phase; Ar collision gas; M |
By formula: Al+ + C2H4 = (Al+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.4 ± 8.4 | kJ/mol | CIDC,EqG | Stockigt, Schwarz, et al., 1996 | Anchored to theory; RCD |
(CAS Reg. No. 25013-41-6 • 4294967295) + = CAS Reg. No. 25013-41-6
By formula: (CAS Reg. No. 25013-41-6 • 4294967295C2H4) + C2H4 = CAS Reg. No. 25013-41-6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 ± 8.8 | kJ/mol | N/A | DePuy, Gronert, et al., 1989 | gas phase; B |
By formula: H2 + C2H3Cl = C2H4 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -76.94 | kJ/mol | Chyd | Lacher, Kianpour, et al., 1956 | gas phase; At 298 K; ALS |
By formula: C2H4 + Cl2 = C2H4Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -182.6 ± 0.63 | kJ/mol | Cm | Conn, Kistiakowsky, et al., 1938 | gas phase; At 355 °K; ALS |
By formula: C2H4ClI = I + Cl + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 320. ± 4.2 | kJ/mol | Kin | Minton, Felder, et al., 1984 | gas phase; ALS |
By formula: (C2H4+ • C2H4) + C2H4 = (C2H4+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase; M |
C12H14Mo (cr) + (cr) = C10H10I2Mo (cr) + (g)
By formula: C12H14Mo (cr) + I2 (cr) = C10H10I2Mo (cr) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -163.0 ± 2.1 | kJ/mol | RSC | Calhorda, Carrondo, et al., 1991 | MS |
By formula: C9H15O2Rh (cr) + 2CO (g) = C7H7O4Rh (cr) + 2C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -53.6 ± 1.7 | kJ/mol | DSC | Jesse, Baks, et al., 1978 | MS |
C9H15IrO2 (cr) + 2 (g) = C7H7IrO4 (cr) + 2 (g)
By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -74.1 ± 4.6 | kJ/mol | DSC | Jesse, Baks, et al., 1978 | MS |
By formula: (Fe+ • C2H4) + C2H4 = (Fe+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 151. ± 15. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Cr+ • C2H4) + C2H4 = (Cr+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Mn+ • C2H4) + C2H4 = (Mn+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 88. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 127. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Ni+ • C2H4) + C2H4 = (Ni+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 152. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Cu+ • C2H4) + C2H4 = (Cu+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. ± 13. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: C7H10 = C5H6 + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 97.2 ± 2.5 | kJ/mol | Eqk | Walsh and Wells, 1976 | gas phase; ALS |
By formula: 2C2H4 = C4H8
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -86.6 ± 4.2 | kJ/mol | Eqk | Quick, Knecht, et al., 1972 | gas phase; At 750 K; ALS |
By formula: C2H4I2 = C2H4 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.1 ± 0.8 | kJ/mol | Eqk | Benson and Amano, 1962 | gas phase; ALS |
By formula: C4H8 + C2H4 = C6H12
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -69.9 | kJ/mol | Eqk | Scacchi and Back, 1977 | liquid phase; ALS |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C2H4+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 10.5138 ± 0.0006 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 680.5 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 651.5 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°(+) ion | 1067. ± 0.8 | kJ/mol | N/A | N/A | |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH(+) ion,0K | 1080. | kJ/mol | N/A | N/A |
Ionization energy determinations
Appearance energy determinations
De-protonation reactions
C2H3- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1704. ± 9. | kJ/mol | AVG | N/A | Average of 5 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1677.8 ± 2.1 | kJ/mol | IMRE | Ervin, Gronert, et al., 1990 | gas phase; B |
ΔrG° | 1670. ± 8.8 | kJ/mol | H-TS | DePuy, Gronert, et al., 1989 | gas phase; B |
ΔrG° | 1668. ± 21. | kJ/mol | H-TS | Peerboom, Rademaker, et al., 1992 | gas phase; B |
ΔrG° | >1661.0 | kJ/mol | IMRB | Froelicher, Freiser, et al., 1986 | gas phase; B |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chao, Hall, et al., 1983
Chao, J.; Hall, K.R.; Yao, J.M.,
Thermodynamic properties of simple alkenes,
Thermochim. Acta, 1983, 64(3), 285-303. [all data]
Egan and Kemp, 1937
Egan, C.J.; Kemp, J.D.,
Ethylene. The heat capacity from 15°K to the boiling point. The heats of fusion and vaporization. The vapor pressure of the liquid. The entropy from thermal measurements compared with the entropy from spectroscopic data,
J. Am. Chem. Soc., 1937, 59, 1264-1268. [all data]
Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C.,
Bonds Strengths of Ethylene and Acetylene,
J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013
. [all data]
DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R.,
The Gas Phase Acidities of the Alkanes,
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. [all data]
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Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,liquid Constant pressure heat capacity of liquid IE (evaluated) Recommended ionization energy S°liquid Entropy of liquid at standard conditions T Temperature ΔfH(+) ion,0K Enthalpy of formation of positive ion at 0K ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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