calcium oxide


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-557.33kJ/molReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
liquid,1 bar62.31J/mol*KReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
Δfsolid-634.92 ± 0.90kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfsolid-635.09kJ/molReviewChase, 1998Data last reviewed in June, 1973
Quantity Value Units Method Reference Comment
solid,1 bar38.1 ± 0.4J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid38.19J/mol*KReviewChase, 1998Data last reviewed in June, 1973

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3200. to 4500.
A 62.76000
B 4.629681×10-7
C -1.092037×10-7
D 8.966312×10-9
E 6.504656×10-7
F -591.8059
G 116.8909
H -557.3339
ReferenceChase, 1998
Comment Data last reviewed in June, 1973

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 3200.
A 49.95403
B 4.887916
C -0.352056
D 0.046187
E -0.825097
F -652.9718
G 92.56096
H -635.0894
ReferenceChase, 1998
Comment Data last reviewed in June, 1973

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)6.66 ± 0.18eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)1190.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity1162.3kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
6.66 ± 0.18END/DERDalleska and Armentrout, 1994LL
6.5 ± 0.3EVALBelyaev, Gotkis, et al., 1990LL
7. ± 1.EIFarber, Srivastava, et al., 1987LBLHLM
6.9 ± 0.15DERMurad, 1983LBLHLM
7. ± 1.EIFarber and Srivastava, 1976LLK
6.5EIDrowart, Exsteen, et al., 1964RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Dalleska and Armentrout, 1994
Dalleska, N.F.; Armentrout, P.B., Guided ion beam studies of reactions of alkaline earth ions with O2, Int. J. Mass Spectrom. Ion Processes, 1994, 134, 203. [all data]

Belyaev, Gotkis, et al., 1990
Belyaev, V.N.; Gotkis, I.S.; Lebedeva, N.L.; Krasnov, K.S., Ionization potentials of MX molecules (M = Ca, Sr, Ba; X = F, Cl, Br, I, OH, O), Russ. J. Phys. Chem., 1990, 64, 773. [all data]

Farber, Srivastava, et al., 1987
Farber, M.; Srivastava, R.D.; Moyer, J.W.; Leeper, J.D., Effusion mass spectrometric determination of thermodynamic properties of the gaseous mono- and di-hydroxides of calcium and KCaO(g), J. Chem. Soc. Faraday Trans. 2, 1987, 83, 3229. [all data]

Murad, 1983
Murad, E., Abstraction reactions of Ca+ and Sr+ ions, J. Chem. Phys., 1983, 78, 6611. [all data]

Farber and Srivastava, 1976
Farber, M.; Srivastava, R.D., The dissociation energies of calcium oxide and strontium oxide, High Temp. Sci., 1976, 8, 73. [all data]

Drowart, Exsteen, et al., 1964
Drowart, J.; Exsteen, G.; Verhaegen, G., Mass spectrometric determination of the dissociation energy of the molecules MgO, CaO, SrO and Sr2O, J. Chem. Soc. Faraday Trans., 1964, 60, 1920. [all data]


Notes

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