Stannane, tetraphenyl-
- Formula: C24H20Sn
- Molecular weight: 427.126
- IUPAC Standard InChIKey: CRHIAMBJMSSNNM-UHFFFAOYSA-N
- CAS Registry Number: 595-90-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraphenylstannane; Tetraphenyltin; Tin, tetraphenyl-,
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Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 600. ± 400. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -13293.4 ± 5.4 | kJ/mol | CC-SB | Adams, Carson, et al., 1969 | Please also see Pedley and Rylance, 1977.; MS |
ΔcH°solid | -13368. ± 13. | kJ/mol | CC-SB | Tel'noi and Rabinovich, 1965 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -13295.6 ± 3.4 | kJ/mol | CC-SB | Pope and Skinner, 1964 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -13566.6 ± 7.1 | kJ/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -13839. ± 13. | kJ/mol | CC-SB | Birr, 1962 | MS |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
426.3 | 298.5 | Smith and Andrews, 1931 | T = 102 to 346 K. Value is unsmoothed experimental datum.; DH |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.1 | PE | Novak and Potts, 1984 | LBLHLM |
8.34 ± 0.03 | PI | Rodionov, Potapov, et al., 1973 | LLK |
9.04 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C6H5Sn+ | 16.1 ± 0.5 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
C12H10Sn+ | 9.1 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
C18H15Sn+ | 9.6 ± 0.2 | ? | EI | Chambers and Glockling, 1970 | RDSH |
C18H15Sn+ | 10.1 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
Sn+ | 9.4 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G.,
J. Chem. Thermodyn., 1969, 1, 393. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. J. Phys. Chem., 1965, 39, 1239. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A.,
Trans. Faraday Soc., 1964, 60, 1402. [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Birr, 1962
Birr, K.-H.,
Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H.,
Thermal energy studies. II. Phenyl derivatives of metals,
J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives,
J. Organomet. Chem., 1984, 262, 17. [all data]
Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L.,
Photoionization of certain aromatic heteroorganic compounds,
High Energy Chem., 1973, 7, 249, In original 278. [all data]
Occolowitz, Lett. 1966
Occolowitz, J.L.,
Electron impact fragmentation of some organotin compounds,
Tetrahedron, Lett. 1966, 5291. [all data]
Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F.,
Electron impact determination of heats of formation and bond energies in triphenyltin compounds,
Inorg. Chim. Acta, 1970, 4, 150. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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