Platinum, (η5-2,4-cyclopentadien-1-yl)trimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas58.77 ± 0.76kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub18.6 ± 0.48kcal/molN/APilcher and Skinner, 1983See also Tel'noi and Rabinovich, 1977.; AC
Δsub18.6 ± 0.50kcal/molCC-SBTel'noi and Rabinovich, 1977, 2MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
7.90PEYang, Bancroft, et al., 1990Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Thermochemistry of organic compounds of transition metals, Usp. Khim., 1977, 46, 8, 1337. [all data]

Tel'noi and Rabinovich, 1977, 2
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Yang, Bancroft, et al., 1990
Yang, D.S.; Bancroft, G.M.; Puddephatt, R.J.; Tan, K.H.; Cutler, J.N.; Bozek, J.D., Assignment of the valence molecular orbitals of CpPtMe3 and Me2Pt(COD) using variable-energy photoelectron spectra, Inorg. Chem., 1990, 29, 4956. [all data]


Notes

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