Methanimidamide, N,N-dimethyl-N'-phenyl-

• Formula: C₉H₁₂N₂
• Molecular weight: 148.2050
• IUPAC Standard InChI: InChI=1S/C9H12N2/c1-11(2)8-10-9-6-4-3-5-7-9/h3-8H,1-2H3 Copy

  
• IUPAC Standard InChIKey: SRPCLECGIYMIMN-UHFFFAOYSA-N Copy
• CAS Registry Number: 1783-25-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Stereoisomers:
  • (CH3)2N-CH=N-phenyl
• Other names: Formamidine, N,N-dimethyl-N'-phenyl-; N,N-Dimethyl-N'-phenylformamidine; N'-Phenyl-N,N-dimethylformamidine; Formamidine, 3,3-dimethyl-1-phenyl; N1N1-dimethyl-N2-phenylformamidine
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • IR Spectrum
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Reduced pressure boiling point

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Appearance energy determinations

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Kuschel and Grutzmacher, 1974
Kuschel, H.; Grutzmacher, H.-F., Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XIII. Einfluβ der dissoziationsenergie auf intramolekulare aromatische substitutionen in den molekul- ionen von N,N-dimethyl- N'-phenylformamidinen, Org. Mass Spectrom., 1974, 9, 408. [all data]

Kuschel and Grutzmacher, 1974, 2
Kuschel, H.; Grutzmacher, H.-F., Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XI. EinfluB von substituenten auf die bildung cyclischer fragment-ionen in den massenspektren von N,N-dimethyl-N'-2-chlorphenylformamidinen und 2-chlorformaniliden, Org. Mass Spectrom., 1974, 9, 395. [all data]

Dolecka, Raczynska, et al., 1988
Dolecka, E.; Raczynska, E.D.; Drapala, T., Retention indices and basicity of N¹N¹-dimethyl-N²-phenylformamidines ortho-substituent effect, J. Chem. Soc. Perkin Trans. 2:, 1988, 3, 257-260, https://doi.org/10.1039/p29880000257 . [all data]

Osek, Oszczapowicz, et al., 1986
Osek, J.; Oszczapowicz, J.; Drzewinski, W., Prediction of Retention Indices of N¹,N¹-Dialkylformamidines on a Non-Polar Column, J. Chromatogr., 1986, 351, 177-182, https://doi.org/10.1016/S0021-9673(01)83486-5 . [all data]

Oszczapowicz, Osek, et al., 1984
Oszczapowicz, J.; Osek, J.; Dolecka, E., Retention indices of dimethylformamidines, dimethylacetamidines and tetramethylguanidines on a non-polar column, J. Chromatogr., 1984, 315, 95-100, https://doi.org/10.1016/S0021-9673(01)90727-7 . [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  Tboil	Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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