(Z)-5-Decene
- Formula: C10H20
- Molecular weight: 140.2658
- IUPAC Standard InChIKey: UURSXESKOOOTOV-KTKRTIGZSA-N
- CAS Registry Number: 7433-78-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (Z)-5-C10H20; cis-5-Decene; 5-Decene, (Z)-
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 160. | K | N/A | Benkeser, Schroll, et al., 1955 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 162. | K | N/A | Campbell and Young, 1943 | Uncertainty assigned by TRC = 1. K; TRC |
Tfus | 161. | K | N/A | Campbell and Eby, 1941 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 161.15 | K | N/A | Campbell and Eby, 1941, 2 | Uncertainty assigned by TRC = 1.5 K; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
10.3 | 412. | A | Stephenson and Malanowski, 1987 | Based on data from 397. to 443. K.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: H2 + C10H20 = C10H22
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -28.56 ± 0.35 | kcal/mol | Chyd | Rogers and Siddiqui, 1975 | liquid phase; solvent: n-Hexane |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.773 ± 0.006 | PI | Rang, Martinson, et al., 1974 | LLK |
8.766 ± 0.005 | PE | Masclet, Grosjean, et al., 1973 | LLK |
8.94 ± 0.01 | PE | Krause, Taylor, et al., 1978 | Vertical value; LLK |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | Copyright (C) 1987 by the Coblentz Society Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | COLGATE-PALMOLIVE COMPANY (KELLENBACH) |
Source reference | COBLENTZ NO. 9782 |
Date | 1967/01/26 |
Name(s) | (5Z)-5-decene 5-Decene, cis- |
State | LIQUID (NEAT) PURITY 96% SOURCE - CHEMICAL SAMPLES CO. |
Instrument | BECKMAN IR-12 (GRATING) |
Instrument parameters | GRATING |
Path length | 0.01056 CM |
Resolution | 2 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | S.A. Rang et al., IR & MS of Unsatd. Hydrocarbons, 1977 |
NIST MS number | 142594 |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Squalane | 100. | 982. | Heinzen, Soares, et al., 1999 | |
Capillary | OV-101 | 40. | 990. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 60. | 991. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 80. | 992. | Laub and Purnell, 1988 | |
Capillary | OV-101 | 110. | 992. | Rang, Kuningas, et al., 1987 | He; Column length: 50. m; Column diameter: 0.25 mm |
Capillary | Squalane | 100. | 982. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 115. | 982. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 86. | 981. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Apiezon L | 100. | 991.6 | Eisen, Orav, et al., 1972 | Column length: 45. m; Column diameter: 0.25 mm |
Capillary | Apiezon L | 120. | 992.4 | Eisen, Orav, et al., 1972 | Column length: 45. m; Column diameter: 0.25 mm |
Capillary | Squalane | 115. | 982.1 | Soják and Bucinská, 1970 | N2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 86. | 981.0 | Soják and Bucinská, 1970 | N2; Column length: 200. m; Column diameter: 0.2 mm |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | PEG 4000 | 100. | 1047. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 110. | 1047. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 120. | 1048. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 70. | 1042. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 80. | 1043. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 100. | 1042. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 110. | 1044. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 90. | 1042. | Rang, Orav, et al., 1988 | |
Capillary | Polyethylene Glycol 4000 | 100. | 1047.0 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Polyethylene Glycol 4000 | 120. | 1047.7 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Polyethylene Glycol 4000 | 70. | 1041.9 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 100. | 1047. | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 120. | 1047.7 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 70. | 1041.9 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-101 | 990. | Orav, Kailas, et al., 1999 | 50. m/0.20 mm/0.50 μm, Helium, 30. C @ 6. min, 1. K/min; Tend: 100. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane | 982. | Junkes, Castanho, et al., 2003 | Program: not specified |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Benkeser, Schroll, et al., 1955
Benkeser, R.A.; Schroll, G.; Sauve, D.M.,
J. Am. Chem. Soc., 1955, 77, 3378. [all data]
Campbell and Young, 1943
Campbell, K.N.; Young, E.E.,
Addition of hydrogen to multiple carbon-carbon bonds: IV the electrolytic reduction of alkyl and aryl acetylenes,
J. Am. Chem. Soc., 1943, 65, 965. [all data]
Campbell and Eby, 1941
Campbell, K.N.; Eby, L.T.,
The preparation of higher cis and trans olefins,
J. Am. Chem. Soc., 1941, 63, 216. [all data]
Campbell and Eby, 1941, 2
Campbell, K.N.; Eby, L.T.,
The Reduction of Multiple Carbon-Carbon Bonds III. Further Studies on the Preparation of Olefins from Acetylenes,
J. Am. Chem. Soc., 1941, 63, 2683. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Rogers and Siddiqui, 1975
Rogers, D.W.; Siddiqui, N.A.,
Heats of hydrogenation of large molecules. I. Esters of unsaturated fatty acids,
J. Phys. Chem., 1975, 79, 574-577. [all data]
Rang, Martinson, et al., 1974
Rang, S.; Martinson, E.; Muurisepp, M.,
Ionization potentials of unsaturated hydrocarbons. 1. n-Alkenes, Eesti NSV Teaduste Akadeemia Toimetised 23,
Eesti. NSV Tead. Akad. Toim., 1974, 352. [all data]
Masclet, Grosjean, et al., 1973
Masclet, P.; Grosjean, D.; Mouvier, G.,
Alkene ionization potentials. Part I. Quantitative determination of alkyl group structural effects,
J. Electron Spectrosc. Relat. Phenom., 1973, 2, 225. [all data]
Krause, Taylor, et al., 1978
Krause, D.A.; Taylor, J.W.; Fenske, R.F.,
An analysis of the effects of alkyl substituents on the ionization potentials of n-alkenes,
J. Am. Chem. Soc., 1978, 100, 718. [all data]
Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A.,
Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes,
J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0
. [all data]
Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H.,
Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908
. [all data]
Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O.,
Retention and Thermodynamics of Solution of n-Alkenes in OV-101,
J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4
. [all data]
Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J.,
Capillary Gas Chromatography of Linear Alkenes on Squalane,
Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039
. [all data]
Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S.,
Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire,
Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600
. [all data]
Soják and Bucinská, 1970
Soják, L.; Bucinská, A.,
Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics,
J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4
. [all data]
Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G.,
Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]
Orav and Eisen, 1972
Orav, A.; Eisen, O.,
The retention indexes for alkenes, alkynes and cyclenes on capillary columns,
Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]
Orav, Kailas, et al., 1999
Orav, A.; Kailas, T.; Muurisepp, M.; Kann, J.,
Composition of the oil from waste tires. 1. Fraction boiling at yp to 160 0C,
Proc. Estonian Acad. Sci. Chem., 1999, 48, 1, 30-39. [all data]
Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F.,
Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies,
Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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