potassium metaborate
- Formula: BKO2
- Molecular weight: 81.908
- CAS Registry Number: 13709-94-9
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -980.73 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1971 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 88.44 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1971 |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | -994.96 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1971 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 79.97 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1971 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 1220. to 2000. |
---|---|
A | 146.4400 |
B | -3.790454×10-7 |
C | 2.080155×10-7 |
D | -3.939274×10-8 |
E | -3.941705×10-8 |
F | -1055.493 |
G | 202.3868 |
H | -980.7296 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1971 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1220. |
---|---|
A | 41.74954 |
B | 119.6164 |
C | -71.80664 |
D | 15.10098 |
E | -0.390727 |
F | -1013.432 |
G | 95.68557 |
H | -994.9552 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1971 |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.17 ± 0.22 | EIAE | Shevchenko, Iljin, et al., 1976 | From K2BO2F; value altered from reference due to conversion from electron convention to ion convention; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8. ± 1. | EI | Farber and Srivastava, 1985 | LBLHLM |
8.62 ± 0.14 | EI | Shevchenko, Iljin, et al., 1976 | LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
K+ | 9.47 ± 0.20 | BO2 | EI | Shevchenko, Iljin, et al., 1976 | LLK |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Shevchenko, Iljin, et al., 1976
Shevchenko, V.E.; Iljin, M.K.; Nikitin, O.T.; Sidorov, L.N.,
Mass-spectrometric study of mixed dimers M2BO2F,
Int. J. Mass Spectrom. Ion Phys., 1976, 21, 279. [all data]
Farber and Srivastava, 1985
Farber, M.; Srivastava, R.D.,
Electron impact and thermodynamic studies of potassium metaborate,
J. Chem. Soc. Faraday Trans. 1, 1985, 81, 913. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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