Fluoroimidogen
- Formula: FN
- Molecular weight: 33.0051
- IUPAC Standard InChI: InChI=1S/FN/c1-2
- IUPAC Standard InChIKey: CMUBZTZNXGBJMQ-UHFFFAOYSA-N
- CAS Registry Number: 13967-06-1
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess
View reactions leading to FN+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.499990 | EIAE | Sidirov, 1982 | value altered from reference due to conversion from electron convention to ion convention; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.1 ± 0.4 | EI | Tarnovsky, Levin, et al., 1994 | LL |
| 12.26 ± 0.01 | PE | Dyke, Jonathan, et al., 1982 | LBLHLM |
| 12.63 ± 0.01 | PE | Dyke, Jonathan, et al., 1982 | Vertical value; LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sidirov, 1982
Sidirov, L.N.,
Molecules with a high electron affinity,
Russ. Chem. Rev., 1982, 51, 356. [all data]
Tarnovsky, Levin, et al., 1994
Tarnovsky, V.; Levin, A.; Becker, K.,
Absolute cross sections for the electron impact ionization of the NF2 and NF free radicals,
J. Chem. Phys., 1994, 100, 5626. [all data]
Dyke, Jonathan, et al., 1982
Dyke, J.M.; Jonathan, N.; Lewis, A.E.; Morris, A.,
Vacuum ultraviolet photoelectron spectroscopy of transient species. Part 14. A study of the ground state of NF+ via the ionization processes NF+(X 2Π)←NF(X3Σ-,a1Δ),
J. Chem. Soc. Faraday Trans. 2, 1982, 78, 1445. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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