Nitrous oxide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
ΔfH°gas82.05kJ/molReviewChase, 1998Data last reviewed in December, 1964
Quantity Value Units Method Reference Comment
S°gas,1 bar219.96J/mol*KReviewChase, 1998Data last reviewed in December, 1964

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 1400.1400. to 6000.
A 27.6798860.30274
B 51.148981.034566
C -30.64454-0.192997
D 6.8479110.012540
E -0.157906-6.860254
F 71.2493448.61390
G 238.6164272.5002
H 82.0482482.04824
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1964 Data last reviewed in December, 1964

Phase change data

Go To: Top, Gas phase thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Ptriple0.87890barN/AFonseca and Lobo, 1989Uncertainty assigned by TRC = 0.0001 bar; TRC
Ptriple0.8791barN/ACalado, Rebelo, et al., 1986Uncertainty assigned by TRC = 0.00008 bar; TRC
Quantity Value Units Method Reference Comment
Tc309.56KN/AOhgaki, Umezono, et al., 1990Uncertainty assigned by TRC = 0.15 K; TRC
Tc309.65KN/ALi and Kiran, 1988Uncertainty assigned by TRC = 0.2 K; TRC
Tc309.49KN/ATsiklis and Prokhorov, 1967TRC
Tc309.55KN/ACook, 1953Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Pc72.38barN/AOhgaki, Umezono, et al., 1990Uncertainty assigned by TRC = 0.20 bar; TRC
Pc72.70barN/ALi and Kiran, 1988Uncertainty assigned by TRC = 0.50 bar; TRC
Pc72.346barN/ACook, 1953Uncertainty assigned by TRC = 0.5066 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.0955l/molN/ALi and Kiran, 1988Uncertainty assigned by TRC = 0.002 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc10.3mol/lN/AOhgaki, Umezono, et al., 1990Uncertainty assigned by TRC = 0.1 mol/l; TRC
ρc10.2mol/lN/ATsiklis and Prokhorov, 1967Visual in pVT apparatus, Khodeeva and Lebedeva Russ. J. Phys. Chem. 1966, 40, 1668.; TRC
ρc10.3mol/lN/ACook, 1953Uncertainty assigned by TRC = 0.05 mol/l; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
16.5184.7Atake and Chihara, 1974AC
16.1221.Hoge, 1945Based on data from 182. to 236. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
129.8 to 187.74.37799621.077-44.659Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
25.1 ± 0.474.LEBryson, Cazcarra, et al., 1974Based on data from 68. to 80. K.; AC
24.6161.N/ABlue and Giauque, 1935Based on data from 148. to 182. K.; AC
23.6113.MGBlack, van Praagh, et al., 1930Based on data from 103. to 123. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
6.5182.4Atake and Chihara, 1974AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

k°H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.0252600.LN/AThe parameterization given by missing citation (parameters A, B, C) doesn't fit the data in the same paper for this substance. Therefore the parameteriztaion of the solubility data (X1) was recalculated.
0.0242800.QN/AOnly the tabulated data between T = 273. K and T = 303. K from missing citation was used to derive kH and -Δ kH/R. Above T = 303. K the tabulated data could not be parameterized by equation (reference missing) very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by missing citation. The quantities A and α from missing citation were assumed to be identical.
0.025 QN/ASeveral references are given in the list of Henry's law constants but not assigned to specific species.
0.0242600.LN/A 
0.026 QN/A 
0.0242700.XN/A 
0.025 XN/AThe value is taken from the compilation of solubilities by W. Asman (unpublished).

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess

View reactions leading to N2O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.889 ± 0.004eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)549.8kJ/molN/AHunter and Lias, 1998at N; HL
Proton affinity (review)575.2kJ/molN/AHunter and Lias, 1998at O; HL
Quantity Value Units Method Reference Comment
Gas basicity523.3kJ/molN/AHunter and Lias, 1998at N; HL
Gas basicity548.7kJ/molN/AHunter and Lias, 1998at O; HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.22 ± 0.10CIDTTiernan and Wu, 1978B
>-0.15 ± 0.10NBIENalley, Compton, et al., 1973B
0.27 ± 0.17ECDWentworth, Chen, et al., 1971B
<0.76 ± 0.10LPESCoe, Snodgrass, et al., 1986Vertical Detachment Energy: ca. 1.5 eV. Anion bent, with little Franck-Condon overlap; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.89PEKimura, Katsumata, et al., 1981LLK
12. ± 1.PIHitchcock, Brion, et al., 1980LLK
12.91 ± 0.03EISahini, Constantin, et al., 1978LLK
12.886 ± 0.002PEBerkowitz and Eland, 1977LLK
12.88 ± 0.005PICoppens, Smets, et al., 1974LLK
12.89 ± 0.005PICoppens, Smets, et al., 1974LLK
12.90PEEland, 1973LLK
12.891 ± 0.008PECollin and Natalis, 1969RDSH
12.893 ± 0.005PEBrundle and Turner, 1969RDSH
12.89PICook, Metzger, et al., 1968RDSH
12.888 ± 0.007PIDibeler and Walker, 1967RDSH
12.8 ± 0.05EICarette, 1967RDSH
12.882 ± 0.008PINicholson, 1965RDSH
12.894STanaka, Jursa, et al., 1960RDSH
12.89PEPotts and Williams, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
N+20. ± 1.NOPIHitchcock, Brion, et al., 1980LLK
N+19.494NOPEBerkowitz and Eland, 1977LLK
N+20.06NOPEDibeler, Walker, et al., 1967RDSH
NO+15.3 ± 0.1NEIOlivier, Locht, et al., 1982LBLHLM
NO+16. ± 1.NPIHitchcock, Brion, et al., 1980LLK
NO+16.53 ± 0.01NPICoppens, Smets, et al., 1974LLK
NO+15.01NPICoppens, Smets, et al., 1974LLK
NO+17.73 ± 0.01NPICoppens, Smets, et al., 1974LLK
NO+14.3 ± 0.3N(4Sø)EIColeman, Delderfield, et al., 1969RDSH
NO+17.74N(2Pø)?PIDibeler and Walker, 1967RDSH
NO+16.53N(2Dø)?PIDibeler and Walker, 1967RDSH
NO+15.01N(4Sø)PIDibeler and Walker, 1967RDSH
NO+13.75 ± 0.10N(4Sø)EICurran and Fox, 1961RDSH
N2+17.3 ± 0.2OEIOlivier, Locht, et al., 1982LBLHLM
N2+18. ± 1.OPIHitchcock, Brion, et al., 1980LLK
N2+17.29OPIDibeler, 1967RDSH
O+15. ± 1.N2PIHitchcock, Brion, et al., 1980LLK
O+15.31N2PIDibeler, Walker, et al., 1967RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Nitrous oxide = (Bromine anion • Nitrous oxide)

By formula: Br- + N2O = (Br- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°23. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°75.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion • Nitrous oxide) + Nitrous oxide = (Bromine anion • 2Nitrous oxide)

By formula: (Br- • N2O) + N2O = (Br- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°23. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°91.2J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion • 2Nitrous oxide) + Nitrous oxide = (Bromine anion • 3Nitrous oxide)

By formula: (Br- • 2N2O) + N2O = (Br- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.8J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Methyl cation + Nitrous oxide = (Methyl cation • Nitrous oxide)

By formula: CH3+ + N2O = (CH3+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°221.kJ/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 202. kJ/mol; Foster, Williamson, et al., 1974; M

Chlorine anion + Nitrous oxide = (Chlorine anion • Nitrous oxide)

By formula: Cl- + N2O = (Cl- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°24. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.3J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • Nitrous oxide) + Nitrous oxide = (Chlorine anion • 2Nitrous oxide)

By formula: (Cl- • N2O) + N2O = (Cl- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°24. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • 2Nitrous oxide) + Nitrous oxide = (Chlorine anion • 3Nitrous oxide)

By formula: (Cl- • 2N2O) + N2O = (Cl- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • 3Nitrous oxide) + Nitrous oxide = (Chlorine anion • 4Nitrous oxide)

By formula: (Cl- • 3N2O) + N2O = (Cl- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • 4Nitrous oxide) + Nitrous oxide = (Chlorine anion • 5Nitrous oxide)

By formula: (Cl- • 4N2O) + N2O = (Cl- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

Fluorine anion + Nitrous oxide = (Fluorine anion • Nitrous oxide)

By formula: F- + N2O = (F- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°41. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • Nitrous oxide) + Nitrous oxide = (Fluorine anion • 2Nitrous oxide)

By formula: (F- • N2O) + N2O = (F- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°39. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 2Nitrous oxide) + Nitrous oxide = (Fluorine anion • 3Nitrous oxide)

By formula: (F- • 2N2O) + N2O = (F- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°35. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 3Nitrous oxide) + Nitrous oxide = (Fluorine anion • 4Nitrous oxide)

By formula: (F- • 3N2O) + N2O = (F- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°31. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°102.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 4Nitrous oxide) + Nitrous oxide = (Fluorine anion • 5Nitrous oxide)

By formula: (F- • 4N2O) + N2O = (F- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°26. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°107.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 5Nitrous oxide) + Nitrous oxide = (Fluorine anion • 6Nitrous oxide)

By formula: (F- • 5N2O) + N2O = (F- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°25. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°108.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 6Nitrous oxide) + Nitrous oxide = (Fluorine anion • 7Nitrous oxide)

By formula: (F- • 6N2O) + N2O = (F- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°14.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(H- • 4294967295Nitrous oxide) + Nitrous oxide = H-

By formula: (H- • 4294967295N2O) + N2O = H-

Quantity Value Units Method Reference Comment
ΔrH°248. ± 17.kJ/molTherSheldon, Ohair, et al., 1995gas phase; Acidity between PhCOMe, HCONHMe, near CF3CH2OH. Acid: H2N-NO; B

HN2O+ + Nitrous oxide = (HN2O+ • Nitrous oxide)

By formula: HN2O+ + N2O = (HN2O+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°69.9kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°86.2kJ/molPHPMSSzulejko and McMahon, 1992gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°132.J/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M

(HN2O+ • Nitrous oxide) + Nitrous oxide = (HN2O+ • 2Nitrous oxide)

By formula: (HN2O+ • N2O) + N2O = (HN2O+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°27.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 2Nitrous oxide) + Nitrous oxide = (HN2O+ • 3Nitrous oxide)

By formula: (HN2O+ • 2N2O) + N2O = (HN2O+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 3Nitrous oxide) + Nitrous oxide = (HN2O+ • 4Nitrous oxide)

By formula: (HN2O+ • 3N2O) + N2O = (HN2O+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 4Nitrous oxide) + Nitrous oxide = (HN2O+ • 5Nitrous oxide)

By formula: (HN2O+ • 4N2O) + N2O = (HN2O+ • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°130.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 5Nitrous oxide) + Nitrous oxide = (HN2O+ • 6Nitrous oxide)

By formula: (HN2O+ • 5N2O) + N2O = (HN2O+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°130.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(HO- • Nitrous oxide) + Nitrous oxide = (HO- • 2Nitrous oxide)

By formula: (HO- • N2O) + N2O = (HO- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°32.6kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.485 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • 2Nitrous oxide) + Nitrous oxide = (HO- • 3Nitrous oxide)

By formula: (HO- • 2N2O) + N2O = (HO- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°28.9kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.761 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • 3Nitrous oxide) + Nitrous oxide = (HO- • 4Nitrous oxide)

By formula: (HO- • 3N2O) + N2O = (HO- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°>30. ± 140.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.981 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- • 4Nitrous oxide) + Nitrous oxide = (HO- • 5Nitrous oxide)

By formula: (HO- • 4N2O) + N2O = (HO- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°>20. ± 230.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 3.146 eV. Affinity is EA difference with next lower +0.08 eV f; B

Hydronium cation + Nitrous oxide = (Hydronium cation • Nitrous oxide)

By formula: H3O+ + N2O = (H3O+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°70.7kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Hydronium cation • Nitrous oxide) + Nitrous oxide = (Hydronium cation • 2Nitrous oxide)

By formula: (H3O+ • N2O) + N2O = (H3O+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°50.6kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Hydronium cation • 2Nitrous oxide) + Nitrous oxide = (Hydronium cation • 3Nitrous oxide)

By formula: (H3O+ • 2N2O) + N2O = (H3O+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°42.7kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Hydronium cation • 3Nitrous oxide) + Nitrous oxide = (Hydronium cation • 4Nitrous oxide)

By formula: (H3O+ • 3N2O) + N2O = (H3O+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

Iodide + Nitrous oxide = (Iodide • Nitrous oxide)

By formula: I- + N2O = (I- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°16. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide • Nitrous oxide) + Nitrous oxide = (Iodide • 2Nitrous oxide)

By formula: (I- • N2O) + N2O = (I- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°14. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide • 2Nitrous oxide) + Nitrous oxide = (Iodide • 3Nitrous oxide)

By formula: (I- • 2N2O) + N2O = (I- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°13.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°63.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Iodide • 3Nitrous oxide) + Nitrous oxide = (Iodide • 4Nitrous oxide)

By formula: (I- • 3N2O) + N2O = (I- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 4Nitrous oxide) + Nitrous oxide = (Iodide • 5Nitrous oxide)

By formula: (I- • 4N2O) + N2O = (I- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 5Nitrous oxide) + Nitrous oxide = (Iodide • 6Nitrous oxide)

By formula: (I- • 5N2O) + N2O = (I- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°9.6 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 6Nitrous oxide) + Nitrous oxide = (Iodide • 7Nitrous oxide)

By formula: (I- • 6N2O) + N2O = (I- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°9.2 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 7Nitrous oxide) + Nitrous oxide = (Iodide • 8Nitrous oxide)

By formula: (I- • 7N2O) + N2O = (I- • 8N2O)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 8Nitrous oxide) + Nitrous oxide = (Iodide • 9Nitrous oxide)

By formula: (I- • 8N2O) + N2O = (I- • 9N2O)

Quantity Value Units Method Reference Comment
ΔrH°10. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 9Nitrous oxide) + Nitrous oxide = (Iodide • 10Nitrous oxide)

By formula: (I- • 9N2O) + N2O = (I- • 10N2O)

Quantity Value Units Method Reference Comment
ΔrH°7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 10Nitrous oxide) + Nitrous oxide = (Iodide • 11Nitrous oxide)

By formula: (I- • 10N2O) + N2O = (I- • 11N2O)

Quantity Value Units Method Reference Comment
ΔrH°4.2 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide • 11Nitrous oxide) + Nitrous oxide = (Iodide • 12Nitrous oxide)

By formula: (I- • 11N2O) + N2O = (I- • 12N2O)

Quantity Value Units Method Reference Comment
ΔrH°5.4 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

Nitric oxide anion + Nitrous oxide = (Nitric oxide anion • Nitrous oxide)

By formula: NO- + N2O = (NO- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°60. ± 100.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°62.3J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=32.2 kJ/mol; M

(Nitric oxide anion • Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 2Nitrous oxide)

By formula: (NO- • N2O) + N2O = (NO- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°24.7 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.2kJ/molN/ACoe, Snodgrass, et al., 1987gas phase; B
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
ΔrH°30.kJ/molPESCoe, Snodgrass, et al., 1986gas phase; D(N2O)2 not accounted for; M
Quantity Value Units Method Reference Comment
ΔrG°-4.2 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 2Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 3Nitrous oxide)

By formula: (NO- • 2N2O) + N2O = (NO- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 3Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 4Nitrous oxide)

By formula: (NO- • 3N2O) + N2O = (NO- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.9 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 4Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 5Nitrous oxide)

By formula: (NO- • 4N2O) + N2O = (NO- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.6 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
ΔrH°19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-6.3 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 5Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 6Nitrous oxide)

By formula: (NO- • 5N2O) + N2O = (NO- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.4 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
ΔrG°-7.9 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 6Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 7Nitrous oxide)

By formula: (NO- • 6N2O) + N2O = (NO- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.6 ± 1.3kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
ΔrG°-11. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°59.0kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol; M
ΔrH°54.8kJ/molPILinn and Ng, 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol; M

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molEICameron, Aitken, et al., 1994gas phase; M
ΔrH°23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(N2O2- • 4294967295Nitrous oxide) + Nitrous oxide = N2O2-

By formula: (N2O2- • 4294967295N2O) + N2O = N2O2-

Quantity Value Units Method Reference Comment
ΔrH°96.7 ± 5.0kJ/molN/ALi and Continetti, 2002gas phase; B
ΔrH°135.1 ± 2.9kJ/molLPDOsboen, Leahy, et al., 1996gas phase; Affinity at 0 K; B

(O- • Nitrous oxide) + Nitrous oxide = (O- • 2Nitrous oxide)

By formula: (O- • N2O) + N2O = (O- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.6 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-1. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 2Nitrous oxide) + Nitrous oxide = (O- • 3Nitrous oxide)

By formula: (O- • 2N2O) + N2O = (O- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.6 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-4. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 3Nitrous oxide) + Nitrous oxide = (O- • 4Nitrous oxide)

By formula: (O- • 3N2O) + N2O = (O- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-8.4 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 4Nitrous oxide) + Nitrous oxide = (O- • 5Nitrous oxide)

By formula: (O- • 4N2O) + N2O = (O- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-9.6 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 5Nitrous oxide) + Nitrous oxide = (O- • 6Nitrous oxide)

By formula: (O- • 5N2O) + N2O = (O- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-11. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- • 6Nitrous oxide) + Nitrous oxide = (O- • 7Nitrous oxide)

By formula: (O- • 6N2O) + N2O = (O- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-14. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Oxygen cation + Nitrous oxide = (Oxygen cation • Nitrous oxide)

By formula: O2+ + N2O = (O2+ • N2O)

Quantity Value Units Method Reference Comment
ΔrH°56.1kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrH°45. ± 2.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=45.2 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
ΔrS°64.0J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=45.2 kJ/mol; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.200.FAAdams and Bohme, 1970gas phase; switching reaction(O2+)O2; M

(Oxygen cation • Nitrous oxide) + Nitrous oxide = (Oxygen cation • 2Nitrous oxide)

By formula: (O2+ • N2O) + N2O = (O2+ • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°31.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 2Nitrous oxide) + Nitrous oxide = (Oxygen cation • 3Nitrous oxide)

By formula: (O2+ • 2N2O) + N2O = (O2+ • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°25.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 3Nitrous oxide) + Nitrous oxide = (Oxygen cation • 4Nitrous oxide)

By formula: (O2+ • 3N2O) + N2O = (O2+ • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 4Nitrous oxide) + Nitrous oxide = (Oxygen cation • 5Nitrous oxide)

By formula: (O2+ • 4N2O) + N2O = (O2+ • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 5Nitrous oxide) + Nitrous oxide = (Oxygen cation • 6Nitrous oxide)

By formula: (O2+ • 5N2O) + N2O = (O2+ • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 6Nitrous oxide) + Nitrous oxide = (Oxygen cation • 7Nitrous oxide)

By formula: (O2+ • 6N2O) + N2O = (O2+ • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

Oxygen anion + Nitrous oxide = (Oxygen anion • Nitrous oxide)

By formula: O2- + N2O = (O2- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2O..O2- + O2 -> O4- + N2O; B
ΔrH°37.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(Oxygen anion • Nitrous oxide) + Nitrous oxide = (Oxygen anion • 2Nitrous oxide)

By formula: (O2- • N2O) + N2O = (O2- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°36.4 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 2Nitrous oxide) + Nitrous oxide = (Oxygen anion • 3Nitrous oxide)

By formula: (O2- • 2N2O) + N2O = (O2- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°26.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 3Nitrous oxide) + Nitrous oxide = (Oxygen anion • 4Nitrous oxide)

By formula: (O2- • 3N2O) + N2O = (O2- • 4N2O)

Quantity Value Units Method Reference Comment
ΔrH°23.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-6.3 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 4Nitrous oxide) + Nitrous oxide = (Oxygen anion • 5Nitrous oxide)

By formula: (O2- • 4N2O) + N2O = (O2- • 5N2O)

Quantity Value Units Method Reference Comment
ΔrH°22.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-7.9 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion • 5Nitrous oxide) + Nitrous oxide = (Oxygen anion • 6Nitrous oxide)

By formula: (O2- • 5N2O) + N2O = (O2- • 6N2O)

Quantity Value Units Method Reference Comment
ΔrH°20.9 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-9.2 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
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NIST MS number 70

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References

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Fonseca and Lobo, 1989
Fonseca, I.M.A.; Lobo, L.Q., Thermodynamics of liquid mixtures of xenon and methyl fluoride, Fluid Phase Equilib., 1989, 47, 249. [all data]

Calado, Rebelo, et al., 1986
Calado, J.C.G.; Rebelo, L.P.N.; Streett, W.B.; Zollweg, J.A., Thermodynamics of liquid (dimethylether + xenon), J. Chem. Thermodyn., 1986, 18, 931. [all data]

Ohgaki, Umezono, et al., 1990
Ohgaki, K.; Umezono, S.; Katayama, T., Pressure-density-temperature (p-ρ-T) relations of fluoroform, nitrous oxide, and propene in the critical region, J. Supercrit. Fluids, 1990, 3, 78-84. [all data]

Li and Kiran, 1988
Li, L.; Kiran, E., Gas-Liquid Critical Properties of Methylamine + Nitrous Oxide and Methylamine + Ethylene Binary Mixtures, J. Chem. Eng. Data, 1988, 33, 342. [all data]

Tsiklis and Prokhorov, 1967
Tsiklis, D.S.; Prokhorov, V.M., Phase equilibria in systems containing fluorine compounds, Zh. Fiz. Khim., 1967, 41, 2195-9. [all data]

Cook, 1953
Cook, D., Vapor Pressure and Orthobaric Density of Nitrous Oxide, Trans. Faraday Soc., 1953, 49, 716. [all data]

Atake and Chihara, 1974
Atake, Tooru; Chihara, Hideaki, A New Condensed Gas Calorimeter. Thermodynamic Properties of Solid and Liquid Dinitrogen Oxide, Bull. Chem. Soc. Jpn., 1974, 47, 9, 2126-2136, https://doi.org/10.1246/bcsj.47.2126 . [all data]

Hoge, 1945
Hoge, H.J., Vapor pressure, latent heat of vaporization, and triple-point temperature of N2O, J. RES. NATL. BUR. STAN., 1945, 34, 3, 281-17, https://doi.org/10.6028/jres.034.015 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Bryson, Cazcarra, et al., 1974
Bryson, Charles E.; Cazcarra, Victor; Levenson, Leonard L., Sublimation rates and vapor pressures of water, carbon dioxide, nitrous oxide, and xenon, J. Chem. Eng. Data, 1974, 19, 2, 107-110, https://doi.org/10.1021/je60061a021 . [all data]

Blue and Giauque, 1935
Blue, R.W.; Giauque, W.F., The Heat Capacity and Vapor Pressure of Solid and Liquid Nitrous Oxide. The Entropy from its Band Spectrum, J. Am. Chem. Soc., 1935, 57, 6, 991-997, https://doi.org/10.1021/ja01309a008 . [all data]

Black, van Praagh, et al., 1930
Black, H.K.; van Praagh, G.; Topley, B., Note on the vapour pressure of solid nitrous oxide, Trans. Faraday Soc., 1930, 26, 196, https://doi.org/10.1039/tf9302600196 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C., Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds, Adv. Mass Spectrom., 1978, 7A, 136. [all data]

Nalley, Compton, et al., 1973
Nalley, S.J.; Compton, R.N.; Schweinler, H.C.; Anderson, V.E., Molecular electron affinities from collisional ionization of cesium. I. NO, NO2, and N2O, J. Chem. Phys., 1973, 59, 4125. [all data]

Wentworth, Chen, et al., 1971
Wentworth, W.E.; Chen, E.; Freeman, R., Thermal electron attachment to N2O, J. Chem. Phys., 1971, 55, 2075. [all data]

Coe, Snodgrass, et al., 1986
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of N2O- and (N2O)2-, Chem. Phys. Lett., 1986, 124, 274. [all data]

Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]

Hitchcock, Brion, et al., 1980
Hitchcock, A.P.; Brion, C.E.; Van der Wiel, M.J., Absolute oscillator strengths for valence-shell ionic photofragmentation of N2O and CO2(8-75 eV), Chem. Phys., 1980, 45, 461. [all data]

Sahini, Constantin, et al., 1978
Sahini, V.E.; Constantin, V.; Serban, I., Determination of ionization potentials using a MI-1305 mass spectrometer, Rev. Roum. Chim., 1978, 23, 479. [all data]

Berkowitz and Eland, 1977
Berkowitz, J.; Eland, J.H.D., Photoionization of N2O: Mechanisms of photoionization and ion dissociation, J. Chem. Phys., 1977, 67, 2740. [all data]

Coppens, Smets, et al., 1974
Coppens, P.; Smets, J.; Fishel, M.G.; Drowart, J., Mass spectrometric study of the photoionization of nitrous oxide in the wavelength interval 1000-600 A, Int. J. Mass Spectrom. Ion Phys., 1974, 14, 57. [all data]

Eland, 1973
Eland, J.H.D., Predissociation of N2O+ and COS+ ions studied by photoelectronphotoion coincidence spectroscopy, Int. J. Mass Spectrom. Ion Phys., 1973, 12, 389. [all data]

Collin and Natalis, 1969
Collin, J.E.; Natalis, P., Determination des etats electroniques et des niveaux de vibration des ions moleculaires par spectroscopie de photoelectrons, Bull. Classe Sci. Acad. Roy. Belg., 1969, 55, 352. [all data]

Brundle and Turner, 1969
Brundle, C.R.; Turner, D.W., Studies on the photoionisation of the linear triatomic molecules: N2O, COS, CS2 and CO2 using high-resolution photoelectron spectroscopy, Intern. J. Mass Spectrom. Ion Phys., 1969, 2, 195. [all data]

Cook, Metzger, et al., 1968
Cook, G.R.; Metzger, P.H.; Ogawa, M., Photoionization and absorption coefficients of N2O, J. Opt. Soc. Am., 1968, 58, 129. [all data]

Dibeler and Walker, 1967
Dibeler, V.H.; Walker, J.A., Mass spectrometric study of the photoionization of small polyatomic molecules, Advan. Mass Spectrom., 1967, 4, 767. [all data]

Carette, 1967
Carette, J.-D., Ionisation par impact electronique de CO2 et N2O, Can. J. Phys., 1967, 45, 2931. [all data]

Nicholson, 1965
Nicholson, A.J.C., Photoionization-efficiency curves. II. False and genuine structure, J. Chem. Phys., 1965, 43, 1171. [all data]

Tanaka, Jursa, et al., 1960
Tanaka, Y.; Jursa, A.S.; LeBlanc, F.J., Higher ionization potentials of linear triatomic molecules. II. CS2, COS, and N2O, J. Chem. Phys., 1960, 32, 1205. [all data]

Potts and Williams, 1974
Potts, A.W.; Williams, T.A., The observation of "forbidden" transitions in He II photoelectron spectra, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 3. [all data]

Dibeler, Walker, et al., 1967
Dibeler, V.H.; Walker, J.A.; Liston, S.K., Mass spectrometric study of photoionization. VII.Nitrogen dioxide and nitrous oxide, J.Res. NBS, 1967, 71A, 371. [all data]

Olivier, Locht, et al., 1982
Olivier, J.L.; Locht, R.; Momigny, J., A dissociative electroionization study of nitrous oxide. The No and N2 dissociation channels, Chem. Phys., 1982, 68, 201. [all data]

Coleman, Delderfield, et al., 1969
Coleman, R.J.; Delderfield, J.S.; Reuben, B.G., The gas-phase decomposition of the nitrous oxide ion, Intern. J. Mass Spectrom. Ion Phys., 1969, 2, 25. [all data]

Curran and Fox, 1961
Curran, R.K.; Fox, R.E., Mass spectrometer investigation of ionization of N2O by electron impact, J. Chem. Phys., 1961, 34, 1590. [all data]

Dibeler, 1967
Dibeler, V.H., N2O bond dissociation energy by photon impact, J. Chem. Phys., 1967, 47, 2191. [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

McMahon, Heinis, et al., 1988
McMahon, T.; Heinis, T.; Nicol, G.; Hovey, J.K.; Kebarle, P., Methyl Cation Affinities, J. Am. Chem. Soc., 1988, 110, 23, 7591, https://doi.org/10.1021/ja00231a002 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Sheldon, Ohair, et al., 1995
Sheldon, J.C.; Ohair, R.A.J.; Downard, K.M.; Gronert, S.; Krempp, M.; Depuy, C.H.; Bowie, J.H., A potential surface map of the H-/N2O system. The gas phase ion chemistry of HN2O-, Aust. J. Chem., 1995, 48, 155. [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Szulejko and McMahon, 1992
Szulejko, J.; McMahon, T.B., personal communication, 1992. [all data]

Kim, Wenthold, et al., 1998
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Photoelectron spectroscopy of OH-(N2O)(n=1-5), J. Chem. Phys., 1998, 108, 3, 830-837, https://doi.org/10.1063/1.475447 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S., Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2), J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444 . [all data]

Coe, Snodgrass, et al., 1987
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Photoelectron spectroscopy of the negative cluster ions, NO-(N2O)n=1,2, J. Chem. Phys., 1987, 87, 4302. [all data]

Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-), J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006 . [all data]

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Li and Continetti, 2002
Li, R.J.; Continetti, R.E., Studies of the excited state dynamics of N2O2 by dissociative photodetachment of N2O2-, J. Phys. Chem. A, 2002, 106, 7, 1183-1189, https://doi.org/10.1021/jp013330u . [all data]

Osboen, Leahy, et al., 1996
Osboen, D.L.; Leahy, D.J.; Cyr, D.R.; Neumark, D.M., Photodissociation Spectroscopy and Dynamics of the N2O2- Anion, J. Chem. Phys., 1996, 104, 13, 5026, https://doi.org/10.1063/1.471132 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References