Stannane, tetraphenyl-
- Formula: C24H20Sn
- Molecular weight: 427.126
- IUPAC Standard InChIKey: CRHIAMBJMSSNNM-UHFFFAOYSA-N
- CAS Registry Number: 595-90-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraphenylstannane; Tetraphenyltin; Tin, tetraphenyl-,
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 170. ± 90. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 130. ± 90. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -3177.2 ± 1.3 | kcal/mol | CC-SB | Adams, Carson, et al., 1969 | Please also see Pedley and Rylance, 1977.; MS |
ΔcH°solid | -3195.0 ± 3.0 | kcal/mol | CC-SB | Tel'noi and Rabinovich, 1965 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -3177.72 ± 0.81 | kcal/mol | CC-SB | Pope and Skinner, 1964 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -3242.5 ± 1.7 | kcal/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Cox and Pilcher, 1970.; MS |
ΔcH°solid | -3307.5 ± 3.0 | kcal/mol | CC-SB | Birr, 1962 | MS |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
101.9 | 298.5 | Smith and Andrews, 1931 | T = 102 to 346 K. Value is unsmoothed experimental datum.; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 501. | K | N/A | Adams and Carson, 1969 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 503.2 | K | N/A | Sangster and Irvine, 1956 | Uncertainty assigned by TRC = 4. K; TRC |
Tfus | 499.1 | K | N/A | Forward, Bowden, et al., 1949 | Uncertainty assigned by TRC = 0.7 K; TRC |
Tfus | 499.15 | K | N/A | Smith and Andrews, 1931, 2 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 38.5 ± 1.0 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Adams, Carson, et al., 1969, 2.; AC |
ΔsubH° | 14.2 | kcal/mol | N/A | Newkirk, 1972 | See also Marcus and Loewenschuss, 1986.; AC |
ΔsubH° | 38.5 ± 1.0 | kcal/mol | CC-SB | Keiser and Kana'an, 1969 | MS |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
36.26 | 427. | A | Stephenson and Malanowski, 1987 | Based on data from 393. to 461. K.; AC |
36.4 ± 0.1 | 428. to 454. | TE | Keiser and Kana'an, 1969, 2 | AC |
36.28 ± 0.26 | 393. to 461. | ME | Keiser and Kana'an, 1969, 2 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
8.89 | 502.2 | DSC | Vitoria and Walkley, 1969 | AC |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.1 | PE | Novak and Potts, 1984 | LBLHLM |
8.34 ± 0.03 | PI | Rodionov, Potapov, et al., 1973 | LLK |
9.04 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C6H5Sn+ | 16.1 ± 0.5 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
C12H10Sn+ | 9.1 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
C18H15Sn+ | 9.6 ± 0.2 | ? | EI | Chambers and Glockling, 1970 | RDSH |
C18H15Sn+ | 10.1 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
Sn+ | 9.4 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 163437 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G.,
J. Chem. Thermodyn., 1969, 1, 393. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. J. Phys. Chem., 1965, 39, 1239. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A.,
Trans. Faraday Soc., 1964, 60, 1402. [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Birr, 1962
Birr, K.-H.,
Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H.,
Thermal energy studies. II. Phenyl derivatives of metals,
J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]
Adams and Carson, 1969
Adams, G.P.; Carson, A.S.,
The Enthalpy of COmbustion of Organimetallic Compounds Measured with a Vacuum-jacketed Aneroud Calorimeter. The Enthalpy of Formation of Tin Tetraphenyl,
J. Chem. Thermodyn., 1969, 1, 393-6. [all data]
Sangster and Irvine, 1956
Sangster, R.C.; Irvine, J.W.,
Study of Organic Scintillators,
J. Chem. Phys., 1956, 24, 670. [all data]
Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J.,
Physical Properties of Triphenyl Compounds of Group VB Elements,
J. Chem. Soc., 1949, 1949, 121-6. [all data]
Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H.,
Thermal Energy Studies II. Phenyl Derivatives of Metals,
J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Adams, Carson, et al., 1969, 2
Adams, G.P.; Carson, A.S.; Laye, P.G.,
The enthalpy of combustion of organometallic compounds measured with a vacuum-jacketed aneroid calorimeter The enthalpy of formation of tin tetraphenyl,
The Journal of Chemical Thermodynamics, 1969, 1, 4, 393-396, https://doi.org/10.1016/0021-9614(69)90069-X
. [all data]
Newkirk, 1972
Newkirk, Herbert W.,
Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead,
Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9
. [all data]
Marcus and Loewenschuss, 1986
Marcus, Yizhak; Loewenschuss, Aharon,
Entropies of tetrahedral M---phenyl species,
J. Chem. Soc., Faraday Trans. 1, 1986, 82, 3, 993, https://doi.org/10.1039/f19868200993
. [all data]
Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S.,
J. Phys. Chem., 1969, 73, 4264. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S.,
Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn,
J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038
. [all data]
Vitoria and Walkley, 1969
Vitoria, M.; Walkley, John,
Studies in regular solution theory. Part 1.?Solubolity studies of tetraphenyltin in simple non-polar solvents,
Trans. Faraday Soc., 1969, 65, 57, https://doi.org/10.1039/tf9696500057
. [all data]
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives,
J. Organomet. Chem., 1984, 262, 17. [all data]
Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L.,
Photoionization of certain aromatic heteroorganic compounds,
High Energy Chem., 1973, 7, 249, In original 278. [all data]
Occolowitz, Lett. 1966
Occolowitz, J.L.,
Electron impact fragmentation of some organotin compounds,
Tetrahedron, Lett. 1966, 5291. [all data]
Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F.,
Electron impact determination of heats of formation and bond energies in triphenyltin compounds,
Inorg. Chim. Acta, 1970, 4, 150. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy Cp,solid Constant pressure heat capacity of solid Tfus Fusion (melting) point ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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