Disiloxane, hexamethyl-

• Formula: C₆H₁₈OSi₂
• Molecular weight: 162.3775
• IUPAC Standard InChI: InChI=1S/C6H18OSi2/c1-8(2,3)7-9(4,5)6/h1-6H3 Copy

  
• IUPAC Standard InChIKey: UQEAIHBTYFGYIE-UHFFFAOYSA-N Copy
• CAS Registry Number: 107-46-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Bis(trimethylsilyl) ether; Bis(trimethylsilyl) oxide; Fluka AG; Hexamethyldisiloxane; ((CH3)3Si)2O; Oxybis(trimethylsilane); Silane, oxybis(trimethyl)-; Dow corning 200/0.65; H7310; HMDSO; Belsil DM 0.65; Disiloxane, 1,1,1,3,3,3-hexamethyl-; KF 96L; NSC 43346; OS 10; SWS-F 221; DC 200 FLUID (Salt/Mix)
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • IR Spectrum
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Enthalpy of fusion

Entropy of fusion

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dzhafarov and Kuliev, 1986
Dzhafarov, O.I.; Kuliev, A.M., Heat capacity and thermodynamic properties of disiloxanes, Dokl. Akad. Nauk. Azerb., 1986, SSR 42, 56-59. [all data]

Scott, Messerly, et al., 1961
Scott, D.W.; Messerly, J.F.; Todd, S.S.; Guthrie, G.B.; Hossenlopp, I.A.; Moore, R.T.; Osborn, A.; Berg, W.T.; McCullough, J.P., Hexamethyldisiloxane: chemical thermodynamic properties and internal rotation about the siloxane linkage, J. Phys. Chem., 1961, 65, 1320-1326. [all data]

Scott, Messerly, et al., 1961, 2
Scott, D.W.; Messerly, J.F.; Todd, S.S.; Guthrie, G.B.; Hossenlopp, I.A.; Moore, R.T.; Osborn, A.G.; Berg, W.T.; McCullough, J.P., Hexamethyldisiloxane: chemical thermodynamic properties and internal rotation about the siloxane linkage, J. Phys. Chem., 1961, 65, 1320-6. [all data]

McLure and Dickinson, 1976
McLure, I.A.; Dickinson, E., Vapor pressure of hexamethyldisiloxane near its critical point: corresponding-states principle for dimethylsiloxanes, J. Chem. Thermodyn., 1976, 8, 93-5. [all data]

Flaningam, 1986
Flaningam, Ora L., Vapor pressures of poly(dimethylsiloxane) oligomers, J. Chem. Eng. Data, 1986, 31, 3, 266-272, https://doi.org/10.1021/je00045a002 . [all data]

Ditsent, Skorokhodov, et al., 1971
Ditsent, V.E.; Skorokhodov, I.I.; Terent'eva, N.A.; Zolotareva, M.N., Russ. J. Phys. Chem., 1971, 45, 6, 901. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Seefeldt, Moller, et al., 1985
Seefeldt, R.; Moller, W.; Schmidt, M., Zur elektronenstossionisierung des hexamethyldisiloxans (HMDS), Z. Phys. Chem. (Leipzig), 1985, 266, 797. [all data]

Molder, Pikver, et al., 1983
Molder, U.H.; Pikver, R.J.; Koppel, I.A., Photoelectron spectra of molecules. 2. Ethers, Org. React. (N.Y. Engl. Transl.), 1983, 20, 208. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Starzewski, Dieck, et al., 1974
Starzewski, K.A.O.; Dieck, H.T.; Bock, H., Photoelectron spectra molecular properties. XXIII. Photoelectron spectra of silicon-substituted ylidic systems, J. Organomet. Chem., 1974, 65, 311. [all data]

Borossay, Csakvari, et al., 1971
Borossay, J.; Csakvari, B.; Szepes, L., Determination of bond energies of organic silicon compounds on the basis of appearance potentials, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 47. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  Cp,liquid	Constant pressure heat capacity of liquid
  Pc	Critical pressure
  S°liquid	Entropy of liquid at standard conditions
  Tboil	Boiling point
  Tc	Critical temperature
  Ttriple	Triple point temperature
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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