1-Piperidinyloxy, 2,2,6,6-tetramethyl-
- Formula: C9H18NO
- Molecular weight: 156.2453
- IUPAC Standard InChIKey: QYTDEUPAUMOIOP-UHFFFAOYSA-N
- CAS Registry Number: 2564-83-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Piperidinooxy, 2,2,6,6-tetramethyl-; (2,2,6,6-Tetramethylpiperidino)oxy; Tanan; Tanane; Tetramethylpiperidine nitroxide; Tetramethylpiperidinooxy; 1-Oxyl-2,2,6,6-tetramethylpiperidine; 1,1,5,5-Tetramethylpentamethylene nitroxide; 2,2,6,6-Tetramethyl-1-oxylpiperidine; 2,2,6,6-Tetramethyl-1-piperadoxyl; 2,2,6,6-Tetramethyl-1-piperidinoxyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy; 2,2,6,6-Tetramethylpiperidin-1-oxy; 2,2,6,6-Tetramethylpiperidin-1-oxyl; 2,2,6,6-Tetramethylpiperidine nitroxide; 2,2,6,6-Tetramethylpiperidine N-oxide radical; 2,2,6,6-Tetramethylpiperidine N-oxyl; 2,2,6,6-Tetramethylpiperidine N-oxyl radical; 2,2,6,6-Tetramethylpiperidine-1-oxyl radical; 2,2,6,6-Tetramethylpiperidinooxy radical; 2,2,6,6-Tetramethylpiperidinooxyl; 2,2,6,6-Tetramethylpiperidinoxyl radical; 2,2,6,6-Tetramethylpiperidinyl-N-oxy; 2,2,6,6-Tetramethylpiperidinyl-1-oxyl; 2,2,6,6-Tetramethylpiperidinyloxy; 2,2,6,6-Tetramethylpiperidoxyl; 1-Piperidinyloxy radical, 2,2,6,6-tetramethyl-; Tempo; 2,2,6,6-Tetramethylpiperidine-1-oxyl; 2,2,6,6-Tetramethyl-1-piperidyloxy; 2,2,6,6-Tetramethylpiperidine nitroxide radical; 2,2,6,6-Tetramethylpiperidinyl 1-oxide
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Gas phase ion energetics data
Go To: Top, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 210.9 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 203.1 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.73 | PE | Morishima, Yoshikawa, et al., 1972 | LLK |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-IW-7690 |
NIST MS number | 233286 |
UV/Visible spectrum
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | (editor), 1982 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 18459 |
Instrument | SF-16 |
Melting point | 37.8-38.1 |
References
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Morishima, Yoshikawa, et al., 1972
Morishima, I.; Yoshikawa, K.; Yonezawa, T.; Matsumoto, H.,
Photoelectron spectral studies of organic free radicals. The nitroxide radical,
Chem. Phys. Lett., 1972, 16, 336. [all data]
(editor), 1982
(editor), Koptyug V.A.,
Atlas of Spectra of Aromatic and Heterocyclic Compounds, 1982, 24, 105. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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