Mercury(II) chloride
- Formula: Cl2Hg
- Molecular weight: 271.50
- CAS Registry Number: 7487-94-7
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Gas phase ion energetics data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.38 ± 0.01 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.380 ± 0.003 | PI | Linn, Brom, et al., 1983 | LBLHLM |
11.5 | PE | Lee and Potts, 1981 | LLK |
11.37 | PE | Eland, 1970 | RDSH |
11.5 | PE | Boggess, Allen, et al., 1973 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Cl+ | 16.72 ± 0.32 | HgCl | PI | Linn, Brom, et al., 1983 | LBLHLM |
Cl+ | 17.7 ± 0.3 | ? | EI | Kiser, Dillard, et al., 1969 | RDSH |
ClHg+ | ≤11.041 | Cl | PI | Linn, Brom, et al., 1983 | LBLHLM |
HgCl+ | 12.06 ± 0.26 | Cl | EI | Kiser, Dillard, et al., 1969 | RDSH |
Hg+ | 12.59 ± 0.18 | Cl2 | PI | Linn, Brom, et al., 1983 | LBLHLM |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Drug Lab |
NIST MS number | 379684 |
References
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Linn, Brom, et al., 1983
Linn, S.H.; Brom, J.M., Jr.; Tzeng, W.-B.; Ng, C.Y.,
Molecular beam photoionization study of HgCl2,
J. Chem. Phys., 1983, 78, 37. [all data]
Lee and Potts, 1981
Lee, E.P.F.; Potts, A.W.,
Fine structure in the He(I)/He(II) photoelectron spectra of the metal valence (d) shells of the group IIB dihalides,
J. Electron Spectrosc. Relat. Phenom., 1981, 22, 247. [all data]
Eland, 1970
Eland, J.H.D.,
Photoelectron spectra and chemical bonding of mercury(II) compounds,
Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]
Boggess, Allen, et al., 1973
Boggess, G.W.; Allen, J.D., Jr.; Schweitzer, G.K.,
The photoelectron spectra of gaseous zinc(II) and cadmium(II) chlorides, bromides, and iodides,
J. Electron Spectrosc. Relat. Phenom., 1973, 2, 467. [all data]
Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L.,
Mass spectrometry of inorganic halides,
Advan. Chem. Ser., 1969, 72, 153. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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