Trimethylamine, compd. with borane (1:1)

• Formula: C₃H₁₂BN
• Molecular weight: 72.945
• IUPAC Standard InChI: InChI=1S/C3H12BN/c1-5(2,3)4/h1-4H3 Copy

  
• IUPAC Standard InChIKey: KQVSXUGMDCAISO-UHFFFAOYSA-N Copy
• CAS Registry Number: 75-22-9
• Chemical structure:
  This structure is also available as a 2d Mol file
• Species with the same structure:
  • Trimethylamine borane
• Other names: Boron, (N,N-dimethylmethanamine)trihydro-, (T-4)-; Trimethylamine borane; (CH3)3NBH3; Borane-trimethylamine complex; Borane-trimethylamine (1:1); Methanamine, N,N-dimethyl-, compd. with borane (1:1); Borane, compd. with N,N-dimethylmethanamine (1:1); Borane, compd. with trimethylamine (1:1); TMAB; NSC 10220; trimethylamine--borane (1:1); Boron, (N,N-dimethylmethanamine)trihydro-
• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

De-protonation reactions

C₃H₁₁BN^- +  =

By formula: C₃H₁₁BN^- + H⁺ = C₃H₁₂BN

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lloyd and Lynaugh, 1972
Lloyd, D.R.; Lynaugh, N., Photoelectron studies of boron compounds. Part 3. Complexes of borane with Lewis bases, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 947. [all data]

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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